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7.2Acids, Bases and Salts

Oxides — Combined Science 0653 - Chemistry Revision Notes & Topical Questions

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7.2 Oxides — COMBINED SCIENCE (CHEMISTRY) notes: Classify oxides as acidic or basic by metallic and non-metallic character.Oxide — = compound of oxygen with one other element.Examples are MgO, ZnO, K2O, CO2, SO2 and H2O.Classification — oxides are classified by their acid-base be…

  • Acidic oxide
  • Basic oxide
  • Neutralisation
  • Classification — oxides are classified by their acid-base behaviour
  • Formed by — a non-metal combining with oxygen
  • Reactions — they react with bases to form a salt and water

Section 1 of 11What oxides are

What oxides are
Oxide
  • = compound of oxygen with one other element.
  • Examples are MgO, ZnO, K2O, CO2, SO2 and H2O.
Classification
  • Classification oxides are classified by their acid-base behaviour.

Section 2 of 11Acidic oxides

Formed by
  • Formed by a non-metal combining with oxygen.
Reactions
  • Reactions they react with bases to form a salt and water.
In water
  • In water they give an acidic solution with a low pH.
Examples
  • CO2, SO2, NO2 and SiO2.

Section 3 of 11Basic oxides

Formed by
  • Formed by a metal combining with oxygen.
Reactions
  • Reactions they react with acids to form a salt and water.
In water
  • In water those that dissolve give a basic solution with a high pH.
Examples
  • CuO and CaO.

Section 4 of 11Metal and non-metal oxides

FeatureBasic oxideAcidic oxide
ElementMetalNon-metal
Reacts withAcidsBases
Solution pHHighLow
ExamplesCuO, CaOCO2, SO2
  • Rule
    • metals form basic oxides and non-metals form acidic oxides.

Section 5 of 11More from the specification

More from the specification
Basic oxides
  • Metallic oxides that react with acids to undergo neutralisation and form salts plus water.
    • (such as magnesium oxide)
Acidic oxides
  • Non-metallic oxides (such as SO2 and CO2) that react with alkalis or water to form acidic solutions.
Amphoteric and neutral oxides
  • Oxides like aluminium oxide react with both acids and bases;
    • neutral oxides like CO and NO show no acid-base properties.
Indicators
  • Substances like litmus or universal indicator that show distinctive colour changes according to pH scale values.
Property
  • A feature that describes what a substance is like and what it does.
Strong acid
  • An acid that is completely dissociated in water.
Carbon dioxide
  • A gas that turns limewater cloudy.
Proton transfer
  • Movement of H+ from acid to base.
Amphoteric oxide
  • An oxide that reacts with both acids and bases.
Methyl orange
  • Indicator with range about pH 3.2 to 4.4, red to yellow.
Universal indicator
  • Mixture of indicators giving a range of colours.
Concentration
  • Moles ÷ volume in dm³, or g/dm³.
Hydrogen
  • A gas that gives a squeaky pop with a lighted splint.
Alkali
  • A soluble base that produces OH− ions in water.
Neutralisation
  • The reaction of an acid with a base to form a salt and water.
Indicator
  • Substance whose colour depends on pH.
Proton
  • Positive particle in the nucleus.
Hydroxide
  • A compound containing the OH− ion, formed by Group I metals with water.
Litmus
  • Dye that is red in acid, blue in alkali and purple in neutral.

Section 6 of 11Neutral oxides

  • Neutral oxide
    • an oxide that reacts with neither acids nor bases.
    • Examples are N2O, NO and CO.
    • Water is also commonly classed as neutral.

Section 7 of 11Amphoteric oxides (supplement)

Amphoteric oxide
  • Amphoteric oxide an oxide that behaves as an acid or a base depending on the other reactant.
  • Zinc oxide and aluminium oxide are the two common examples.
  • Their hydroxides are also amphoteric.
Products
  • Products in both cases a salt and water are formed.

Section 8 of 11Aluminium oxide as a base and as an acid

RoleReactantEquation
BaseAcid (HCl)Al2O3 + 6HCl → 2AlCl3 + 3H2O
AcidAlkali (NaOH)Al2O3 + 2NaOH → 2NaAlO2 + H2O

Section 9 of 11More from the specification

More from the specification
Acidic, basic, and amphoteric oxides
  • Basic metallic oxides react with acids to form salts and water;
    • acidic non-metallic oxides dissolve in water to form acidic solutions;
    • amphoteric oxides react with both acids and bases.
Neutralisation reactions and net ionic equations
  • Mixing aqueous hydrochloric acid with basic metal oxides or hydroxides yields neutralisation: H+(aq) + OH−(aq) → H2O(l).
Reaction of magnesium oxide with acids
  • Solid magnesium oxide reacts with dilute sulfuric acid to form soluble magnesium sulfate and water: MgO(s) + H2SO4(aq) → MgSO4(aq) + H2O(l).
pH logarithmic scale
  • pH logarithmic scale every single unit decrease on the pH scale represents a tenfold increase in aqueous hydrogen ion concentration.
Strong versus weak acids
  • Strong versus weak acids hydrochloric acid dissociates fully in aqueous solution, whereas weak acids dissociate partially at identical molarity.
Acid-base neutralisation
  • Acid-base neutralisation hydrogen ions react with hydroxide ions to form neutral water molecules, detectable by universal indicator colour changes.
Property
  • A feature that describes what a substance is like and what it does.
Strong acid
  • An acid that is completely dissociated in water.
Carbon dioxide
  • A gas that turns limewater cloudy.
Proton transfer
  • Movement of H+ from acid to base.
Methyl orange
  • Indicator with range about pH 3.2 to 4.4, red to yellow.
Universal indicator
  • Mixture of indicators giving a range of colours.
Concentration
  • Moles ÷ volume in dm³, or g/dm³.
Neutralisation
  • The reaction of an acid with a base to form a salt and water.
Indicator
  • Substance whose colour depends on pH.
Proton
  • Positive particle in the nucleus.
Litmus
  • Dye that is red in acid, blue in alkali and purple in neutral.

Section 10 of 11Key terms

TermMeaning
OxideCompound of oxygen and one other element.
Acidic oxideNon-metal oxide that reacts with bases.
Basic oxideMetal oxide that reacts with acids.
SaltProduct of an acid reacting with a base.
NeutralisationReaction of an acid with a base.
TermMeaning
Neutral oxideOxide that reacts with neither acids nor bases.
Amphoteric oxideOxide that reacts with both acids and bases.
Acidic oxideNon-metal oxide that reacts with bases.
Basic oxideMetal oxide that reacts with acids.
HydroxideCompound containing the OH^{-} ion.

Section 11 of 11Exam technique

1
Saying all oxides are acidic.
2
Mixing up which type of oxide reacts with acids — basic oxides react with acids.
3
Saying non-metals form basic oxides.
4
Forgetting that a salt and water are formed in both reactions.
1
Classifying aluminium oxide as acidic only — it is amphoteric.
2
Saying neutral oxides form acids with water.
3
Mixing up metal and non-metal oxide types.
4
Writing water as a product incorrectly for amphoteric reactions.

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