Section 1 of 7Ionisation in water (HT only)
Acids release H+
- Acids release H+ When an acid dissolves in water its molecules split into hydrogen ions and a negative ion.
- In generalHX → H+ + X−.
Strength is about the extent of ionisation
- Strength is about the extent of ionisation A strong acid ionises completely, so every molecule splits into ions.
- A weak acid ionises only partially, so most molecules remain intact.
Effect on pH
- Effect on pH More H+ ions at the same concentration means a lower pH.
- Strong acids typically have pH 0–3 while weak acids are around pH 4–6.
Section 2 of 7Strong versus weak (HT only)
| Feature | Strong acid | Weak acid |
|---|---|---|
| Ionisation | Complete | Partial |
| Arrow in equation | → (goes to completion) | ⇌ (reversible) |
| Concentration of H+ | High | Low |
| Typical pH at same concentration | Low | Higher, nearer the middle of the scale |
| Examples | Hydrochloric, nitric, sulfuric | Ethanoic, citric, carbonic |
Section 3 of 7Equations to know (HT only)
Ionisation equations
Hydrochloric acid
- Hydrochloric acid HCl(aq) → H+(aq) + Cl−(aq)
Nitric acid
- Nitric acid HNO3(aq) → H+(aq) + NO3−(aq)
Sulfuric acid
- Sulfuric acid H2SO4(aq) → 2H+(aq) + SO42−(aq)
Ethanoic acid
- Ethanoic acid CH3COOH(aq) ⇌ H+(aq) + CH3COO−(aq)
Section 4 of 7Equilibrium in a weak acid (HT only)
1Dissolve
- Dissolve Weak acid molecules enter the water.
2Some ionise
- Some ionise A few molecules split into H+ and anions.
3Reverse reaction
- Reverse reaction Ions recombine to give molecules again, so the change is reversible.
4Equilibrium lies left
- Equilibrium lies left Mostly molecules, few ions, so the H+ concentration is low.
Section 5 of 7Strength versus concentration
Strength
- Strength A property of the acid itself: how much it ionises in water.
Concentration
- Concentration The amount of acid dissolved per dm3;
- you can have a dilute strong acid or a concentrated weak acid.
Reactions with alkali
- Reactions with alkali Weak acids still neutralise alkalis completely, for example CH3COOH + NaOH → CH3COONa + H2O.
Section 6 of 7Key terms
| Term | Meaning |
|---|---|
| Strong acid | An acid that ionises completely in water. |
| Weak acid | An acid that ionises only partially in water. |
| Ionisation | The splitting of a molecule into ions when it dissolves. |
| Reversible reaction | A reaction in which products can react to re-form the reactants, shown by ⇌. |
| Concentration | The amount of a substance dissolved in a given volume of solution. |
Section 7 of 7Exam technique
1
Confusing strong with concentrated; strength is about ionisation, concentration is about quantity per volume.
2
Writing a single arrow for weak acids when the reaction is reversible.
3
Saying weak acids do not neutralise alkalis fully — they do, only more slowly to ionise.
4
Assuming a weak acid has no H+ ions; it has fewer, not none.