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10.2.1Air and the Environment

Air — Combined Science 0653 - Chemistry Revision Notes & Topical Questions

5 min read 7 parts Lesson 6 of 7 Unit quiz

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Part 1 of 5What clean, dry air contains

GasApproximate shareComment
Nitrogen, N278%The most abundant gas and very unreactive.
Oxygen, O221%Needed for respiration and combustion.
Carbon dioxide and noble gasesRemaining 1% or soOnly trace amounts of carbon dioxide, argon and other noble gases.

Part 2 of 5Pollutants from burning fuels

Carbon dioxide
  • Carbon dioxide Made by the complete combustion of carbon-containing fuels, for example CH4 + 2O2 → CO2 + 2H2O.
  • It is a greenhouse gas, so more of it increases global warming and leads to climate change.
Carbon monoxide
  • Carbon monoxide Made by incomplete combustion when the oxygen supply is limited.
  • It is toxic because it binds to haemoglobin in red blood cells and stops them carrying oxygen round the body.
Particulates (soot)
  • Particulates (soot) Tiny particles of unburnt carbon are also produced by incomplete combustion, for example CH4 + O2 → C + 2H2O.
  • Breathing them in causes respiratory problems and can contribute to cancer.

Part 3 of 5Other pollutants and where they come from

Methane
  • Methane Released by the digestion of farm animals, from rotting vegetation, and from bacteria in swamps, rice paddies and landfill sites.
  • Like carbon dioxide it is a greenhouse gas that increases global warming.
Oxides of nitrogen
  • Oxides of nitrogen Nitrogen and oxygen react together at very high temperatures, in car engines, furnaces and lightning strikes.
    • Bacteria in soil also make some.
  • They cause photochemical smog, irritate the eyes, throat and lungs, and dissolve in rain to make acid rain.
Sulfur dioxide
  • Sulfur dioxide Formed when fuels containing sulfur compounds burn: S + O2 → SO2.
    • Power stations are a major source.
  • It dissolves in rainwater to form acid rain.

Part 4 of 5Complete and incomplete combustion

Burning a hydrocarbon
Plenty of oxygen
  • Plenty of oxygen The products are carbon dioxide and water only.
Too little oxygen
  • Too little oxygen The products are carbon monoxide and water, and sometimes carbon particles as well.
Example
  • Example Incomplete combustion of octane can be written C8H18 + 10O2 → 5CO + 3CO2 + 9H2O, which is one possible balanced version.

Part 5 of 5Effects of acid rain

1Gases released
  • Gases released Sulfur dioxide and oxides of nitrogen enter the atmosphere.
2Dissolve in rain
  • Dissolve in rain They react with water droplets to give acidic rainwater.
3Damage on the ground
  • Damage on the ground Metal structures corrode and limestone buildings and statues are eaten away because carbonates react with acid.
4Damage to life
  • Damage to life Aquatic organisms are harmed and crops and water supplies become polluted.

Key terms

TermMeaning
Air pollutantA gas or particle in the atmosphere, usually from human activity, that harms health or the environment.
Complete combustionBurning in plenty of oxygen to produce carbon dioxide and water.
Incomplete combustionBurning in limited oxygen, producing carbon monoxide and sometimes soot.
ParticulatesTiny solid particles, such as carbon soot, suspended in the air.
Acid rainRain made acidic by dissolved sulfur dioxide and oxides of nitrogen.
Greenhouse gasA gas such as carbon dioxide or methane that traps heat in the atmosphere.

Avoid these mistakes

1
Saying air is 80% oxygen or that carbon dioxide is a major component. Clean dry air is about 78% nitrogen and 21% oxygen.
2
Stating that carbon monoxide is made by complete combustion. It forms only when the oxygen supply is limited.
3
Writing that carbon monoxide 'stops you breathing'. It binds to haemoglobin so blood cannot carry oxygen.
4
Linking carbon dioxide to acid rain. Acid rain is caused by sulfur dioxide and oxides of nitrogen, whereas carbon dioxide causes global warming.
5
Saying oxides of nitrogen come from nitrogen in fuel. They form when nitrogen and oxygen from the air react at high temperature.

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