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Chapter 1 - Transition Elements and Iron Metallurgy

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Lesson 1 Quiz: Introduction to Organic Chemistry, Wöhler’s Synthesis and Alkanes

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1.
STEM Electrochemistry Problem 11: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+0.42 V
-1.10 V (electrolytic cell)
+0.58 V
+1.10 V (spontaneous galvanic cell)
2.
STEM Electrochemistry Problem 24: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
-1.10 V (electrolytic cell)
+0.58 V
+1.10 V (spontaneous galvanic cell)
+0.42 V
3.
STEM Transition Elements Problem 3: Why are most compounds of transition metals in the first series colored and paramagnetic?
Due to nuclear fission within the metal atom
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Because they possess completely filled 3d10 orbitals
Because of the total absence of electrons in the d-subshell
4.
STEM Transition Elements Problem 13: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because of the total absence of electrons in the d-subshell
Due to nuclear fission within the metal atom
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Because they possess completely filled 3d10 orbitals
5.
STEM Organic Chemistry Problem 42: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Ethylene glycol through addition
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethyl alcohol (Ethanol) directly in one step
Acetic acid (Ethanoic acid) directly
6.
STEM Electrochemistry Problem 9: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+0.58 V
+1.10 V (spontaneous galvanic cell)
+0.42 V
-1.10 V (electrolytic cell)
7.
STEM Chemistry Problem 43: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
50.0 mL of NaOH
25.0 mL of NaOH
10.0 mL of NaOH
12.5 mL of NaOH
8.
STEM Electrochemistry Problem 17: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
-1.10 V (electrolytic cell)
+0.58 V
+0.42 V
+1.10 V (spontaneous galvanic cell)
9.
STEM Transition Elements Problem 8: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Due to nuclear fission within the metal atom
Because of the total absence of electrons in the d-subshell
10.
STEM Electrochemistry Problem 10: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+0.42 V
+0.58 V
-1.10 V (electrolytic cell)
+1.10 V (spontaneous galvanic cell)
11.
STEM Organic Chemistry Problem 18: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Acetic acid (Ethanoic acid) directly
Ethylene glycol through addition
Ethyl alcohol (Ethanol) directly in one step
12.
STEM Transition Elements Problem 43: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because of the total absence of electrons in the d-subshell
Because they possess completely filled 3d10 orbitals
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Due to nuclear fission within the metal atom
13.
STEM Electrochemistry Problem 14: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
-1.10 V (electrolytic cell)
+0.58 V
+1.10 V (spontaneous galvanic cell)
+0.42 V
14.
STEM Organic Chemistry Problem 27: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethylene glycol through addition
Acetic acid (Ethanoic acid) directly
Ethyl alcohol (Ethanol) directly in one step
15.
STEM Organic Chemistry Problem 16: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Ethylene glycol through addition
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethyl alcohol (Ethanol) directly in one step
Acetic acid (Ethanoic acid) directly
16.
STEM Chemistry Problem 27: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
25.0 mL of NaOH
50.0 mL of NaOH
12.5 mL of NaOH
10.0 mL of NaOH
17.
STEM Organic Chemistry Problem 32: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Acetic acid (Ethanoic acid) directly
Ethylene glycol through addition
Ethyl alcohol (Ethanol) directly in one step
18.
STEM Chemical Equilibrium Problem 32: For the equilibrium reaction: N2(g) + 3 H2(g) 2 NH3(g) (ΔH = -92 kJ/mol), which change will shift the equilibrium to the right and increase ammonia yield?
Removing nitrogen gas continuously from the chamber
Decreasing temperature and increasing total pressure
Increasing temperature and decreasing pressure
Adding a positive catalyst at constant volume
19.
STEM Chemistry Problem 2: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
25.0 mL of NaOH
12.5 mL of NaOH
10.0 mL of NaOH
50.0 mL of NaOH
20.
STEM Electrochemistry Problem 35: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+0.42 V
+0.58 V
+1.10 V (spontaneous galvanic cell)
-1.10 V (electrolytic cell)
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