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Chapter 1 - Transition Elements and Iron Metallurgy

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Lesson 3 Quiz: Quantitative Chemical Analysis – Volumetric and Gravimetric Methods

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1.
STEM Organic Chemistry Problem 27: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Acetic acid (Ethanoic acid) directly
Ethylene glycol through addition
Ethyl alcohol (Ethanol) directly in one step
2.
STEM Transition Elements Problem 17: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because of the total absence of electrons in the d-subshell
Due to nuclear fission within the metal atom
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Because they possess completely filled 3d10 orbitals
3.
STEM Faradaic Problem 37: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
3.175 g of Cu
6.35 g of Cu
1.587 g of Cu
12.70 g of Cu
4.
STEM Faradaic Problem 16: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
6.35 g of Cu
1.587 g of Cu
12.70 g of Cu
3.175 g of Cu
5.
STEM Chemical Equilibrium Problem 11: For the equilibrium reaction: N2(g) + 3 H2(g) 2 NH3(g) (ΔH = -92 kJ/mol), which change will shift the equilibrium to the right and increase ammonia yield?
Adding a positive catalyst at constant volume
Increasing temperature and decreasing pressure
Decreasing temperature and increasing total pressure
Removing nitrogen gas continuously from the chamber
6.
STEM Analytical Chemistry Problem 43: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfide anion (S2−) producing H2S
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Carbonate anion (CO32−) producing CO2
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
7.
STEM Faradaic Problem 5: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
1.587 g of Cu
12.70 g of Cu
6.35 g of Cu
3.175 g of Cu
8.
STEM Analytical Chemistry Problem 7: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Sulfide anion (S2−) producing H2S
9.
STEM Organic Distinction Problem 36: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Heating with concentrated sulfuric acid at 180°C
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
Adding sodium metal: only ethanol reacts with sodium
Adding litmus paper: ethanol turns blue litmus red
10.
STEM Electrochemistry Problem 35: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+0.42 V
+1.10 V (spontaneous galvanic cell)
+0.58 V
-1.10 V (electrolytic cell)
11.
STEM Analytical Chemistry Problem 37: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Sulfide anion (S2−) producing H2S
12.
STEM Electrochemistry Problem 29: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+0.42 V
-1.10 V (electrolytic cell)
+0.58 V
+1.10 V (spontaneous galvanic cell)
13.
STEM Chemistry Problem 12: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
12.5 mL of NaOH
10.0 mL of NaOH
50.0 mL of NaOH
25.0 mL of NaOH
14.
STEM Analytical Chemistry Problem 38: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Sulfide anion (S2−) producing H2S
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
15.
STEM Chemical Equilibrium Problem 7: For the equilibrium reaction: N2(g) + 3 H2(g) 2 NH3(g) (ΔH = -92 kJ/mol), which change will shift the equilibrium to the right and increase ammonia yield?
Adding a positive catalyst at constant volume
Removing nitrogen gas continuously from the chamber
Decreasing temperature and increasing total pressure
Increasing temperature and decreasing pressure
16.
STEM Electrochemistry Problem 24: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+1.10 V (spontaneous galvanic cell)
+0.58 V
-1.10 V (electrolytic cell)
+0.42 V
17.
STEM Organic Chemistry Problem 6: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Ethyl alcohol (Ethanol) directly in one step
Acetic acid (Ethanoic acid) directly
Ethylene glycol through addition
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
18.
STEM Faradaic Problem 28: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
6.35 g of Cu
12.70 g of Cu
3.175 g of Cu
1.587 g of Cu
19.
STEM Organic Distinction Problem 14: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Adding sodium metal: only ethanol reacts with sodium
Heating with concentrated sulfuric acid at 180°C
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
Adding litmus paper: ethanol turns blue litmus red
20.
STEM Faradaic Problem 8: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
3.175 g of Cu
12.70 g of Cu
1.587 g of Cu
6.35 g of Cu
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