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2.2.2Inorganic Chemistry: Part 1

Acids, Alkalis and Neutralisation

5 min read 6 parts Lesson 9 of 20 1 quiz

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Section 1 of 6Acids, alkalis and the pH scale

Acids, alkalis and the pH scale
Acids
Acids substances that dissolve in water to produce hydrogen ions, H+(aq). (pH less than 7).
Bases
Bases substances that neutralise acids to form a salt and water (metal oxides and metal hydroxides).
Alkalis
Alkalis soluble bases that dissolve in water to produce hydroxide ions, OH-(aq). (pH greater than 7).
Indicators and pH
  • Universal Indicatorred (strong acid), yellow/green (weak acid), green (neutral, pH 7), blue (weak alkali), purple (strong alkali).
  • Litmusred in acid, blue in alkali.
  • Methyl orangered in acid, yellow in alkali.
  • Phenolphthaleincolourless in acid, bright pink in alkali.
Neutralisation ionic equation

H+(aq) + OH-(aq) → H2O(l)

Section 2 of 6Reactions of acids

ReactantsProductsExample Equation
Acid + MetalSalt + HydrogenMg + 2HCl → MgCl2 + H2
Acid + Metal OxideSalt + WaterCuO + H2SO4 → CuSO4 + H2O
Acid + Metal HydroxideSalt + WaterNaOH + HCl → NaCl + H2O
Acid + Metal CarbonateSalt + Water + Carbon DioxideCaCO3 + 2HCl → CaCl2 + H2O + CO2

Section 3 of 6Strong vs weak acids

Strong vs weak acids
Strong acids
Strong acids fully dissociate/ionise in aqueous solution:

HCl(aq) → H+(aq) + Cl-(aq)

Examples: hydrochloric acid (HCl), sulfuric acid (H2SO4), nitric acid (HNO3).
Weak acids
Weak acids only partially dissociate/ionise in aqueous solution (reversible reaction at equilibrium):

CH3COOH(aq) ⇌ CH3COO-(aq) + H+(aq)

Examples: ethanoic acid, citric acid, carbonic acid.
Strength vs concentration
  • Strength refers to the degree of ionisation of acid molecules in water.
  • Concentration refers to the amount of acid dissolved in a given volume of solution (mol dm-3 or g dm-3).

Section 4 of 6Key terms

TermMeaning
AcidA substance that releases H+ ions when dissolved in water.
AlkaliA soluble base that releases OH- ions in water.
NeutralisationThe reaction between H+ and OH- ions to produce neutral water (H2O).
Strong acidAn acid that completely dissociates into ions in aqueous solution.
Weak acidAn acid that only partially dissociates into ions in aqueous solution.

Section 5 of 6Syllabus checklist

  • Preparation of copper sulfate crystals from copper(II) oxide and sulfuric acid:
    • 1. Warm sulfuric acid gently in a beaker over a water bath.
    • 2.
      • Add insoluble copper(II) oxide powder in excess, stirring until no more dissolves (ensures all acid is neutralised).
    • 3. Filter the warm mixture to remove the unreacted excess black copper oxide residue.
    • 4. Heat the clear blue filtrate in an evaporating basin until the crystallisation point is reached.
    • 5. Leave to cool slowly, filter the crystals, and pat dry with filter paper.

Section 6 of 6Exam technique

Avoid these mistakes
Confusing strong and concentrated — a strong acid fully ionises regardless of concentration; a concentrated acid simply contains many moles per unit volume.
Heating copper sulfate crystals to complete dryness — this produces anhydrous white powder instead of hydrated blue crystals; always crystallise by cooling.
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