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23.1.3Quantum and nuclear physics (A Level)

Mass Defect and Binding Energy

5 min read 11 parts Lesson 16 of 23 1 quiz

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23.1.3 Mass Defect and Binding Energy — AS PHYSICS 9702 notes: Define mass defect, binding energy and binding energy per nucleon and interpret the binding energy per nucleon curve.Mass defect = the difference between the mass of a nucleus and the sum of the individual masses of i…

  • Calculation
  • Bound system
  • Atomic masses
  • Not stored energy
  • Mass defect usage
  • Nuclear reactions

Section 1 of 11Mass defect

Mass defect
Mass defect
Mass defect the difference between the mass of a nucleus and the sum of the individual masses of its protons and neutrons.
Calculation
  • Δm = Zmp + (A − Z)mn − mnucleus.
  • Z is the proton number, A the nucleon number, and mp, mn the proton and neutron masses.
Bound system
  • A system of separated nucleons has more mass than the same nucleons bound together.
Atomic masses
  • Tables often give the mass of the whole atom including electrons.
  • Subtract the electron masses, or use hydrogen atom masses instead of proton masses so electrons cancel.

Section 2 of 11Binding energy

Binding energy
Binding energy the energy required to break a nucleus into its constituent protons and neutrons,
  • which is the minimum energy to separate the nucleons completely.
Equation
  • EB = Δmc2.
Formation
  • Forming a nucleus from free nucleons releases energy, so it is exothermic.
Unit
  • Binding energies are measured in MeV, and 1 u of mass defect corresponds to 931.5 MeV.
Not stored energy
  • It is the energy that must be put in to separate all the nucleons, not energy stored in the nucleus.
Mass defect usage
  • Use the term only when all the nucleons are separated, not for the mass decrease in radioactive decay.

Section 3 of 11Nuclear and chemical energy

Nuclear reactions
  • They involve changes in nuclear binding energy, which is in MeV.
Chemical reactions
  • They involve changes in electron binding energy, which is a few eV.
Result
  • This is why nuclear reactions release far more energy than chemical reactions.

Section 4 of 11Binding energy per nucleon

Definition
  • The binding energy of a nucleus divided by the number of nucleons in it, EB/A.
Stability
  • A higher binding energy per nucleon means a more stable nucleus.
Comparison
  • Always compare per nucleon, since higher total binding energy does not by itself mean greater stability.

Section 5 of 11Binding energy per nucleon curve

Shape
  • A graph of binding energy per nucleon (MeV) against nucleon number A.
Light nuclei
  • The curve rises steeply, with hydrogen-2 about 1.1 MeV per nucleon.
  • Helium-4 is unusually high at about 7.1 MeV, showing it is particularly stable.
  • Carbon-12 and oxygen-16 can be considered as three and four helium nuclei bound together.
Peak
  • The broad maximum is about 8.8 MeV per nucleon near A = 56, close to iron-56.
  • Iron-56 is the most stable nucleus (nickel-62 is marginally higher).
Heavy nuclei
  • The curve falls slowly to about 7.6 MeV per nucleon for uranium-238.

Section 6 of 11Drawing the curve

Start
  • Do not start the curve at A = 0, because a single nucleon is not a nucleus.
Anomaly
  • Mark helium as a cross above the best-fit curve.
Labels
  • Label both axes with units and give numbers, especially at the peak for iron-56.

Section 7 of 11Significance of the curve

Low A
  • Attractive nuclear forces dominate repulsion between protons, so nuclei can undergo fusion.
  • The gradient is steep, so fusion releases more energy per nucleon than fission.
High A
  • Repulsive electrostatic forces between protons begin to dominate, so nuclei can undergo fission.
  • The gradient is gentler, so fission releases less energy per nucleon than fusion.
Neutron excess
  • Heavier stable nuclei need more neutrons than protons,
  • because the electrostatic repulsion has long range but the strong force acts only between near neighbours.
Unstable ratios
  • Nuclei with a very high or very low neutron-to-proton ratio decay by beta emission towards the stable region.

Section 8 of 11Calculation method

1
Write the number of protons Z and neutrons A − Z.
2
Find the total mass of the separate nucleons.
3
Subtract the nuclear mass to get Δm.
4
Convert to energy using c2 or 931.5 MeV per u.
5
Divide by A for the binding energy per nucleon.
  • Precision
    • Keep several significant figures in the subtraction, since Δm is a small difference of two large numbers.

Section 9 of 11More from the specification

More from the specification
Mass-energy equivalence and mass defect
  • Mass and energy are equivalent via Einstein's equation delta E = delta m * c2;
    • the total mass of separated nucleons always exceeds the mass of the bound nucleus.
Nuclear binding energy per nucleon curve
  • Binding energy per nucleon rises steeply from hydrogen to a maximum of ~8.8 MeV per nucleon near iron-56, decreasing gradually for heavier actinides.
Energy release in fission and fusion
  • Nuclear fusion of light nuclides or fission of heavy uranium-235 produces daughter nuclei with higher binding energy per nucleon, converting mass defect into kinetic energy.
Daughter nuclei
  • The smaller nuclei produced in fission.
Mass-energy equivalence
  • The principle that mass and energy are interchangeable, E = mc2.

Section 10 of 11Key terms

TermMeaning
Mass defectThe difference between the mass of a nucleus and the sum of the individual masses of its protons and neutrons.
Binding energyThe energy required to break a nucleus into its constituent protons and neutrons.
Binding energy per nucleonThe binding energy of a nucleus divided by the number of nucleons in it.
NucleonA proton or neutron in a nucleus.
Strong nuclear forceThe short-range attractive force that binds nucleons together in a nucleus.

Section 11 of 11Exam technique

1
Using atomic mass as nuclear mass without allowing for electrons — subtract the electron masses or use hydrogen atom masses.
2
Saying binding energy is stored in the nucleus — it is the energy needed to break the nucleus apart.
3
Thinking higher total binding energy always means more stable — compare binding energy per nucleon.
4
Placing the peak of the curve at uranium — the peak is near iron-56.
5
Forgetting the neutron count A − Z when adding the separated nucleons — include all the neutrons.
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