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Chapter 1 - Transition Elements and Iron Metallurgy

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Chapter 2 - Chemical Analysis

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Chapter 3 - Chemical Equilibrium

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Chapter 4 - Electrochemistry

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Chapter 5 - Organic Chemistry

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Lesson 4 Quiz: Iron Chemical Properties, Reactions and Oxides

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1.
STEM Chemistry Problem 34: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
25.0 mL of NaOH
10.0 mL of NaOH
12.5 mL of NaOH
50.0 mL of NaOH
2.
What is the exact chemical deduction according to Egyptian curriculum standards for: Standard Hydrogen Electrode (SHE) and Galvanic Cells?
SHE can only act as an anode and never as a cathode
SHE has an arbitrarily defined standard potential E° = 0.00 V under standard conditions (1 atm H2 gas, 1.0 M H+ solution, 298 K)
SHE potential changes to 1.00 V when connected to Zinc
The standard hydrogen electrode uses pure copper wire without platinum black
3.
STEM Faradaic Problem 40: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
3.175 g of Cu
1.587 g of Cu
6.35 g of Cu
12.70 g of Cu
4.
STEM Analytical Chemistry Problem 9: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Sulfide anion (S2−) producing H2S
5.
STEM Transition Elements Problem 24: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because of the total absence of electrons in the d-subshell
Due to nuclear fission within the metal atom
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Because they possess completely filled 3d10 orbitals
6.
STEM Organic Distinction Problem 44: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
Adding sodium metal: only ethanol reacts with sodium
Adding litmus paper: ethanol turns blue litmus red
Heating with concentrated sulfuric acid at 180°C
7.
STEM Organic Chemistry Problem 42: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Acetic acid (Ethanoic acid) directly
Ethylene glycol through addition
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethyl alcohol (Ethanol) directly in one step
8.
STEM Transition Elements Problem 40: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because of the total absence of electrons in the d-subshell
Due to nuclear fission within the metal atom
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Because they possess completely filled 3d10 orbitals
9.
STEM Chemistry Problem 37: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
50.0 mL of NaOH
10.0 mL of NaOH
12.5 mL of NaOH
25.0 mL of NaOH
10.
STEM Chemistry Problem 33: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
10.0 mL of NaOH
25.0 mL of NaOH
50.0 mL of NaOH
12.5 mL of NaOH
11.
STEM Chemistry Problem 12: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
50.0 mL of NaOH
10.0 mL of NaOH
12.5 mL of NaOH
25.0 mL of NaOH
12.
STEM Analytical Chemistry Problem 34: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Sulfide anion (S2−) producing H2S
13.
STEM Transition Elements Problem 5: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Due to nuclear fission within the metal atom
Because of the total absence of electrons in the d-subshell
14.
STEM Faradaic Problem 4: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
1.587 g of Cu
12.70 g of Cu
3.175 g of Cu
6.35 g of Cu
15.
STEM Transition Elements Problem 11: Why are most compounds of transition metals in the first series colored and paramagnetic?
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Due to nuclear fission within the metal atom
Because of the total absence of electrons in the d-subshell
Because they possess completely filled 3d10 orbitals
16.
STEM Faradaic Problem 3: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
3.175 g of Cu
1.587 g of Cu
12.70 g of Cu
6.35 g of Cu
17.
STEM Analytical Chemistry Problem 43: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Carbonate anion (CO32−) producing CO2
Sulfide anion (S2−) producing H2S
Thiosulfate anion producing SO2 and yellow sulfur precipitate
18.
STEM Chemistry Problem 20: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
50.0 mL of NaOH
25.0 mL of NaOH
10.0 mL of NaOH
12.5 mL of NaOH
19.
STEM Electrochemistry Problem 30: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+1.10 V (spontaneous galvanic cell)
-1.10 V (electrolytic cell)
+0.58 V
+0.42 V
20.
What is the exact chemical deduction according to Egyptian curriculum standards for: Markovnikov's Rule in Electrophilic Addition to Alkenes?
Hydrogen always attaches to the carbon with fewer hydrogen atoms
Addition occurs with the halogen attaching to the terminal methyl group
Markovnikov's rule applies exclusively to symmetrical alkynes like ethyne
When an asymmetric reagent (HX) adds to an asymmetric alkene, the positive hydrogen ion attaches to the double-bonded carbon with more hydrogen atoms, while the halide adds to the more substituted carbon
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