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Chapter 1 - Transition Elements and Iron Metallurgy

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Lesson 6 Quiz: Carboxylic Acids, Esters and Organic Polymers

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1.
STEM Transition Elements Problem 8: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Because of the total absence of electrons in the d-subshell
Due to nuclear fission within the metal atom
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
2.
STEM Faradaic Problem 29: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
6.35 g of Cu
12.70 g of Cu
3.175 g of Cu
1.587 g of Cu
3.
STEM Chemistry Problem 39: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
25.0 mL of NaOH
10.0 mL of NaOH
12.5 mL of NaOH
50.0 mL of NaOH
4.
STEM Organic Chemistry Problem 25: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Acetic acid (Ethanoic acid) directly
Ethylene glycol through addition
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethyl alcohol (Ethanol) directly in one step
5.
What is the exact chemical deduction according to Egyptian curriculum standards for: Standard Hydrogen Electrode (SHE) and Galvanic Cells?
The standard hydrogen electrode uses pure copper wire without platinum black
SHE can only act as an anode and never as a cathode
SHE potential changes to 1.00 V when connected to Zinc
SHE has an arbitrarily defined standard potential E° = 0.00 V under standard conditions (1 atm H2 gas, 1.0 M H+ solution, 298 K)
6.
STEM Electrochemistry Problem 22: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+0.42 V
+0.58 V
-1.10 V (electrolytic cell)
+1.10 V (spontaneous galvanic cell)
7.
STEM Organic Chemistry Problem 36: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Acetic acid (Ethanoic acid) directly
Ethyl alcohol (Ethanol) directly in one step
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethylene glycol through addition
8.
STEM Analytical Chemistry Problem 11: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Sulfide anion (S2−) producing H2S
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
9.
STEM Analytical Chemistry Problem 35: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Sulfide anion (S2−) producing H2S
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
10.
STEM Organic Distinction Problem 22: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Adding sodium metal: only ethanol reacts with sodium
Heating with concentrated sulfuric acid at 180°C
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
Adding litmus paper: ethanol turns blue litmus red
11.
STEM Organic Chemistry Problem 18: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethylene glycol through addition
Acetic acid (Ethanoic acid) directly
Ethyl alcohol (Ethanol) directly in one step
12.
STEM Chemistry Problem 30: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
50.0 mL of NaOH
12.5 mL of NaOH
10.0 mL of NaOH
25.0 mL of NaOH
13.
STEM Analytical Chemistry Problem 2: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfide anion (S2−) producing H2S
Carbonate anion (CO32−) producing CO2
14.
STEM Organic Distinction Problem 43: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Adding sodium metal: only ethanol reacts with sodium
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
Heating with concentrated sulfuric acid at 180°C
Adding litmus paper: ethanol turns blue litmus red
15.
STEM Organic Chemistry Problem 2: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethylene glycol through addition
Acetic acid (Ethanoic acid) directly
Ethyl alcohol (Ethanol) directly in one step
16.
STEM Chemistry Problem 35: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
50.0 mL of NaOH
10.0 mL of NaOH
12.5 mL of NaOH
25.0 mL of NaOH
17.
STEM Transition Elements Problem 3: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Due to nuclear fission within the metal atom
Because of the total absence of electrons in the d-subshell
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
18.
STEM Faradaic Problem 15: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
6.35 g of Cu
12.70 g of Cu
3.175 g of Cu
1.587 g of Cu
19.
STEM Electrochemistry Problem 42: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+0.58 V
+1.10 V (spontaneous galvanic cell)
+0.42 V
-1.10 V (electrolytic cell)
20.
STEM Analytical Chemistry Problem 43: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfide anion (S2−) producing H2S
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Carbonate anion (CO32−) producing CO2
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
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