11 3.2 Why water dissolves ionic compounds
When an ionic compound is added to water, its crystal lattice breaks down into free ions surrounded by water molecules:
- positive ions (cations) are attracted to the negative pole of water (the oxygen atoms);
- negative ions (anions) are attracted to the positive pole of water (the hydrogen atoms).
- The water molecules form a "shell" around each ion (hydration), which keeps the ions apart so they cannot recombine.
- Energy released by hydration compensates for the energy needed to break the lattice.