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Complete PDF with figures and original page layoutPage 1 WJEC GCSE Chemistry Your notes 2.3 Metals & Their Extraction Contents Metal Ores Native Metals Metal Reactivity Metal Displacement Reactions Oxidation & Reduction Extraction of Iron …
Section 1 of 34Metal ores
Crust
the Earth’s crust contains metals and metal compounds such as gold, copper, iron oxide and aluminium oxide
Abundance
aluminium is the most abundant metal in the crust and, being reactive, forms compounds
Ore = a rock containing enough metal to make extraction worthwhile
Extraction methods
electrolysis, a blast furnace, or reaction with a more reactive material
Reduction
many ores are oxides, so extraction removes oxygen and is a reduction
Ore
Metal compound
Formula
Haematite
Iron oxide
Fe2O3
Bauxite
Aluminium oxide
Al2O3
Rock salt
Sodium chloride
NaCl
Rutile
Titanium dioxide
TiO2
Section 2 of 34Native metals and extraction method
Native metals
unreactive metals found as the uncombined element because they do not easily react, such as gold and silver
Rule
the extraction method depends on the metal’s position in the reactivity series
steel rods increase the strength of concrete in buildings
Exam skill
explain why a substance suits its use, such as copper conducting electricity in wiring
Section 18 of 34Transition metals
Position
found in the centre of the Periodic Table
Typical metal properties
high melting and boiling points, malleable, high density, and conduct heat and electricity
Extra properties
they form coloured compounds, can form more than one type of ion (such as Fe2+ and Fe3+) and are useful as catalysts
Catalyst uses
Iron in the Haber process to make ammonia.
Platinum in catalytic converters to reduce nitrogen oxides and carbon monoxide in car exhausts.
Section 19 of 34Coloured compounds (Higher tier)
Reason
transition metals form more than one ion and their compounds are often coloured, such as blue copper(II) sulfate containing Cu2+
Ion
Colour of compounds
Fe2+
Pale green
Fe3+
Brown
Cu2+
Blue
Precision
Fe2+ must be described as pale green, not just green
Section 20 of 34Identifying metal ions with sodium hydroxide (Higher tier)
Method
add a few drops of aqueous NaOH to the solution of metal cations and note the precipitate colour
Ion
Equation
Precipitate
Fe2+
Fe2+(aq) + 2OH-(aq) → Fe(OH)2(s)
Pale green
Fe3+
Fe3+(aq) + 3OH-(aq) → Fe(OH)3(s)
Orange-brown
Cu2+
Cu2+(aq) + 2OH-(aq) → Cu(OH)2(s)
Blue
State symbols
give them only when asked
Section 21 of 34Alloys
Alloy = a mixture of two or more metals, or a metal with a non-metal such as carbon
Properties
they can be stronger, harder, and resistant to corrosion or extreme temperatures, which makes them more useful than pure metals
Not a compound
an alloy is a mixture and its elements are not chemically combined
Why alloys are harder
Atoms of different sizes distort the regular lattice.
It is harder for the layers to slide over each other.
Section 22 of 34Common alloys and uses
Steel
iron with carbon, and different steels are made by varying the carbon content and adding other metals
Stainless steel
iron with chromium, nickel and carbon, used in cutlery for hardness and corrosion resistance
Brass
copper and zinc, much stronger than either metal, used in musical instruments, ornaments and door knobs
Iron–tungsten alloys
extremely hard and resistant to high temperatures
Iron with chromium or nickel
resistant to corrosion
Aluminium alloys
aluminium with copper, manganese and silicon for aircraft bodies, stronger but still low density
Section 23 of 34Electrolysis of water
Reaction
2H2O(l) → 2H2(g) + O2(g), done in a Hoffman voltameter
Cathode
H+ ions are attracted and gain electrons (reduced)
2H+(aq) + 2e- → H2(g).
Anode
OH- ions are attracted and lose electrons (oxidised)
2OH-(aq) → O2(g) + 2H+(aq) + 4e-.
Gas volumes
twice as much hydrogen as oxygen forms, because the equation shows 2 mol H2 to 1 mol O2
Gas tests
hydrogen gives a squeaky pop with a lit splint, and oxygen relights a glowing splint
Syllabus note
the cathode equation must be written, and higher tier must balance the anode equation
Section 24 of 34Electrolysis of aqueous solutions: ions present
Water
it is always present and partly ionises, H2O(l) ⇌ H+(aq) + OH-(aq)
Anode
OH- and other negative ions (Cl-, Br-) are attracted and lose electrons, such as 2Cl- → Cl2 + 2e-
Cathode
H+ and other positive ions (Cu2+, Ag+) are attracted and gain electrons
Metal at the cathode
only metals below hydrogen in the reactivity series form there, such as Cu2+ + 2e- → Cu
Solution
Product at anode
Product at cathode
Copper(II) chloride
Chlorine
Copper
Sodium bromide
Bromine
Hydrogen
Collecting gases
use inverted test tubes filled with water, so the gas displaces the water
Section 25 of 34Competing ions (Higher tier)
Anode rule
If a halide ion and OH- are both present, the halide is discharged and forms the halogen.
If no halide is present, OH- is discharged and forms oxygen.
The other negative ion stays in solution.
Cathode rule
Only one of H+ and a metal ion gains electrons.
If the metal is above hydrogen in the reactivity series, hydrogen forms and bubbles are seen.
If the metal is below hydrogen, the metal forms.
Solution
Ions present
Anode
Cathode
Sodium chloride
H+, OH-, Na+, Cl-
2Cl-(aq) → Cl2(g) + 2e-
2H+ + 2e- → H2(g)
Copper(II) chloride
H+, OH-, Cu2+, Cl-
2Cl-(aq) → Cl2(g) + 2e-
Cu2+(aq) + 2e- → Cu(s)
Explanation
in copper(II) chloride copper is below hydrogen so Cu2+ is discharged,
and in sodium chloride sodium is above hydrogen so H+ is discharged, with chlorine formed at the anode in both
Syllabus note
anode products for nitrate or sulfate solutions need not be known
Section 26 of 34Practical: electrolysis of copper(II) sulfate (graphite electrodes)
Apparatus
250 cm3 beaker, two graphite electrodes, 12 V DC supply, leads and crocodile clips, and 400 cm3 of about 0.5 mol dm-3 copper(II) sulfate
Pour the copper(II) sulfate solution into a beaker.
Place two graphite rods in the solution.
Connect one electrode to the negative terminal and the other to the positive terminal of a DC supply.
Fill two small test tubes with copper(II) sulfate solution and invert one over each electrode.
Switch on the power supply and observe each electrode.
Test any gas with a glowing splint and a burning splint.
Record observations at each electrode, including the gas tests.
Section 27 of 34Copper sulfate electrolysis with graphite electrodes: results
Anode
bubbling occurs and the gas relights a glowing splint, so it is oxygen
Cathode
an orange-brown solid, copper metal, forms on the electrode
Tip
the anode is the electrode where gas is produced and bubbles are seen
Cathode equation
Cu2+(aq) + 2e- → Cu(s), a reduction
Anode equation
2OH-(aq) → O2(g) + 2H+(aq) + 4e-
Section 28 of 34Copper sulfate electrolysis with copper electrodes: method
Apparatus
250 cm3 beaker, two copper electrodes (foil), 12 V DC supply, leads and crocodile clips, and 400 cm3 of about 0.5 mol dm-3 copper(II) sulfate
Pour copper(II) sulfate solution into a beaker.
Weigh and record the mass of a piece of copper foil.
Connect it to the negative terminal and dip it in the solution.
Weigh a second piece of foil and connect it to the positive terminal.
Keep the electrodes apart and switch on the supply.
Adjust to a constant current and leave for 20 minutes.
Remove one electrode, wash it with distilled water, dip it in propanone, and let it evaporate dry without wiping.
Weigh and record its mass.
Repeat with the other electrode, taking care to know which is which.
Repeat with fresh electrodes and different currents.
Practical tip
make sure the electrode is dry, or the mass will be false
Section 29 of 34Copper sulfate electrolysis with copper electrodes: results and conclusion
Example data
the anode falls from 18.0 g to 17.6 g and the cathode rises from 18.0 g to 18.4 g, so the cathode gains and the anode loses 0.4 g
Anode
copper atoms are oxidised to ions: Cu(s) → Cu2+(aq) + 2e-
Cathode
copper ions are reduced to atoms: Cu2+(aq) + 2e- → Cu(s)
Mass link
the mass gained equals the mass lost, so the copper deposited is the same copper lost from the anode
Concentration
Cu2+ ions leave and enter the solution at the same rate, so the blue colour is maintained
Section 30 of 34Electroplating
Electroplating
coating the surface of one metal with a layer of a different metal
Anode
made from the pure metal to be plated
Cathode
the object to be plated
Electrolyte
an aqueous solution of a soluble salt of the plating metal
Iron plated with tin (electrolyte tin(II) chloride)
AnodeSn(s) → Sn2+(aq) + 2e-.
CathodeSn2+(aq) + 2e- → Sn(s), coating the iron.
Uses
to resist corrosion or damage, such as chromium and nickel plating, and to improve appearance, such as silver on cutlery and jewellery
Section 31 of 34Purification of copper (Higher tier)
Principle
electrolysis separates a metal from its impurities
Anode
impure copper, which becomes thinner as copper atoms lose electrons: Cu → Cu2+ + 2e-
Cathode
a thin sheet of pure copper, which becomes thicker as ions gain electrons: Cu2+ + 2e- → Cu
Electrolyte
an aqueous solution of a soluble copper salt such as CuSO4
Sludge
impurities fall to the bottom of the cell as anode sludge,
which is valuable and further refined because it often contains precious metals such as silver
Section 32 of 34Electrolysis of brine (Higher tier)
Brine
concentrated aqueous sodium chloride, containing Na+, H+, Cl- and OH-
Cathode
H+ is discharged because it is less reactive than Na+: 2H+ + 2e- → H2
Anode
Cl- is discharged: 2Cl- → Cl2 + 2e-
Solution left
Na+ and OH- remain, forming sodium hydroxide solution
Product
Used to make
Chlorine
Bleach
Hydrogen
Margarine
Sodium hydroxide
Soap and detergents
Syllabus note
the electrode equations are needed, but details of membrane cells are not
Section 33 of 34Economic factors and site of an extraction plant
Viability
extracting the metal must give more financial gain than it costs
Costs
raw materials, energy, labour and the site
Site requirements
Good transport links such as rail and road.
Near a populated area for a workforce, but not so close that noise is a problem.
Close to power stations because large amounts of energy are needed.
Near the coast to import raw materials.
Common error
plants are sited near the coast mainly to import raw materials, not just to export products
Section 34 of 34Sustainability and recycling
Sustainability
resources meet present needs and remain available for future generations
Aims
reduce environmental impact, conserve resources, use energy-efficient methods and renewable energy, minimise waste, recycle,
and cut the carbon footprint
Aluminium
extraction needs huge amounts of electricity and energy to keep the electrolyte molten, so a power station should be close
Iron
raw materials such as haematite and limestone are imported because of cost and the environmental impact of quarrying
Recycling
It is economically beneficial, especially for costly metals like aluminium.
Recycling aluminium needs about 5% of the energy used to extract it from bauxite.
It is a growing industry that provides jobs.
It reduces the environmental damage of mining and lessens landfill waste and transport energy.
Example
Wylfa power station powered Anglesey Aluminium before decommissioning
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🌳 Student Search Tree & Frequently Asked Exam Questions: metals and their extraction
Step-by-step problem-solving guide, mark scheme criteria, and experimental error analysis curated by Dr. Khaled Dabour (DABOURHUB).
Q1: How to solve metals and their extraction examination questions step-by-step?
1. Identify all given values and convert non-standard units, 2. State the primary formula or physiological/chemical principle, 3. Calculate to 3 significant figures and clearly state units.
Q2: What are the common mistakes and experimental sources of error for metals and their extraction?
Avoid confusing independent vs dependent variables in practical questions. In calculation questions, double-check percentage change formula: (change / original) × 100.
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