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Chapter 1 - Transition Elements and Iron Metallurgy

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Chapter 2 - Chemical Analysis

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Chapter 3 - Chemical Equilibrium

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Chapter 4 - Electrochemistry

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Chapter 5 - Organic Chemistry

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Lesson 1 Quiz: Chemical Reaction Rates and Le Chatelier’s Principle

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1.
STEM Analytical Chemistry Problem 8: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfide anion (S2−) producing H2S
2.
STEM Organic Chemistry Problem 22: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Ethyl alcohol (Ethanol) directly in one step
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethylene glycol through addition
Acetic acid (Ethanoic acid) directly
3.
STEM Chemistry Problem 11: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
25.0 mL of NaOH
10.0 mL of NaOH
12.5 mL of NaOH
50.0 mL of NaOH
4.
STEM Transition Elements Problem 44: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Due to nuclear fission within the metal atom
Because of the total absence of electrons in the d-subshell
5.
STEM Electrochemistry Problem 43: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+0.58 V
+1.10 V (spontaneous galvanic cell)
+0.42 V
-1.10 V (electrolytic cell)
6.
STEM Organic Distinction Problem 14: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Adding sodium metal: only ethanol reacts with sodium
Adding litmus paper: ethanol turns blue litmus red
Heating with concentrated sulfuric acid at 180°C
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
7.
STEM Chemical Equilibrium Problem 13: For the equilibrium reaction: N2(g) + 3 H2(g) 2 NH3(g) (ΔH = -92 kJ/mol), which change will shift the equilibrium to the right and increase ammonia yield?
Decreasing temperature and increasing total pressure
Removing nitrogen gas continuously from the chamber
Adding a positive catalyst at constant volume
Increasing temperature and decreasing pressure
8.
STEM Chemical Equilibrium Problem 4: For the equilibrium reaction: N2(g) + 3 H2(g) 2 NH3(g) (ΔH = -92 kJ/mol), which change will shift the equilibrium to the right and increase ammonia yield?
Adding a positive catalyst at constant volume
Removing nitrogen gas continuously from the chamber
Increasing temperature and decreasing pressure
Decreasing temperature and increasing total pressure
9.
STEM Electrochemistry Problem 6: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+1.10 V (spontaneous galvanic cell)
-1.10 V (electrolytic cell)
+0.42 V
+0.58 V
10.
STEM Chemical Equilibrium Problem 26: For the equilibrium reaction: N2(g) + 3 H2(g) 2 NH3(g) (ΔH = -92 kJ/mol), which change will shift the equilibrium to the right and increase ammonia yield?
Removing nitrogen gas continuously from the chamber
Decreasing temperature and increasing total pressure
Increasing temperature and decreasing pressure
Adding a positive catalyst at constant volume
11.
STEM Organic Distinction Problem 20: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
Heating with concentrated sulfuric acid at 180°C
Adding litmus paper: ethanol turns blue litmus red
Adding sodium metal: only ethanol reacts with sodium
12.
STEM Analytical Chemistry Problem 33: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfide anion (S2−) producing H2S
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Carbonate anion (CO32−) producing CO2
13.
STEM Electrochemistry Problem 14: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+1.10 V (spontaneous galvanic cell)
+0.42 V
-1.10 V (electrolytic cell)
+0.58 V
14.
STEM Faradaic Problem 18: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
3.175 g of Cu
1.587 g of Cu
12.70 g of Cu
6.35 g of Cu
15.
STEM Analytical Chemistry Problem 7: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfide anion (S2−) producing H2S
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Carbonate anion (CO32−) producing CO2
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
16.
STEM Chemistry Problem 37: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
12.5 mL of NaOH
10.0 mL of NaOH
25.0 mL of NaOH
50.0 mL of NaOH
17.
STEM Transition Elements Problem 39: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Due to nuclear fission within the metal atom
Because of the total absence of electrons in the d-subshell
18.
STEM Analytical Chemistry Problem 22: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Sulfide anion (S2−) producing H2S
19.
STEM Chemistry Problem 2: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
50.0 mL of NaOH
10.0 mL of NaOH
25.0 mL of NaOH
12.5 mL of NaOH
20.
STEM Transition Elements Problem 34: Why are most compounds of transition metals in the first series colored and paramagnetic?
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Because of the total absence of electrons in the d-subshell
Due to nuclear fission within the metal atom
Because they possess completely filled 3d10 orbitals
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