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Chapter 1 - Transition Elements and Iron Metallurgy

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Lesson 3 Quiz: Alkynes (Acetylene) and Cyclic Hydrocarbons

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1.
STEM Organic Chemistry Problem 41: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Acetic acid (Ethanoic acid) directly
Ethylene glycol through addition
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethyl alcohol (Ethanol) directly in one step
2.
STEM Chemistry Problem 30: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
25.0 mL of NaOH
10.0 mL of NaOH
12.5 mL of NaOH
50.0 mL of NaOH
3.
STEM Faradaic Problem 32: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
6.35 g of Cu
12.70 g of Cu
3.175 g of Cu
1.587 g of Cu
4.
STEM Chemical Equilibrium Problem 20: For the equilibrium reaction: N2(g) + 3 H2(g) 2 NH3(g) (ΔH = -92 kJ/mol), which change will shift the equilibrium to the right and increase ammonia yield?
Decreasing temperature and increasing total pressure
Adding a positive catalyst at constant volume
Increasing temperature and decreasing pressure
Removing nitrogen gas continuously from the chamber
5.
STEM Organic Distinction Problem 3: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
Adding sodium metal: only ethanol reacts with sodium
Adding litmus paper: ethanol turns blue litmus red
Heating with concentrated sulfuric acid at 180°C
6.
STEM Chemistry Problem 29: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
12.5 mL of NaOH
50.0 mL of NaOH
25.0 mL of NaOH
10.0 mL of NaOH
7.
STEM Chemistry Problem 32: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
50.0 mL of NaOH
25.0 mL of NaOH
10.0 mL of NaOH
12.5 mL of NaOH
8.
STEM Analytical Chemistry Problem 34: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfide anion (S2−) producing H2S
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
9.
STEM Transition Elements Problem 18: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because of the total absence of electrons in the d-subshell
Due to nuclear fission within the metal atom
Because they possess completely filled 3d10 orbitals
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
10.
STEM Organic Chemistry Problem 17: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethylene glycol through addition
Acetic acid (Ethanoic acid) directly
Ethyl alcohol (Ethanol) directly in one step
11.
STEM Transition Elements Problem 4: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because of the total absence of electrons in the d-subshell
Due to nuclear fission within the metal atom
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Because they possess completely filled 3d10 orbitals
12.
STEM Chemistry Problem 34: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
25.0 mL of NaOH
50.0 mL of NaOH
12.5 mL of NaOH
10.0 mL of NaOH
13.
STEM Electrochemistry Problem 37: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
-1.10 V (electrolytic cell)
+0.58 V
+0.42 V
+1.10 V (spontaneous galvanic cell)
14.
STEM Organic Chemistry Problem 5: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethyl alcohol (Ethanol) directly in one step
Acetic acid (Ethanoic acid) directly
Ethylene glycol through addition
15.
STEM Chemistry Problem 18: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
25.0 mL of NaOH
12.5 mL of NaOH
10.0 mL of NaOH
50.0 mL of NaOH
16.
STEM Organic Distinction Problem 34: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Heating with concentrated sulfuric acid at 180°C
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
Adding sodium metal: only ethanol reacts with sodium
Adding litmus paper: ethanol turns blue litmus red
17.
STEM Transition Elements Problem 40: Why are most compounds of transition metals in the first series colored and paramagnetic?
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Because of the total absence of electrons in the d-subshell
Because they possess completely filled 3d10 orbitals
Due to nuclear fission within the metal atom
18.
STEM Organic Distinction Problem 2: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
Heating with concentrated sulfuric acid at 180°C
Adding litmus paper: ethanol turns blue litmus red
Adding sodium metal: only ethanol reacts with sodium
19.
STEM Analytical Chemistry Problem 32: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Sulfide anion (S2−) producing H2S
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
20.
STEM Electrochemistry Problem 22: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+1.10 V (spontaneous galvanic cell)
+0.58 V
-1.10 V (electrolytic cell)
+0.42 V
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