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Chapter 1 - Transition Elements and Iron Metallurgy

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Chapter 2 - Chemical Analysis

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Chapter 3 - Chemical Equilibrium

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Chapter 4 - Electrochemistry

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Chapter 5 - Organic Chemistry

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Lesson 5 Quiz: Hydrocarbon Derivatives – Alcohols and Phenols

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1.
STEM Analytical Chemistry Problem 31: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfide anion (S2−) producing H2S
Carbonate anion (CO32−) producing CO2
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Thiosulfate anion producing SO2 and yellow sulfur precipitate
2.
STEM Organic Distinction Problem 29: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Adding sodium metal: only ethanol reacts with sodium
Heating with concentrated sulfuric acid at 180°C
Adding litmus paper: ethanol turns blue litmus red
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
3.
STEM Electrochemistry Problem 11: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+1.10 V (spontaneous galvanic cell)
-1.10 V (electrolytic cell)
+0.58 V
+0.42 V
4.
STEM Chemical Equilibrium Problem 11: For the equilibrium reaction: N2(g) + 3 H2(g) 2 NH3(g) (ΔH = -92 kJ/mol), which change will shift the equilibrium to the right and increase ammonia yield?
Adding a positive catalyst at constant volume
Increasing temperature and decreasing pressure
Decreasing temperature and increasing total pressure
Removing nitrogen gas continuously from the chamber
5.
STEM Faradaic Problem 29: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
3.175 g of Cu
1.587 g of Cu
12.70 g of Cu
6.35 g of Cu
6.
STEM Chemical Equilibrium Problem 33: For the equilibrium reaction: N2(g) + 3 H2(g) 2 NH3(g) (ΔH = -92 kJ/mol), which change will shift the equilibrium to the right and increase ammonia yield?
Adding a positive catalyst at constant volume
Removing nitrogen gas continuously from the chamber
Decreasing temperature and increasing total pressure
Increasing temperature and decreasing pressure
7.
STEM Organic Chemistry Problem 31: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Ethyl alcohol (Ethanol) directly in one step
Ethylene glycol through addition
Acetic acid (Ethanoic acid) directly
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
8.
STEM Electrochemistry Problem 32: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+0.58 V
+1.10 V (spontaneous galvanic cell)
+0.42 V
-1.10 V (electrolytic cell)
9.
STEM Transition Elements Problem 13: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Due to nuclear fission within the metal atom
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Because of the total absence of electrons in the d-subshell
10.
STEM Faradaic Problem 23: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
6.35 g of Cu
12.70 g of Cu
1.587 g of Cu
3.175 g of Cu
11.
STEM Chemistry Problem 24: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
50.0 mL of NaOH
10.0 mL of NaOH
12.5 mL of NaOH
25.0 mL of NaOH
12.
STEM Electrochemistry Problem 42: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+1.10 V (spontaneous galvanic cell)
+0.58 V
-1.10 V (electrolytic cell)
+0.42 V
13.
STEM Analytical Chemistry Problem 44: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfide anion (S2−) producing H2S
Carbonate anion (CO32−) producing CO2
14.
STEM Analytical Chemistry Problem 7: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfide anion (S2−) producing H2S
15.
STEM Transition Elements Problem 18: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Due to nuclear fission within the metal atom
Because of the total absence of electrons in the d-subshell
16.
STEM Transition Elements Problem 43: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Due to nuclear fission within the metal atom
Because of the total absence of electrons in the d-subshell
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
17.
STEM Analytical Chemistry Problem 13: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Sulfide anion (S2−) producing H2S
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Carbonate anion (CO32−) producing CO2
18.
STEM Faradaic Problem 8: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
3.175 g of Cu
12.70 g of Cu
1.587 g of Cu
6.35 g of Cu
19.
STEM Chemistry Problem 23: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
12.5 mL of NaOH
50.0 mL of NaOH
25.0 mL of NaOH
10.0 mL of NaOH
20.
STEM Chemistry Problem 10: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
12.5 mL of NaOH
50.0 mL of NaOH
25.0 mL of NaOH
10.0 mL of NaOH
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