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Chapter 1 - Transition Elements and Iron Metallurgy

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Chapter 2 - Chemical Analysis

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Chapter 3 - Chemical Equilibrium

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Chapter 5 - Organic Chemistry

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Lesson 1 Quiz: First Transition Series, Electronic Configurations and Economic Significance

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  • Questions count: 20
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1.
STEM Chemistry Problem 28: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
50.0 mL of NaOH
25.0 mL of NaOH
10.0 mL of NaOH
12.5 mL of NaOH
2.
STEM Electrochemistry Problem 34: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+1.10 V (spontaneous galvanic cell)
-1.10 V (electrolytic cell)
+0.42 V
+0.58 V
3.
STEM Analytical Chemistry Problem 42: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfide anion (S2−) producing H2S
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Carbonate anion (CO32−) producing CO2
4.
STEM Transition Elements Problem 37: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because of the total absence of electrons in the d-subshell
Because they possess completely filled 3d10 orbitals
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Due to nuclear fission within the metal atom
5.
STEM Transition Elements Problem 30: Why are most compounds of transition metals in the first series colored and paramagnetic?
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Because of the total absence of electrons in the d-subshell
Due to nuclear fission within the metal atom
Because they possess completely filled 3d10 orbitals
6.
STEM Transition Elements Problem 8: Why are most compounds of transition metals in the first series colored and paramagnetic?
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Because of the total absence of electrons in the d-subshell
Because they possess completely filled 3d10 orbitals
Due to nuclear fission within the metal atom
7.
STEM Analytical Chemistry Problem 5: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfide anion (S2−) producing H2S
8.
STEM Organic Distinction Problem 40: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Adding sodium metal: only ethanol reacts with sodium
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
Heating with concentrated sulfuric acid at 180°C
Adding litmus paper: ethanol turns blue litmus red
9.
STEM Transition Elements Problem 16: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Due to nuclear fission within the metal atom
Because of the total absence of electrons in the d-subshell
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
10.
STEM Organic Chemistry Problem 37: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethyl alcohol (Ethanol) directly in one step
Acetic acid (Ethanoic acid) directly
Ethylene glycol through addition
11.
STEM Faradaic Problem 28: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
3.175 g of Cu
1.587 g of Cu
12.70 g of Cu
6.35 g of Cu
12.
STEM Analytical Chemistry Problem 2: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Sulfide anion (S2−) producing H2S
Carbonate anion (CO32−) producing CO2
Thiosulfate anion producing SO2 and yellow sulfur precipitate
13.
STEM Chemistry Problem 33: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
10.0 mL of NaOH
25.0 mL of NaOH
50.0 mL of NaOH
12.5 mL of NaOH
14.
STEM Electrochemistry Problem 29: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+1.10 V (spontaneous galvanic cell)
+0.42 V
-1.10 V (electrolytic cell)
+0.58 V
15.
STEM Analytical Chemistry Problem 4: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Carbonate anion (CO32−) producing CO2
Sulfide anion (S2−) producing H2S
Thiosulfate anion producing SO2 and yellow sulfur precipitate
16.
STEM Analytical Chemistry Problem 23: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Sulfide anion (S2−) producing H2S
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Carbonate anion (CO32−) producing CO2
17.
STEM Electrochemistry Problem 18: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+0.42 V
+0.58 V
+1.10 V (spontaneous galvanic cell)
-1.10 V (electrolytic cell)
18.
STEM Chemistry Problem 25: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
10.0 mL of NaOH
25.0 mL of NaOH
50.0 mL of NaOH
12.5 mL of NaOH
19.
STEM Analytical Chemistry Problem 40: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfide anion (S2−) producing H2S
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
20.
STEM Analytical Chemistry Problem 21: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfide anion (S2−) producing H2S
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