3cPhysical Chemistry
Reversible reactions and equilibria — Edexcel Modular - OL (Chemistry) Revision Notes & Topical Questions
5 min read 7 parts Lesson 3 of 3 2 quizzes
Reversible reactions and equilibria Edexcel O Level Modular Chemistry notes: know that some reactions are reversible and this is indicated by the symbol in equationsOnly temperature changes the value of Kc.Contact process2SO₂ + O₂ ⇌ 2SO₃, V₂O₅ catalyst, 450 °C, 1–2 atm.Strong aci…
- Reversible reactions and equilibria Edexcel O Level Modular Chemistry: what to do next
- Dynamic equilibrium
- Closed system
- Le Chatelier principle
- Bronsted–Lowry acid
- Bronsted–Lowry base
Section 1 of 7Process & sequence
Section 2 of 7Keep going
Reversible reactions and equilibria Edexcel O Level Modular Chemistry: what to do next
These Reversible reactions and equilibria Edexcel O Level Modular Chemistry notes covered the key ideas, worked examples and exam technique for this topic. Check your Reversible reactions and equilibria Edexcel O Level Modular Chemistry understanding with the practice questions below, then reread any Reversible reactions and equilibria Edexcel O Level Modular Chemistry point you were unsure about before moving on.
Section 3 of 7Compare
| Change | Shift | Effect on Kc | Reason | Haber process example (ΔH −92) | Industrial compromise |
|---|---|---|---|---|---|
| More reactant | Right | None | Uses up added reactant | More NH₃ | — |
| Higher pressure | To fewer gas moles | None | Reduces pressure | Right (4 mol → 2 mol) | About 200 atm – cost and safety |
| Higher temperature | Endothermic direction | Changes | Absorbs heat | Left – less NH₃ | About 450 °C – rate vs yield |
| Lower temperature | Exothermic direction | Changes | Releases heat | Right – more NH₃ but slow | — |
| Catalyst | No shift | None | Speeds both directions equally | Iron catalyst | Equilibrium reached faster |
Section 4 of 7Key terms
Section 5 of 7Syllabus checklist
- the forward and reverse reactions occur at the same rate
- the concentrations of reactants and products remain constant
- an increase (or decrease) in temperature shifts the position of equilibrium in the direction of the endothermic (or exothermic) reaction
- an increase (or decrease) in pressure shifts the position of equilibrium in the direction that produces fewer (or more) moles of gas
Section 6 of 7Command terms
Section 7 of 7Exam technique
Keywords the mark scheme looks for in this lesson
How to get full marks (examiner guidance)
Marked practiceQuizzes for this lesson
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