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1gPrinciples of Chemistry

Covalent bonding — Edexcel Linear - OL (Chemistry) Revision Notes & Topical Questions

5 min read 11 parts Lesson 9 of 25 1 quiz

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Curriculum Equation Key قوانين الرقم الهيدروجيني والاتزان الأيوني - pH & Acid-Base Equilibrium FormulasFast Exam Solution
pH = -log[H⁺] | pOH = -log[OH⁻] | pH + pOH = 14 | [H⁺][OH⁻] = 10⁻¹⁴
Word Equation & Conditions: الرقم الهيدروجيني = -لوغاريتم تركيز أيون الهيدروجين | pH + pOH = 14
Location & Specifications: الاتزان الأيوني، كيمياء 3 ثانوي، التحصيلي، و AP Chemistry.
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Lesson summary

Covalent bonding Edexcel O Level Linear Chemistry notes: know that a covalent bond is formed between atoms by the sharing of a pair of electronsEach lone pair reduces bond angle by about 2.5°.Hydrogen bonding explains high bp of water and low density of ice.σ bonds form by head-o…

  • Covalent bonding Edexcel O Level Linear Chemistry: what to do next
  • Ionic bond
  • Dative bond
  • Metallic bond
  • Electronegativity
  • van der Waals (id–id)

Section 1 of 11Process & sequence

Structure types
Giant ionic NaCl – high mp, conducts molten
Simple molecular I₂ – low mp
Giant covalent diamond, SiO₂ – very high mp
Giant metallic Cu – conducts, malleable
  • Lone pair–lone pair
  • >
  • lone pair–bond pair
  • >
  • bond pair–bond pair

Section 2 of 11Keep going

Covalent bonding Edexcel O Level Linear Chemistry: what to do next

These Covalent bonding Edexcel O Level Linear Chemistry notes covered the key ideas, worked examples and exam technique for this topic. Check your Covalent bonding Edexcel O Level Linear Chemistry understanding with the practice questions below, then reread any Covalent bonding Edexcel O Level Linear Chemistry point you were unsure about before moving on.

Covalent bonding Edexcel O Level Linear Chemistry revision notes

Section 3 of 11Giant covalent structures

Giant covalent structures
Giant covalent structures
Diamond and graphite are forms of carbon with giant covalent structures. They contain networks of atoms held by many strong covalent bonds, not separate carbon molecules.
Both have high melting points because many strong covalent bonds must be broken to melt their structures. Breaking those bonds requires a large energy input.

Section 4 of 11Diamond

Four covalent bonds
In diamond, every carbon atom forms four covalent bonds to other carbon atoms in a three-dimensional network. The network resists scratching, making diamond very hard.
Diamond does not conduct electricity because its outer electrons are used in bonds and there are no mobile charged particles to carry current. A hard material can still be brittle: a sufficiently strong impact can fracture diamond.

Section 5 of 11Graphite

Three covalent bonds
In graphite, each carbon atom forms three covalent bonds within a flat layer of hexagons. The layers are held together by weak forces, so they can slide over one another. This makes graphite soft and slippery.
Delocalised
One electron from each carbon atom is delocalised and can move within the layers. These mobile electrons allow graphite to conduct electricity and help transfer heat.

Section 6 of 11Compare and explain

To explain a property, name the structural feature responsible: diamond's four-bond network gives hardness; graphite's weak forces between layers allow sliding; graphite's delocalised electrons enable conduction; strong covalent bonds give both high melting points.
Check:
Check Why is graphite a conductor but diamond is not? Answer: Graphite has mobile delocalised electrons, whereas diamond has no mobile charged particles.

Section 7 of 11Compare

Shapes of molecules (VSEPR)
Bonding pairsLone pairsShapeBond angleExamplePolar?
20Linear180°CO₂No
30Trigonal planar120°BF₃No
40Tetrahedral109.5°CH₄No
31Pyramidal107°NH₃Yes
22Non-linear (bent)104.5°H₂OYes
60Octahedral90°SF₆No

Section 8 of 11Key terms

Section 9 of 11Syllabus checklist

1
know that a covalent bond is formed between atoms by the sharing of a pair of electrons
2
understand covalent bonds in terms of electrostatic attractions
3
understand how to use dot-and-cross diagrams to represent covalent bonds in
  • - diatomic molecules
  • including hydrogen, oxygen
  • nitrogen
  • halogens and hydrogen halides - inorganic molecules including water
  • ammonia and carbon dioxide - organic molecules containing up to two carbon atoms
  • including methane, ethane
  • ethene and those containing halogen atoms
4
explain why substances with a simple molecular structures are gases or liquids, or solids with low melting and boiling points the term intermolecular forces of attraction can be used to represent all forces between molecules
5
explain why the melting and boiling points of substances with simple molecular structures increase, in general, with increasing relative molecular mass
6
explain why substances with giant covalent structures are solids with high melting and boiling points
7
explain how the structures of diamond, graphite and C60 fullerene influence their physical properties, including electrical conductivity and hardness
8
know that covalent compounds do not usually conduct electricity

Section 10 of 11Command terms

Command terms
Give / State / Name
Recall a fact; one idea per mark.
Define
Give the exact meaning using the specification keywords.
Describe
Give an account of what happens / the pattern in data, quoting values; no reasons needed.
Explain
Give reasons with linked statements (cause → effect). Each linked step is usually a separate marking point.
Suggest
Use knowledge in a new context; more than one answer may be accepted.
Compare
Similarities and differences; each point must refer to both items.
Calculate
Show working; include units; check significant figures. Method marks are given even if the final answer is wrong.
Discuss
Explore the issue from different angles and link the points.
Evaluate / Assess
Weigh strengths and weaknesses and reach a supported judgement.
Deduce
Draw a conclusion from the information given.
Justify
Support a statement/choice with evidence.

Section 11 of 11Exam technique

Keywords the mark scheme looks for in this lesson

Keywords the mark scheme looks for in this lesson
Ionic bond · Covalent bond · Dative bond · Metallic bond · Electronegativity · VSEPR · Hydrogen bond · van der Waals (id–id)
Learn each definition in the Key words tab exactly; a missing keyword in a definition usually loses the mark.

How to get full marks (examiner guidance)

How to get full marks (examiner guidance)
Use specification keywords exactly (e.g. electronegativity, nucleophile, dynamic equilibrium, activation energy).
Link ideas
Link ideas for “explain” each marking point is usually a cause → consequence step; unlinked facts often score nothing.
Use the information in the question
“discuss/evaluate” answers must use the data provided and match the number of marks.
Convert units carefully (mg → g, cm³ → dm³) and show working for calculations.
Avoid vague words
“it”, “stuff”, “things”, “goes up”, “energy is made”. Name the substance and the process.
Do not extrapolate a graph line beyond the data or to zero unless asked.
Six-mark extended responses are marked on content AND a logical, linked line of reasoning.

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