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Chapter 1 - Transition Elements and Iron Metallurgy

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Chapter 2 - Chemical Analysis

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Chapter 3 - Chemical Equilibrium

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Chapter 4 - Electrochemistry

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Chapter 5 - Organic Chemistry

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Lesson 2 Quiz: Ionic Equilibrium, pH Scale, Hydrolysis and Solubility Product (Ksp)

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1.
STEM Analytical Chemistry Problem 43: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfide anion (S2−) producing H2S
2.
STEM Chemical Equilibrium Problem 4: For the equilibrium reaction: N2(g) + 3 H2(g) 2 NH3(g) (ΔH = -92 kJ/mol), which change will shift the equilibrium to the right and increase ammonia yield?
Decreasing temperature and increasing total pressure
Removing nitrogen gas continuously from the chamber
Adding a positive catalyst at constant volume
Increasing temperature and decreasing pressure
3.
STEM Chemical Equilibrium Problem 35: For the equilibrium reaction: N2(g) + 3 H2(g) 2 NH3(g) (ΔH = -92 kJ/mol), which change will shift the equilibrium to the right and increase ammonia yield?
Decreasing temperature and increasing total pressure
Adding a positive catalyst at constant volume
Removing nitrogen gas continuously from the chamber
Increasing temperature and decreasing pressure
4.
STEM Analytical Chemistry Problem 13: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfide anion (S2−) producing H2S
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
5.
STEM Electrochemistry Problem 15: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+1.10 V (spontaneous galvanic cell)
+0.58 V
-1.10 V (electrolytic cell)
+0.42 V
6.
STEM Organic Distinction Problem 43: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Adding sodium metal: only ethanol reacts with sodium
Adding litmus paper: ethanol turns blue litmus red
Heating with concentrated sulfuric acid at 180°C
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
7.
STEM Transition Elements Problem 36: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Because of the total absence of electrons in the d-subshell
Due to nuclear fission within the metal atom
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
8.
STEM Electrochemistry Problem 14: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
-1.10 V (electrolytic cell)
+0.42 V
+1.10 V (spontaneous galvanic cell)
+0.58 V
9.
STEM Transition Elements Problem 15: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Due to nuclear fission within the metal atom
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Because of the total absence of electrons in the d-subshell
10.
STEM Analytical Chemistry Problem 44: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfide anion (S2−) producing H2S
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Carbonate anion (CO32−) producing CO2
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
11.
STEM Transition Elements Problem 8: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because of the total absence of electrons in the d-subshell
Due to nuclear fission within the metal atom
Because they possess completely filled 3d10 orbitals
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
12.
STEM Electrochemistry Problem 34: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+0.58 V
+1.10 V (spontaneous galvanic cell)
+0.42 V
-1.10 V (electrolytic cell)
13.
STEM Chemical Equilibrium Problem 16: For the equilibrium reaction: N2(g) + 3 H2(g) 2 NH3(g) (ΔH = -92 kJ/mol), which change will shift the equilibrium to the right and increase ammonia yield?
Adding a positive catalyst at constant volume
Increasing temperature and decreasing pressure
Decreasing temperature and increasing total pressure
Removing nitrogen gas continuously from the chamber
14.
STEM Organic Distinction Problem 19: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Adding sodium metal: only ethanol reacts with sodium
Adding litmus paper: ethanol turns blue litmus red
Heating with concentrated sulfuric acid at 180°C
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
15.
STEM Transition Elements Problem 12: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Because of the total absence of electrons in the d-subshell
Due to nuclear fission within the metal atom
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
16.
STEM Transition Elements Problem 31: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Due to nuclear fission within the metal atom
Because of the total absence of electrons in the d-subshell
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
17.
STEM Transition Elements Problem 16: Why are most compounds of transition metals in the first series colored and paramagnetic?
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Due to nuclear fission within the metal atom
Because of the total absence of electrons in the d-subshell
Because they possess completely filled 3d10 orbitals
18.
STEM Organic Chemistry Problem 43: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethylene glycol through addition
Acetic acid (Ethanoic acid) directly
Ethyl alcohol (Ethanol) directly in one step
19.
STEM Organic Chemistry Problem 23: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Acetic acid (Ethanoic acid) directly
Ethyl alcohol (Ethanol) directly in one step
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethylene glycol through addition
20.
STEM Organic Chemistry Problem 3: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Ethyl alcohol (Ethanol) directly in one step
Acetic acid (Ethanoic acid) directly
Ethylene glycol through addition
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
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