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CHEMISTRY · Stage 8 · Chapter 9: Chemical Reactions 2

Chemistry 9.6 Metals and oxygen — Metal Oxide Formation and Reactivity

5 min read 6 parts Lesson 6 of 12

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9.6 Metals and oxygen — Metal Oxide Formation and Reactivity — Alhussan International Academy — Chemistry (Stages 7–9) notes: Define reactivity, describe how metals react with oxygen to form oxides and rank metals by the vigour of the reaction.General pattern — metal + oxygen → m…

  • Corrosion without heating
  • Metal properties
  • Observation
  • Surface atoms
  • Calcium and potassium
  • Heating magnesium ribbon

Part 1 of 6Metals and oxygen

  • General pattern — metal + oxygen → metal oxide, which is an oxidation reaction.
  • Magnesium — it burns vigorously with a bright white flame to make white magnesium oxide: magnesium + oxygen → magnesium oxide.
    • Flares contain magnesium for the bright white light, with strontium nitrate to make a red flame.
  • Corrosion without heating — in air, over time, surface atoms of magnesium react with oxygen to make a thin layer of magnesium oxide.
  • Metal properties — metals have similar physical properties (shiny, conduct heat and electricity) and patterns in their chemical properties too.

Part 2 of 6Reactivity

  • Reactivity the tendency of a substance to take part in chemical reactions.
  • Observationthe more reactive a metal is, the more vigorously it reacts.
  • Surface atomsonly the surface atoms of a metal react with oxygen, forming an oxide layer.

Part 3 of 6Reactions of different metals with oxygen

MetalReaction with oxygenProduct
SodiumBurns very vigorously; surface reacts quickly without heatingSodium oxide and sodium peroxide
MagnesiumBurns vigorously with a bright white flame; surface reacts slowly without heatingMagnesium oxide
ZincPowder burns vigorously with a greenish flame; bigger pieces do not burn easilyZinc oxide
IronPowder burns vigorously; bigger pieces do not burn easilyIron oxide
CopperDoes not burn; surface turns black when heatedCopper oxide
GoldNo reactionNone
  • Order — the metals get less reactive from sodium to gold, and their reactivity decreases down the table.
  • Sodium — when it burns there is a mixture of products, sodium oxide (Na2O) and sodium peroxide (Na2O2).
    • A freshly cut surface reacts with oxygen at once, making white sodium oxide.
  • Calcium and potassium — potassium tarnishes within seconds and burns fiercely, and calcium burns with a red flame to make calcium oxide.
  • Copper — word equation: copper + oxygen → copper oxide.
  • Gold — its surface atoms do not react with oxygen, so it stays shiny and is used for connectors in audio equipment.

Part 4 of 6Mass change

1Heating magnesium ribbon1 point
— in a covered crucible, the mass of the solid increases because oxygen from the air becomes part of the oxide.
  • The lid is raised briefly to let air in without letting smoke escape.
2Conservation of mass
— mass of metal + mass of oxygen = mass of oxide.
3Properties of oxides1 point
— metal oxides are usually solids with high melting points.
  • Oxides of soluble metals such as sodium, potassium and calcium dissolve in water to form alkaline solutions, but many others are insoluble bases.
4Exothermic
— burning reactions of metals are exothermic, shown by the heat and light produced.

Part 5 of 6Explaining reactivity

  • Electrons — reactive metals lose their outer electrons easily to become positive ions.
    • Potassium has one outer electron far from the nucleus, so it is lost with very little energy.
    • Magnesium has two outer electrons, and copper holds its electrons more tightly.
  • Position in series — metals higher in the reactivity series combine with oxygen more readily.

Part 6 of 6Oxide layers and rusting

1Aluminium
— its oxide layer is hard, unreactive and sticks firmly, which protects the metal underneath.
2Iron1 point
— iron oxide (rust) is flaky and falls off, exposing new metal that then rusts further.
  • Rusting needs oxygen and water and is speeded up by salt.
3Comparing metals in a practical2 points
— use the same mass of each metal in the same form and heat in the same way.
  • Record the time to start burning, flame colour and the appearance of the product in a table.
  • Do not look directly at burning magnesium, and use tongs and a heat-resistant mat.

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