11 2.4 Life application: how a match lights
- The match head contains an oxidising agent, potassium chlorate (KClO₃), together with easily burned substances, glue and powdered glass.
- The striking strip on the side of the box contains red phosphorus, glue and glass powder.
When you strike a match, friction heat turns a tiny amount of red phosphorus into white phosphorus, which ignites spontaneously in air. This heat decomposes potassium chlorate: 2KClO₃ → 2KCl + 3O₂ The oxygen released makes the match head and the wood burn faster and more intensely.