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Theme B — The Particulate Nature of Matter

B.1.1 Solids, Liquids and Gases — IB Physics HL Revision Notes & Topical Questions

5 min read 10 parts Lesson 3 of 53 1 quiz

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Lesson summary

B.1.1 Solids, Liquids and Gases — IB PHYSICS SL notes: Describe the arrangement, motion and forces between particles in solids, liquids and gases and use this to explain their properties.Kinetic theory of matter — a model that explains the three states of matter, treating particl…

  • Energy and forces
  • Density differences
  • Gas pressure
  • Changes of state
  • Solid keeps its shape
  • Liquid flows

Part 1 of 8The particle model

The particle model
Kinetic theory of matter
  • Kinetic theory of matter a model that explains the three states of matter, treating particles as small spheres.
Particles
  • Particles atoms, molecules or ions that move continually and attract or repel each other.
State
  • State it depends on the balance between kinetic energy, which spreads particles out, and intermolecular forces, which hold them together.
Water
  • Water ice, liquid water and steam differ only in the arrangement of the particles.

Part 2 of 8Solids

Arrangement
  • Arrangement particles are closely packed in a fixed pattern (lattice) with no spaces between them.
  • In an amorphous solid such as glass the order is only local.
Motion
  • Motion particles vibrate about fixed positions and do not move past each other.
Energy and forces
  • Energy and forces they have low energy and cannot overcome the strong forces of attraction holding them together.
Properties
  • Properties fixed shape and volume, very difficult to compress and higher density than liquids and gases.
Heating
  • Heating the vibrations grow in amplitude and at the melting point break the rigid arrangement.

Part 3 of 8Liquids

Arrangement
  • Arrangement particles are closely packed but randomly arranged, with no long-range order.
Motion
  • Motion particles vibrate and flow past each other.
Energy and forces
  • Energy and forces higher energy than solids, so they partially overcome the intermolecular forces.
Properties
  • Properties fixed volume but no fixed shape, difficult to compress, flows easily.
Density
  • Density lower than solids but higher than gases;
    • water is an exception since ice is less dense than liquid water.

Part 4 of 8Gases

Arrangement
  • Arrangement particles are far apart and randomly arranged, with a spacing about 10 times the distance in solids and liquids.
Motion
  • Motion particles move in all directions at a variety of speeds, colliding with each other and with the container walls.
Size
  • Size the particles are negligible in size compared with the volume of the gas.
Energy and forces
  • Energy and forces highest energy, enough to overcome the forces of attraction;
    • the forces matter only during collisions.
Properties
  • Properties no fixed shape or volume, fills the container, can be compressed and has the lowest density.
Density
  • Density about 1000 times smaller than a solid or liquid.
Ideal gas
  • Ideal gas a gas with no intermolecular forces and particles of negligible size.

Part 5 of 8Comparison of the states

PropertySolidLiquidGas
Particle arrangementFixed pattern (lattice)RandomRandom
Space between particlesNo spaceSome spaceLarge space
Particle movementVibrates about a fixed positionFlows past each otherMoves around at different speeds
Particle energyLowMediumHigh
ShapeFixedNot fixedNot fixed
VolumeFixedFixedNot fixed
DensityHighMediumLow
CompressibleNoBarelyYes

Part 6 of 8Macroscopic properties from particle behaviour

Macroscopic properties from particle behaviour
Density differences
  • Density differences they come from the spacing of the particles.
Fluids
  • Fluids liquids and gases are both fluids because their particles are free to move past each other.
Gas pressure
  • Gas pressure each collision exerts an impulse and the vast number per second gives a steady force per unit area.
Changes of state
  • Changes of state added energy overcomes the forces between particles and raises potential energy while the temperature stays constant.

Part 7 of 8Explaining in terms of particles

1Pattern
  • Pattern state how the particles are arranged, how they move and how strongly they attract, then link to the observation.
2Solid keeps its shape
  • Solid keeps its shape its particles are held in fixed positions by strong forces.
3Liquid flows
  • Liquid flows its particles slide past one another but stay in contact.
4Diagrams
  • Diagrams solids are rows of touching circles, liquids touching circles in random order, gases widely spaced circles with arrows.
5Limits of the model
  • Limits of the model glass is amorphous yet solid, and a gas close to condensation shows noticeable intermolecular forces.

Part 8 of 8More from the specification

1
Gravitational compaction of planetary materials
  • Gravitational compaction of planetary materials high pressure inside Earth compresses matter into high-density crystalline solids, liquid iron,
    • and atmospheric gases.
2
Internal Energy in States of Matter
  • The internal energy of a substance is the sum of random kinetic energy and intermolecular potential energy of its constituent particles,
  • increasing through solid, liquid,
  • and gas phases.
3
Specific Latent Heat of Vaporisation
  • The thermal energy required per unit mass to change a substance from liquid to gas at constant boiling temperature, calculated using Q = m * Lv.
4
Modes of Thermal Energy Transfer
  • Thermal energy transfers from hotter to cooler regions via particle conduction in solids (such as copper), fluid bulk movement in convection,
  • or electromagnetic waves in radiation.
5
Surface Emission and Radiation
  • Every object with a temperature above absolute zero emits electromagnetic thermal radiation from its surface, with emission rate governed by the Stefan-Boltzmann law.
6
Wavelength
  • Distance between a point on one wave and the same point on the next wave
7
Fusion
  • Joining of light nuclei into a heavier one.
8
Intensity
  • Power per unit area perpendicular to the wave direction.
9
Apparent brightness
  • The power received per unit area at the observer
10
Thermal equilibrium
  • Constant temperature because energy is absorbed and lost at equal rates
11
Phase change
  • Change of matter from one state to another
12
Thermal conductivity
  • Material constant relating the rate of conduction to the temperature gradient and area
13
Surface temperature
  • Effective temperature of the star's radiating surface.
14
Thermal
  • A convection current in the air.
15
Radiation
  • Transfer by electromagnetic waves, requiring no medium
16
Copper
  • Metal widely used for electrical wires.
17
Convection
  • Transfer of thermal energy by the movement of a heated fluid
18
Conduction
  • Transfer of thermal energy by lattice vibrations and free electrons
19
Luminosity
  • The total power of radiation emitted by a star.
20
Capacity
  • Charge a cell can supply, in A h or C.

Key terms

TermMeaning
Kinetic theory of matterModel explaining the properties of matter in terms of moving particles
LatticeRegular repeating arrangement of particles in a crystalline solid
Intermolecular forceForce of attraction between particles
FluidA liquid or a gas, able to flow
Amorphous solidSolid with only local order, such as glass
Ideal gasGas with no intermolecular forces and negligible particle size

Avoid these mistakes

1
Saying solid particles do not move — they vibrate about fixed positions.
2
Saying gas particles are bigger or heavier than liquid particles — only the spacing and energy differ.
3
Drawing gas particles close together — they are far apart.
4
Saying liquids have no forces between particles — the forces are weaker than in solids but significant.
5
Saying water is as dense as ice — ice is less dense than liquid water.

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