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4.2.7Chemical Changes

Strong and Weak Acids

5 min read 7 parts Lesson 12 of 21 1 quiz

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Section 1 of 7Ionisation in water (HT only)

Acids release H+
  • Acids release H+ When an acid dissolves in water its molecules split into hydrogen ions and a negative ion.
  • In generalHX → H+ + X−.
Strength is about the extent of ionisation
  • Strength is about the extent of ionisation A strong acid ionises completely, so every molecule splits into ions.
  • A weak acid ionises only partially, so most molecules remain intact.
Effect on pH
  • Effect on pH More H+ ions at the same concentration means a lower pH.
  • Strong acids typically have pH 0–3 while weak acids are around pH 4–6.

Section 2 of 7Strong versus weak (HT only)

FeatureStrong acidWeak acid
IonisationCompletePartial
Arrow in equation→ (goes to completion)⇌ (reversible)
Concentration of H+HighLow
Typical pH at same concentrationLowHigher, nearer the middle of the scale
ExamplesHydrochloric, nitric, sulfuricEthanoic, citric, carbonic

Section 3 of 7Equations to know (HT only)

Ionisation equations
Hydrochloric acid
  • Hydrochloric acid HCl(aq) → H+(aq) + Cl−(aq)
Nitric acid
  • Nitric acid HNO3(aq) → H+(aq) + NO3−(aq)
Sulfuric acid
  • Sulfuric acid H2SO4(aq) → 2H+(aq) + SO42−(aq)
Ethanoic acid
  • Ethanoic acid CH3COOH(aq) ⇌ H+(aq) + CH3COO−(aq)

Section 4 of 7Equilibrium in a weak acid (HT only)

1Dissolve
  • Dissolve Weak acid molecules enter the water.
2Some ionise
  • Some ionise A few molecules split into H+ and anions.
3Reverse reaction
  • Reverse reaction Ions recombine to give molecules again, so the change is reversible.
4Equilibrium lies left
  • Equilibrium lies left Mostly molecules, few ions, so the H+ concentration is low.

Section 5 of 7Strength versus concentration

Strength
  • Strength A property of the acid itself: how much it ionises in water.
Concentration
  • Concentration The amount of acid dissolved per dm3;
    • you can have a dilute strong acid or a concentrated weak acid.
Reactions with alkali
  • Reactions with alkali Weak acids still neutralise alkalis completely, for example CH3COOH + NaOH → CH3COONa + H2O.

Section 6 of 7Key terms

TermMeaning
Strong acidAn acid that ionises completely in water.
Weak acidAn acid that ionises only partially in water.
IonisationThe splitting of a molecule into ions when it dissolves.
Reversible reactionA reaction in which products can react to re-form the reactants, shown by ⇌.
ConcentrationThe amount of a substance dissolved in a given volume of solution.

Section 7 of 7Exam technique

1
Confusing strong with concentrated; strength is about ionisation, concentration is about quantity per volume.
2
Writing a single arrow for weak acids when the reaction is reversible.
3
Saying weak acids do not neutralise alkalis fully — they do, only more slowly to ionise.
4
Assuming a weak acid has no H+ ions; it has fewer, not none.
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