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Chapter 1 - Transition Elements and Iron Metallurgy

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Lesson 1 Quiz: Qualitative Analysis of Acidic Radicals (Anions)

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  • Questions count: 20
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1.
STEM Faradaic Problem 19: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
1.587 g of Cu
12.70 g of Cu
3.175 g of Cu
6.35 g of Cu
2.
STEM Analytical Chemistry Problem 32: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfide anion (S2−) producing H2S
Carbonate anion (CO32−) producing CO2
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Thiosulfate anion producing SO2 and yellow sulfur precipitate
3.
STEM Chemical Equilibrium Problem 3: For the equilibrium reaction: N2(g) + 3 H2(g) 2 NH3(g) (ΔH = -92 kJ/mol), which change will shift the equilibrium to the right and increase ammonia yield?
Removing nitrogen gas continuously from the chamber
Decreasing temperature and increasing total pressure
Increasing temperature and decreasing pressure
Adding a positive catalyst at constant volume
4.
STEM Chemistry Problem 1: A 25.0 mL sample of 0.10 M H2SO4 is completely neutralized by 0.20 M NaOH. What volume of NaOH solution is required to reach the equivalence point?
50.0 mL of NaOH
25.0 mL of NaOH
10.0 mL of NaOH
12.5 mL of NaOH
5.
STEM Faradaic Problem 36: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
3.175 g of Cu
6.35 g of Cu
1.587 g of Cu
12.70 g of Cu
6.
STEM Analytical Chemistry Problem 34: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Sulfide anion (S2−) producing H2S
Carbonate anion (CO32−) producing CO2
Thiosulfate anion producing SO2 and yellow sulfur precipitate
7.
STEM Electrochemistry Problem 40: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+1.10 V (spontaneous galvanic cell)
-1.10 V (electrolytic cell)
+0.42 V
+0.58 V
8.
STEM Transition Elements Problem 15: Why are most compounds of transition metals in the first series colored and paramagnetic?
Because they possess completely filled 3d10 orbitals
Due to nuclear fission within the metal atom
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Because of the total absence of electrons in the d-subshell
9.
STEM Chemical Equilibrium Problem 24: For the equilibrium reaction: N2(g) + 3 H2(g) 2 NH3(g) (ΔH = -92 kJ/mol), which change will shift the equilibrium to the right and increase ammonia yield?
Increasing temperature and decreasing pressure
Decreasing temperature and increasing total pressure
Removing nitrogen gas continuously from the chamber
Adding a positive catalyst at constant volume
10.
STEM Organic Distinction Problem 6: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Heating with concentrated sulfuric acid at 180°C
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
Adding sodium metal: only ethanol reacts with sodium
Adding litmus paper: ethanol turns blue litmus red
11.
STEM Faradaic Problem 21: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
6.35 g of Cu
12.70 g of Cu
3.175 g of Cu
1.587 g of Cu
12.
STEM Electrochemistry Problem 31: In a Daniell cell, Zn | Zn2+ (1 M) || Cu2+ (1 M) | Cu, given E°(Zn2+/Zn) = -0.76 V and E°(Cu2+/Cu) = +0.34 V, what is the standard electromotive force (E°cell)?
+0.42 V
+0.58 V
-1.10 V (electrolytic cell)
+1.10 V (spontaneous galvanic cell)
13.
STEM Organic Distinction Problem 38: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Adding sodium metal: only ethanol reacts with sodium
Adding litmus paper: ethanol turns blue litmus red
Heating with concentrated sulfuric acid at 180°C
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
14.
STEM Organic Chemistry Problem 27: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Ethyl alcohol (Ethanol) directly in one step
Acetic acid (Ethanoic acid) directly
Ethylene glycol through addition
15.
STEM Organic Distinction Problem 15: How can you chemically distinguish between phenol (C6H5OH) and ethanol (C2H5OH) using a simple qualitative test?
Adding litmus paper: ethanol turns blue litmus red
Heating with concentrated sulfuric acid at 180°C
Adding neutral FeCl3 solution: phenol produces a distinct violet color, whereas ethanol shows no change
Adding sodium metal: only ethanol reacts with sodium
16.
STEM Transition Elements Problem 10: Why are most compounds of transition metals in the first series colored and paramagnetic?
Due to the presence of unpaired electrons in 3d orbitals that absorb specific wavelengths of visible light for d-d excitation
Due to nuclear fission within the metal atom
Because of the total absence of electrons in the d-subshell
Because they possess completely filled 3d10 orbitals
17.
STEM Faradaic Problem 20: What mass of copper (atomic mass = 63.5 g/mol) is deposited at the cathode when a constant current of 9.65 A passes through a CuSO4 solution for 1,000 seconds? (Faraday constant = 96,500 C/mol)
6.35 g of Cu
1.587 g of Cu
12.70 g of Cu
3.175 g of Cu
18.
STEM Organic Chemistry Problem 8: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Ethyl alcohol (Ethanol) directly in one step
Acetic acid (Ethanoic acid) directly
Ethylene glycol through addition
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
19.
STEM Organic Chemistry Problem 11: Catalytic hydration of acetylene (ethyne, C2H2) with H2O in the presence of 40% H2SO4 and 1% HgSO4 at 60°C yields which intermediate and final product?
Unstable vinyl alcohol intermediate that tautomerizes to Acetaldehyde (Ethanal, CH3CHO)
Acetic acid (Ethanoic acid) directly
Ethyl alcohol (Ethanol) directly in one step
Ethylene glycol through addition
20.
STEM Analytical Chemistry Problem 31: When dilute hydrochloric acid (HCl) is added to a solid unknown salt, a colorless gas evolves that turns paper moistened with acidified potassium dichromate from orange to green. What is the anion?
Carbonate anion (CO32−) producing CO2
Sulfite anion (SO32−) producing sulfur dioxide gas (SO2)
Thiosulfate anion producing SO2 and yellow sulfur precipitate
Sulfide anion (S2−) producing H2S
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