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R1.3Reactivity 1 — What drives chemical reactions?

Energy from fuels — IB Chemistry SL Revision Notes & Topical Questions

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R1.3 Energy from fuels — IB CHEMISTRY SL notes: Write equations for complete and incomplete combustion, evaluate fossil fuels and biofuels, link CO2 to climate, calculate specific energy and describe fuel cells.Combustion — a rapid, exothermic oxidation of a fuel that needs oxyge…

  • Non-metals
  • Organic fuels
  • Conditions
  • Hydrocarbons
  • Carbon monoxide
  • Carbon content

Section 1 of 33Combustion reactions

Combustion
  • Combustion a rapid, exothermic oxidation of a fuel that needs oxygen and an ignition source, giving heat and light.
Metals
  • Metals all metals oxidise, but only reactive or finely divided ones combust, e.g. 2Mg + O2 → 2MgO;
    • copper only forms black CuO on heating.
Non-metals
  • Non-metals form covalent, usually acidic oxides, e.g. S + O2 → SO2 and P4 + 5O2 → P4O10.
Redox
  • Redox the fuel is oxidised and oxygen is reduced.
Organic fuels
  • Organic fuels hydrocarbons and alcohols are used because they release much energy,
    • and their high activation energy makes them safe to store and transport.

Section 2 of 33Complete combustion

Conditions
  • Conditions a plentiful supply of oxygen, giving CO2 and H2O.
Hydrocarbons
CxHy + (x + y/4)O2 → xCO2 + (y/2)H2O, e.g. CH4 + 2O2 → CO2 + 2H2O.
Alcohols
  • Alcohols e.g. C2H5OH + 3O2 → 2CO2 + 3H2O, where the oxygen in the alcohol must be counted.
Balancing
  • Balancing balance carbon, then hydrogen, then supply the product oxygen from O2, using fractions and doubling if needed.
Flame
  • Flame a Bunsen burner gives a blue, non-luminous flame.

Section 3 of 33Incomplete combustion

Conditions
  • Conditions limited oxygen, common in car engines and faulty boilers, giving a yellow, luminous flame.
Products
  • Products water plus carbon monoxide and/or carbon (soot), and it releases less energy per mole than complete combustion.
Carbon monoxide
  • Carbon monoxide colourless, odourless and toxic because it binds irreversibly to haemoglobin and prevents oxygen transport, e.g. C3H8 + 3.5O2 → 3CO + 4H2O.
Soot
  • C3H8 + 2O2 → 3C + 4H2O, causing respiratory problems and global dimming.
Hydrogen
  • Hydrogen is never a product because it is preferentially oxidised to water.
Carbon content
  • Carbon content compounds with a higher percentage of carbon, such as benzene derivatives, burn with sootier flames.
Alcohols
  • Alcohols burn more cleanly than hydrocarbons because they already contain oxygen.

Section 4 of 33Fossil fuels

  • Origin
    • coal, oil and natural gas formed over millions of years from dead organisms, so they are non-renewable and finite.
FuelAdvantagesDisadvantages
CoalCheap, widely available, long-lasting, safe to storeMost CO2 per unit energy, SO2 and particulates, mining damage
OilHigh energy density, easily transported and refined by fractional distillation and crackingCO2, SO2, CO and smog, oil spills, uneven distribution
Natural gasCheapest, high specific energy, burns cleanly with least CO2Hard and costly to store under pressure, leaks of methane
  • Chain length
    • as hydrocarbon chains lengthen, more CO2 and less energy per gram are released,
      • and incomplete combustion is more likely; methane releases the most energy per gram.

Section 5 of 33Specific energy and enthalpy of combustion

Heat energy
Heat energy q = mcΔT, with c = 4.18 J g−1 K−1 for water.
What the symbols mean: E, Q or q = energy transferred (J) · m = mass (kg; g in chemistry calorimetry) · c = specific heat capacity (J kg−1 °C−1; water 4.18 J g−1 °C−1) · ΔT or Δθ = temperature change (°C or K)
Enthalpy of combustion
ΔHc = −q/n(fuel), in kJ mol−1.
Specific energy
Specific energy the energy released per unit mass of fuel, equal to |ΔHc| divided by molar mass in kg mol−1 (kJ kg−1).
Energy density
Energy density the energy released per unit volume of fuel (kJ dm−3), equal to specific energy × density.
Experimental method
  • Experimental method burn a fuel in a spirit burner under a copper calorimeter of water and find the fuel mass lost.
Low experimental value
  • Low experimental value the result is less exothermic than the data-booklet value because of heat loss, incomplete combustion, fuel evaporation and heat absorbed by the calorimeter.
Alcohols
  • Alcohols release less energy per gram than hydrocarbons because they are partly oxidised, so ethanol has lower specific energy than octane.

Section 6 of 33Carbon dioxide and the greenhouse effect

Carbon dioxide and the greenhouse effect
Sources
  • Sources burning fossil fuels, deforestation, livestock (methane) and decomposition of carbonates.
    • (especially for electricity)
Greenhouse gases
  • CO2, CH4, N2O/NOx and water vapour.
Mechanism
  • Mechanism short-wavelength radiation from the Sun reaches the Earth,
  • which re-emits longer-wavelength infrared, and greenhouse gases absorb it because their bond vibrations change the dipole moment.
Re-radiation
  • Re-radiation the gases re-emit the energy in all directions, trapping heat.
Enhanced greenhouse effect
  • Enhanced greenhouse effect extra warming from human-made increases in greenhouse gas concentrations, causing global warming and climate change.
Oceans
  • Oceans dissolved CO2 forms carbonic acid, causing ocean acidification.
Monitoring
  • Mauna Loa records CO2 since 1958, with seasonal fluctuations caused by photosynthesis.

Section 7 of 33Biofuels

Renewable resources
  • Renewable resources replaced as fast as or faster than they are used; non-renewable ones are finite.
Bioethanol
  • Bioethanol glucose from photosynthesis is fermented anaerobically by yeast, C6H12O6 → 2C2H5OH + 2CO2.
Biodiesel
  • Biodiesel triglycerides react with methanol by transesterification, usually with an alkali catalyst, to give methyl esters;
    • excess methanol shifts the equilibrium.
Biogas
  • Biogas anaerobic breakdown of organic waste gives mostly CH4 and CO2.
Carbon neutrality
  • CO2 absorbed in growth equals that released on burning, but energy used in farming, transport and processing adds CO2.
AdvantagesDisadvantages
Renewable and close to carbon neutralLand used instead of food crops and deforestation
Can be made from organic waste, reducing landfillFertiliser and pesticide use and soil depletion
Create jobs and incomeLower specific energy than fossil fuels and costly engine conversion

Section 8 of 33Fuel cells

Definition
Definition an electrochemical cell that converts the chemical energy of a continuously supplied fuel and oxidant directly into electrical energy.
Operation
  • Operation the cell runs while fuel and oxygen are supplied, with no recharging, and energy is not stored in the cell.
Efficiency
  • Efficiency higher than combustion engines because chemical energy becomes electrical energy without passing through heat.
CellAnodeCathode
Hydrogen, acidic (PEM)H2 → 2H+ + 2e−O2 + 4H+ + 4e− → 2H2O
Hydrogen, alkalineH2 + 2OH− → 2H2O + 2e−O2 + 2H2O + 4e− → 4OH−
Methanol (PEM)CH3OH + H2O → CO2 + 6H+ + 6e−O2 + 4H+ + 4e− → 2H2O
1Overall
  • Overall hydrogen cell 2H2 + O2 → 2H2O (E = +1.23 V) and methanol cell 2CH3OH + 3O2 → 2CO2 + 4H2O.
2Hydrogen cell advantages
  • Hydrogen cell advantages water is the only product, no NOx, quiet with no moving parts.
3Hydrogen cell disadvantages
  • Hydrogen cell disadvantages expensive platinum catalyst, flammable and hard-to-store hydrogen with low energy density by volume,
    • and mostly made from fossil fuels.
4Methanol cell versus hydrogen
  • Methanol cell versus hydrogen easier to store, higher energy density by volume and can come from biomass,
    • but toxic, flammable, lower power and it produces CO2.

Section 9 of 33More from the specification

Carbon dioxide
  • A gas that turns limewater cloudy.
Chemical formula
  • Symbols and numbers showing the relative number of atoms of each element.

Section 10 of 33Combustion and reactivity with oxygen

Combustion
  • Combustion a type of oxidation in which a substance reacts with oxygen and releases energy.
Non-metals
  • Non-metals form non-metal oxides, e.g. sulfur + oxygen → sulfur dioxide.
Complete combustion
  • Complete combustion hydrocarbons and alcohols burning in plenty of oxygen give carbon dioxide and water.
Hydrocarbon pattern
CxHy + (x + y/4)O2 → xCO2 + (y/2)H2O.
Incomplete combustion
  • Incomplete combustion limited oxygen gives carbon monoxide and/or carbon (soot) with water and a smaller energy release.
Carbon monoxide
  • Carbon monoxide is a toxic gas.

Section 11 of 33Balancing combustion equations

Balancing combustion equations
Balance carbon first, using one CO2 for each carbon.
Balance hydrogen next, using one H2O for each two hydrogens.
Count the oxygen atoms on the product side and supply them from O2, using fractions and then doubling for whole numbers.
Butane
  • C4H10 + 6.5O2 → 4CO2 + 5H2O, or 2C4H10 + 13O2 → 8CO2 + 10H2O.
Ethanol
  • C2H5OH + 3O2 → 2CO2 + 3H2O, because the oxygen already in the alcohol counts.

Section 12 of 33Calculating the mass of carbon dioxide produced

What the symbols mean:
Calculate the moles of fuel, n = m/M.
What the symbols mean: n = amount of substance (mol) · m = mass (g) · M or Mr = molar mass (g mol−1, numerically equal to Mr)
Use the mole ratio from the balanced equation, e.g. 1 C4H10 : 4 CO2.
Multiply the moles of CO2 by its molar mass, 12.01 + 2 × 16.00 = 44.01 g mol−1.
Mole ratio
  • Mole ratio use the mole ratio, not the mass ratio.
Mass relationship
  • Mass relationship the mass of CO2 formed exceeds the mass of fuel because oxygen from the air is added to the carbon, about 3 g of CO2 per gram of a hydrocarbon such as butane.
Carbon content
  • Carbon content a fuel with a higher proportion of carbon produces more CO2 per kilogram.

Section 13 of 33Using the energy released

Energy released
Energy released n × |ΔHc|.
Fair comparison
  • Fair comparison compare energy per gram, per mole and CO2 per kilojoule on the same basis.
Methane
  • Methane has the lowest CO2 per unit energy among hydrocarbons because it has the highest hydrogen-to-carbon ratio.

Section 14 of 33Combustion of alcohols

Fuel use
  • Fuel use alcohols are used as fuels as well as hydrocarbons.
Enthalpy trend
  • Enthalpy trend the enthalpy of combustion rises with chain length by roughly 650 kJ mol−1 for each extra CH2 unit,
    • because more bonds form in the products.
Energy per gram
  • Energy per gram alcohols release less energy per gram than hydrocarbons because they already contain oxygen.

Section 15 of 33Carbon dioxide and the greenhouse effect link

Greenhouse gas
  • CO2 from combustion contributes to the greenhouse effect.
Sources
  • Sources electricity generation accounts for a large part of fossil fuel use.
Trend
  • Trend atmospheric CO2 has risen steadily, with seasonal ups and downs caused by photosynthesis in the northern hemisphere.
Removal
  • Removal photosynthesis removes CO2 from the air and the oceans dissolve some, forming carbonic acid.

Section 16 of 33More from the specification

More from the specification
Combustion of Hydrocarbon Fuels
  • Complete combustion of organic hydrocarbon fuels like propane produces carbon dioxide and water vapour with a clean blue flame, releasing large quantities of heat.
    • (C₃H₈ + 5O₂ → 3CO₂ + 4H₂O)
Principles of Fuel Cells
  • A fuel cell is an electrochemical cell that converts chemical energy from a fuel directly into electrical energy via redox reactions without combustion;
    • in a hydrogen-oxygen fuel cell, water is the sole chemical product.
Renewable vs Non-Renewable Resources
  • Fossil fuels are finite non-renewable resources that deplete over time, driving the global transition toward renewable solar, wind,
    • (coal, crude oil, natural gas)
  • and biofuel resources.
Atmospheric Carbon Dioxide and Global Warming
  • Burning fossil fuels elevates carbon dioxide levels in the global atmosphere, enhancing the greenhouse effect and accelerating anthropogenic climate change.
Chemical formula
  • Symbols and numbers showing the relative number of atoms of each element.
Specific energy
  • The energy released per unit mass of fuel.
Renewable
  • Can be replaced as quickly as it is used
Compound
  • Two or more elements chemically combined in a fixed ratio.
Non-renewable
  • Cannot be replaced in a human lifetime
Energy density
  • Energy released per unit mass or volume
Global warming
  • Rise in the Earth's average temperature caused by extra greenhouse gases.

Section 17 of 33Carbon dioxide formed by burning a fuel

Source of the amount
  • Source of the amount the balanced equation gives the moles of CO2 from the moles of fuel.
Butane
  • C4H10 + 6.5O2 → 4CO2 + 5H2O, so one mole of fuel gives four moles of CO2.
Carbon dioxide formed by burning a fuel
Convert the mass of fuel to moles.
Use the 1 : 4 ratio to find the moles of CO2.
Multiply by 44.01 g mol−1 to get the mass.

Section 18 of 33Rising carbon dioxide and its sources

Trend
  • Trend atmospheric CO2 has increased steadily because of human activity.
Main source
  • Main source burning fossil fuels for electricity, transport and industry.
Other sources
  • Other sources deforestation, livestock and cement production.
    • (which also release methane)
Seasonal fluctuation
  • Seasonal fluctuation an annual cycle is superimposed on the rise because plants take in more CO2 in the growing season.
Carbonate sources
  • CO2 is released when carbonate rocks are heated (CaCO3 → CaO + CO2) and when acids react with carbonates to give a salt, water and CO2.
Other natural sources
  • Other natural sources respiration of plants and animals.

Section 19 of 33Greenhouse gases

Carbon dioxide
  • Carbon dioxide from respiration and burning fuels.
Methane
  • Methane from livestock, landfills and mining.
Nitrogen oxides
  • Nitrogen oxides from impurities in fossil fuels and high-temperature combustion.
Water vapour
  • Water vapour from combustion and evaporation.
Importance
  • Importance without the natural greenhouse effect Earth's temperature would swing widely, as on Mars.
    • (20 °C to −153 °C)

Section 20 of 33Mechanism of the greenhouse effect

1
The Sun emits mostly short-wavelength radiation (visible and ultraviolet) that passes through the atmosphere.
2
The Earth's surface absorbs it and re-emits longer-wavelength infrared radiation.
3
Greenhouse gases absorb part of this infrared radiation.
4
They re-emit the energy in all directions, so some returns to the surface and the lower atmosphere warms.
1Why gases absorb
  • Why gases absorb molecules absorb infrared when their bond vibrations change the dipole moment, so CO2 and CH4 absorb but N2 and O2 do not.
2Enhanced greenhouse effect
  • Enhanced greenhouse effect the extra warming caused by human-made increases in greenhouse gas concentrations.

Section 21 of 33Effects and responses

Climate
  • Climate a rise in global mean temperature, melting ice and rising sea levels.
Oceans
  • Oceans dissolved CO2 forms carbonic acid, lowering pH and harming organisms with calcium carbonate shells.
Reduction strategies
  • Reduction strategies greater efficiency, renewable energy, carbon capture and storage, and replacing fossil fuels with biofuels or hydrogen.
Evaluation
  • Evaluation compare CO2 emitted per kilojoule delivered and consider the whole life cycle, including production and transport.

Section 22 of 33Structuring answers on CO<sub>2</sub> and climate

Chain of reasoning
  • Chain of reasoning source of the gas, property that makes it a greenhouse gas, absorption and re-emission of infrared, then the consequence.
Solutions
  • Solutions name the strategy, say how it reduces net CO2 and state one limitation such as cost or land use.
Quantitative pattern
  • Quantitative pattern moles of fuel, moles of CO2 from the equation ratio, then mass or volume, showing the molar masses used.

Section 23 of 33More from the specification

1Coordination chemistry of d-block metals
  • Coordination chemistry of d-block metals vacant d-orbitals in transition metals accept lone pairs from neutral or anionic ligands to form coordination complexes.
2Complete Combustion of Hydrocarbons
  • Hydrocarbon fuels such as propane (C3H8) undergo complete combustion in an excess supply of oxygen,
  • producing carbon dioxide and water while burning with a clean blue flame: C3H8 + 5 O2 → 3 CO2 + 4 H2O.
3Incomplete Combustion and Carbon Monoxide Toxicity
  • In a limited supply of oxygen, hydrocarbons undergo incomplete combustion to yield soot (carbon) and toxic carbon monoxide (CO),
  • which binds irreversibly to haemoglobin and prevents oxygen transport in the blood.
4Fuel Cells vs. Direct Combustion
  • Electrochemical fuel cells combine fuels like hydrogen or small organic molecules directly with oxygen to produce electricity with high efficiency, avoiding thermal losses and noxious emissions associated with burning fossil resources.
5Transition Away from Fossil Resources
  • Fossil hydrocarbons are non-renewable energy resources, driving the development of renewable alternatives such as biofuels and metal-catalyzed catalytic fuel cells.
6Energy density
  • Energy released per unit mass or volume
7Chemical formula
  • Symbols and numbers showing the relative number of atoms of each element.
8Specific energy
  • The energy released per unit mass of fuel.
9Oxygen
  • A gas that relights a glowing splint.
10Metal
  • An element with a lattice of positive ions in a sea of delocalised electrons, usually shiny, conductive and malleable.
11Hydrocarbon
  • A compound containing hydrogen and carbon only.
12Compound
  • Two or more elements chemically combined in a fixed ratio.
13Non-renewable
  • Cannot be replaced in a human lifetime
14Complete combustion
  • Burning in plenty of oxygen to give carbon dioxide and water.
15Incomplete combustion
  • Burning in limited oxygen to give CO, soot and water.
16Carbon monoxide
  • A toxic gas that binds to haemoglobin.

Section 24 of 33Renewable and non-renewable resources

Renewable
  • Renewable replaced as quickly as or faster than used, such as wood, bioethanol, wind and solar energy.
Non-renewable
  • Non-renewable finite on a human time scale;
    • coal, crude oil and natural gas formed from organisms over millions of years.
Sustainable
  • Sustainable meets present needs without compromising future generations.
Fossil fuels
  • Fossil fuels have a high energy density and are easy to transport and burn, but release CO2, SO2 and oxides of nitrogen.
    • (from sulfur impurities)
Reasons for biofuels
  • Reasons for biofuels to cut pollution, reduce global warming and replace depleting fossil fuels.

Section 25 of 33Bioethanol

Production
  • Production yeast ferments plant sugars in the absence of oxygen: C6H12O6 → 2C2H5OH + 2CO2.
Separation
  • Separation ethanol is separated by fractional distillation.
Source of glucose
  • Source of glucose green plants make glucose by photosynthesis, 6CO2 + 6H2O → C6H12O6 + 6O2.
Use
  • Use can be blended with petrol.
Fermentation
  • Fermentation is anaerobic.

Section 26 of 33Biodiesel and biogas

Biodiesel
  • Biodiesel a vegetable oil or animal fat (triglyceride) reacts with methanol by transesterification with a strong base catalyst to form fatty acid methyl esters and glycerol.
    • (propane-1,2,3-triol)
Transesterification
  • Transesterification the reaction is reversible, so excess methanol is used and yields can reach 98%.
Biogas
  • Biogas organic waste broken down by microorganisms without oxygen gives mainly methane and CO2.
Composition
  • Composition glucose gives biogas with 50% methane, C6H12O6 → 3CO2 + 3CH4.
Advantages of biofuelsDisadvantages of biofuels
Renewable; made from crops that absorb CO2Land and water used instead of for food
Close to carbon neutral overallFertiliser and processing use energy and release greenhouse gases
Usable in existing engines as blendsLower energy density than petrol or diesel
  • Carbon neutrality
    • biofuels are not always carbon neutral because of farming, processing and transport.

Section 27 of 33Specific energy and energy density

Specific energy
  • Specific energy the energy released per unit mass (kJ g−1), found by dividing |ΔHc| by molar mass.
Energy density
  • Energy density the energy released per unit volume (kJ dm−3).
Ethanol versus octane
  • Ethanol versus octane ethanol is about 29.7 kJ g−1 (1367 ÷ 46.07) and octane about 47.9 kJ g−1 (5470 ÷ 114.2).
Oxygenated fuels
  • Oxygenated fuels alcohols release less energy per gram because they are already partly oxidised.
Hydrogen
  • Hydrogen has very high specific energy (about 120 kJ g−1) but very low energy density as a gas, which makes storage difficult.

Section 28 of 33Fuel cells as an alternative

1Operation
  • Operation hydrogen is oxidised at one electrode and oxygen reduced at the other.
2Continuous running
  • Continuous running the cell works while fuel and oxygen are supplied, and energy is not stored in it.
3Electron flow
  • Electron flow electrons pass through the external circuit, and the only product is water.
4Efficiency
  • Efficiency chemical energy converts directly to electrical energy, which is more efficient than burning fuel to drive a heat engine.
5Limitation
  • Limitation the production, storage and distribution of hydrogen.

Section 29 of 33Comparing fuels

FuelAdvantagesDisadvantages
CoalLarge reserves, cheap, easily storedMost CO2 per unit energy, SO2, particulates, non-renewable
Crude oil productsHigh energy density, easily transported, many usesNon-renewable, CO2, CO and NOx, spills
Natural gasBurns cleanly, least CO2 per unit energy of fossil fuelsNon-renewable, methane leaks, hard to store
BiofuelsRenewable, closer to carbon neutralFarmland and water use, lower specific energy
HydrogenOnly product is water, very high specific energyLow energy density as gas, mostly made from fossil fuels

Section 30 of 33Deciding which fuel is best

Criteria
  • Criteria energy per gram, energy per unit volume for storage, CO2 per kilojoule, availability and cost, and other products such as SO2.
No single best
  • No single best hydrogen has the highest specific energy and forms only water but needs high-pressure storage, ethanol is renewable with lower energy density,
    • and petrol is convenient but non-renewable.
Conclusion
  • Conclusion weigh the criteria against the use, such as aircraft, cars or home heating.

Section 31 of 33More from the specification

More from the specification
Complete combustion of hydrocarbons
  • In plentiful oxygen, hydrocarbons burn completely with a clean blue flame, described by stoichiometric combustion equations producing carbon dioxide (CO2) and water (H2O).
Incomplete combustion and toxic byproducts
  • Under restricted oxygen supply, hydrocarbons undergo incomplete combustion, yielding soot particulates, carbon monoxide (CO),
  • and unburnt hydrocarbons with a smoky yellow flame.
Combustion of reactive metals
  • Reactive metals ignite exothermically in oxygen to form solid basic metal oxides, represented by balanced chemical equations without producing greenhouse gases.
    • (e.g. 2Mg + O2 → 2MgO)
Environmental effect of combustion products
  • Burning fossil fuels releases massive quantities of carbon dioxide, intensifying the greenhouse effect, trapping radiated infrared energy,
  • and causing ocean acidification.
Complete combustion of hydrocarbons
  • In plentiful oxygen, hydrocarbons burn completely with a clean blue flame, described by stoichiometric combustion equations producing carbon dioxide (CO2) and water (H2O).
Incomplete combustion and toxic byproducts
  • Under restricted oxygen supply, hydrocarbons undergo incomplete combustion, yielding soot particulates, carbon monoxide (CO),
  • and unburnt hydrocarbons with a smoky yellow flame.
Combustion of reactive metals
  • Reactive metals ignite exothermically in oxygen to form solid basic metal oxides, represented by balanced chemical equations without producing greenhouse gases.
    • (e.g. 2Mg + O2 → 2MgO)
Environmental effect of combustion products
  • Burning fossil fuels releases massive quantities of carbon dioxide, intensifying the greenhouse effect, trapping radiated infrared energy,
  • and causing ocean acidification.
Complete combustion
  • Burning in plenty of oxygen to give carbon dioxide and water.
Incomplete combustion
  • Burning in limited oxygen to give CO, soot and water.
Chemical equation
  • A statement using formulas to show reactants and products.
Greenhouse effect
  • Absorption and re-emission of thermal energy by atmospheric gases, which reduces energy lost to space.
Carbon monoxide
  • A toxic gas that binds to haemoglobin.
Chemical formula
  • Symbols and numbers showing the relative number of atoms of each element.
Combustion
  • Burning in oxygen
Metal
  • An element with a lattice of positive ions in a sea of delocalised electrons, usually shiny, conductive and malleable.
Hydrocarbon
  • A compound containing hydrogen and carbon only.
Compound
  • Two or more elements chemically combined in a fixed ratio.
Carbon dioxide
  • A gas that turns limewater cloudy.

Section 32 of 33Key terms

TermMeaning
Complete combustionCombustion in excess oxygen giving CO2 and H2O.
Incomplete combustionCombustion in limited oxygen giving CO and/or C as well as water.
Specific energyThe energy released per unit mass of fuel.
Energy densityThe energy released per unit volume of fuel.
BiofuelA fuel made from recently living biomass.
Greenhouse gasA gas that absorbs infrared radiation emitted by the Earth.
Fuel cellA cell converting the chemical energy of a continuously supplied fuel directly into electrical energy.
TermMeaning
Complete combustionCombustion in excess oxygen producing CO2 and H2O.
Incomplete combustionCombustion in limited oxygen producing CO and/or C.
OxidationReaction with oxygen.
StoichiometryThe quantitative relationships from a balanced equation.
Molar massThe mass of one mole of a substance.
TermMeaning
Greenhouse gasA gas that absorbs infrared radiation emitted by the Earth.
Enhanced greenhouse effectAdditional warming from human-made increases in greenhouse gases.
Infrared radiationLong-wavelength radiation emitted by warm surfaces.
Thermal decompositionThe breakdown of a compound by heating.
Carbonic acidH2CO3, formed when CO2 dissolves in water.
TermMeaning
Non-renewableA resource used faster than it forms.
BioethanolEthanol made by fermentation of plant sugars.
TransesterificationReaction of an oil with an alcohol to give esters and glycerol.
Specific energyEnergy released per unit mass of fuel.
Energy densityEnergy released per unit volume of fuel.
FermentationAnaerobic breakdown of sugar by yeast to ethanol and CO2.

Section 33 of 33Exam technique

1
Forgetting the oxygen in an alcohol when balancing — count it on the reactant side.
2
Stating hydrogen forms in incomplete combustion — hydrogen is oxidised to water first.
3
Saying biofuels are always carbon neutral — farming and processing add CO2.
4
Saying greenhouse gases trap the Sun's rays — they absorb infrared emitted by the Earth.
1
Forgetting the oxygen in the fuel when balancing alcohol combustion — count the oxygen in the alcohol too.
2
Using the mass ratio rather than the mole ratio — convert to moles first.
3
Using M(CO2) = 28 — it is 44.01 g mol−1.
4
Writing carbon dioxide for incomplete combustion — the products are CO and/or C.
1
Saying the greenhouse effect is caused by holes in the ozone layer — these are separate problems.
2
Writing that greenhouse gases trap the Sun's rays — they absorb infrared emitted by the Earth.
3
Using the mass of fuel rather than moles in the ratio — convert to moles first.
4
Ignoring the 4 : 1 mole ratio for butane — four moles of CO2 form per mole.
1
Saying biofuels are always carbon neutral — farming, processing and transport release CO2.
2
Confusing renewable with sustainable — sustainability also considers future generations.
3
Comparing energy per mole when per gram is needed — divide by molar mass.
4
Saying fermentation uses oxygen — it is anaerobic.

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