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Chapter 1 - Transition Elements and Iron Metallurgy

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Lesson 1: Chemical Reaction Rates and Le Chatelier’s Principle — Lesson quiz

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1.
For the exothermic Haber-Bosch reaction N₂(g) + 3 H₂(g) ⇌ 2 NH₃(g) (ΔH = -92 kJ), which change increases the equilibrium constant Kc?
Lowering the temperature of the system
Increasing the total pressure
Adding an iron catalyst
Increasing the concentration of nitrogen gas
2.
What is the exact chemical deduction according to Egyptian curriculum standards for: Electronic Configuration of the First Transition Series?
Chromium (Cr: 24) has an anomalous configuration [Ar] 4s1 3d5 to achieve half-filled d-subshell stability, and Copper (Cu: 29) is [Ar] 4s1 3d10 for completely filled d-subshell stability
Scandium (Sc: 21) exhibits stable oxidation states of +1, +2, and +3
Zinc (Zn: 30) is considered a typical transition element in all its compounds
Both Chromium and Copper have fully filled 4s2 orbitals
3.
What is the exact chemical deduction according to Egyptian curriculum standards for: Le Chatelier's Principle in Gas-Phase Equilibrium?
Increasing pressure on an equilibrium mixture shifts the reaction toward the side with fewer moles of gas, without changing the equilibrium constant (Kc)
Increasing temperature always increases the value of Kc for exothermic reactions
Adding a catalyst shifts the equilibrium position toward products
Decreasing volume increases the value of Kp for any reaction
4.
What is the exact chemical deduction according to Egyptian curriculum standards for: Standard Hydrogen Electrode (SHE) and Galvanic Cells?
SHE potential changes to 1.00 V when connected to Zinc
SHE has an arbitrarily defined standard potential E° = 0.00 V under standard conditions (1 atm H₂ gas, 1.0 M H+ solution, 298 K)
SHE can only act as an anode and never as a cathode
The standard hydrogen electrode uses pure copper wire without platinum black
5.
What is the exact chemical deduction according to Egyptian curriculum standards for: Markovnikov's Rule in Electrophilic Addition to Alkenes?
Hydrogen always attaches to the carbon with fewer hydrogen atoms
Markovnikov's rule applies exclusively to symmetrical alkynes like ethyne
Addition occurs with the halogen attaching to the terminal methyl group
When an asymmetric reagent (HX) adds to an asymmetric alkene, the positive hydrogen ion attaches to the double-bonded carbon with more hydrogen atoms, while the halide adds to the more substituted carbon
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