Theme E — Nuclear and Quantum Physics
E.2.2 The Photoelectric Equation — IB Physics HL Revision Notes & Topical Questions
5 min read 9 parts Lesson 12 of 45 1 quiz
Curriculum Equation Key قوانين الرقم الهيدروجيني والاتزان الأيوني - pH & Acid-Base Equilibrium FormulasFast Exam Solution
pH = -log[H⁺] | pOH = -log[OH⁻] | pH + pOH = 14 | [H⁺][OH⁻] = 10⁻¹⁴
Word Equation & Conditions: الرقم الهيدروجيني = -لوغاريتم تركيز أيون الهيدروجين | pH + pOH = 14
Location & Specifications: الاتزان الأيوني، كيمياء 3 ثانوي، التحصيلي، و AP Chemistry.
Lesson summary
E.2.2 The Photoelectric Equation — IB PHYSICS HL notes: Use hf = Φ + Ek,max, the threshold condition and the Ek,max against f graph.Photon energy — E = hf, so energy is directly proportional to frequencyWhat the symbols mean: E = energy of one photon (J) · h = Planck constant (6.…
- Energy division
- Below threshold
- At threshold
- Above threshold
- Alternative form
- Maximum speed
Part 1 of 7Einstein's equation
Photon energy
- E = hf,
- so energy is directly proportional to frequencyWhat the symbols mean: E = energy of one photon (J) · h = Planck constant (6.63 × 10−34 J s) · f = frequency (Hz)
Energy division
- Energy division an energy Φ liberates the electron and the rest becomes kinetic energy
Equation
- Equation hf = Φ + Ek,max so Ek,max = hf − Φ
Symbols
- Symbols h Planck constant in J s, f frequency in Hz, Φ work function in J or eV, Ek,max in J
Part 2 of 7Consequences
1Below threshold
- Below threshold photons with hf less than Φ liberate no electrons
2At threshold
- At threshold hf0 = Φ, the electrons just escape with zero kinetic energy
3Above threshold
- Above threshold the majority of electrons have kinetic energy below Ek,max
4Intensity
- Ek,max depends only on the frequency and the work function, not the intensity
5Alternative form
- Ek,max = h(f − f0)
6Maximum speed
- Ek,max = ½mevmax2
Part 3 of 7Threshold values
Frequency
- Frequency f0 = Φ/h
Wavelength
- λ0 = hc/Φ
Visible photons
- 1.8 to 3.1 eV, so they eject electrons only from metals with low work function
Part 4 of 7Graph of maximum kinetic energy against frequency
Form
- Ek,max = hf − Φ compares with y = mx + c
Gradient
- Planck's constant h, the same for every metal
x-intercept
- x-intercept the threshold frequency f0
y-intercept
- −Φ when extended back
Below f0
- Below f0 no electrons are emitted
Different metals
- Different metals parallel lines shifted along the frequency axis
Stopping potential graph
- Stopping potential graph eVs against f has the same features
Part 5 of 7Working in electronvolts
Photon energy
- Photon energy in eV it is 1240/λ(nm)
Same units
- Same units hf, Φ and Ek,max must all be in eV or all in J
Conversion
- 1 eV = 1.60 × 10−19 J, divide joules by this to get eV
Stopping potential
- Stopping potential its value in volts equals Ek,max in eV
Part 6 of 7Changing the conditions
1Double the intensity
- Double the intensity doubles the number of photons per second and the photocurrent, but Ek,max is unchanged
2Raise the frequency
- Raise the frequency raises Ek,max and Vs linearly
3Different metal
- Different metal changes the threshold but not the gradient
4Two wavelengths on one metal
- Two wavelengths on one metal e(V2 − V1) = hc(1/λ2 − 1/λ1)
Part 7 of 7More from the specification
More from the specification
Radiation
- Transfer by electromagnetic waves, requiring no medium
Diffraction
- Spreading of waves through a gap or around an edge
Scattering
- Deflection of particles from their original path.
Photoelectric effect
- The emission of electrons from a metal surface when electromagnetic radiation of high enough frequency is absorbed.
Scattering angle
- The angle θ through which the photon is deflected.
Wave-particle duality
- The property that radiation and matter show both wave and particle behaviour.
Compton scattering
- Scattering of a photon by an outer electron, with transfer of part of the photon's energy.
Wave theory prediction
- Wave theory prediction energy would build up gradually, so any frequency should eventually eject electrons and brighter light should give faster ones.
Constant intensity
- Constant intensity a higher frequency means each photon carries more energy, so fewer photons per second give the same intensity.
Key terms
| Term | Meaning |
|---|---|
| Photoelectric equation | hf = Φ + Ek,max. |
| Work function | The minimum energy needed to remove an electron from the surface. |
| Threshold frequency | f0 = Φ/h, the lowest frequency that causes emission. |
| Maximum kinetic energy | The kinetic energy of the most energetic photoelectrons, hf − Φ. |
| Planck constant | h = 6.63 × 10−34 J s, the gradient of the Ek,max–f graph. |
Avoid these mistakes
1
Using the photon energy as the kinetic energy — always subtract the work function.
2
Using wavelength where frequency is required, or leaving nm unconverted.
3
Thinking Ek,max depends on intensity or that all electrons have Ek,max.
4
Taking the gradient to be Φ — it is h.
5
Mixing eV and J in the same equation.
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