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5.1.1Energy Changes

Energy Transfer in Reactions — AQA GCSE Combined Science Trilogy 8464 - Chemistry Revision Notes & Topical Questions

5 min read 7 parts Lesson 2 of 5

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Part 1 of 5Energy is conserved

Conservation of energy
  • Conservation of energy Energy cannot be created or destroyed in a chemical reaction; it is only transferred.
  • The total energy before and after is the same.
Measured by temperature
  • Measured by temperature Energy transfer to or from the surroundings is detected as a change in temperature with a thermometer.
Link to products
  • Link to products If energy goes to the surroundings, the products store less energy than the reactants did, by the same amount.

Part 2 of 5Exothermic and endothermic reactions

FeatureExothermicEndothermic
Energy transferReleased to surroundingsTaken in from surroundings
Temperature of surroundingsRisesFalls
Energy of products compared with reactantsLowerHigher
ExamplesCombustion, neutralisation, oxidation of metals, many oxidationsThermal decomposition, electrolysis, first stage of photosynthesis, citric acid with sodium hydrogencarbonate

Part 3 of 5Everyday applications

Using energy changes
Hand warmers
  • Hand warmers Exothermic oxidation of iron or crystallisation of a salt releases heat on demand.
Self-heating cans
  • Self-heating cans An exothermic reaction inside warms food or drinks.
Cold packs
  • Cold packs An endothermic dissolving or reaction takes in heat from an injury to reduce swelling.
Fuels
  • Fuels Combustion gives heat energy for cooking, heating and transport.

Part 4 of 5Observing a temperature change

1
Measure the starting temperature of the reactants with a thermometer.
2
Mix the reactants, stirring gently.
3
Record the highest or lowest temperature reached.
4
Subtract the starting value from the final value to find the temperature change.
5
A rise shows exothermic; a fall shows endothermic.

Part 5 of 5Where the energy goes

1Reactants
  • Reactants Particles hold energy in their chemical bonds.
2Reaction
  • Reaction Bonds are broken and new bonds formed.
3Energy exchange
  • Energy exchange Net energy is released to, or absorbed from, the surroundings.
4Temperature changes
  • Temperature changes The surroundings warm up or cool down accordingly.

Key terms

TermMeaning
ExothermicA reaction that transfers energy to the surroundings, so the temperature rises.
EndothermicA reaction that takes in energy from the surroundings, so the temperature falls.
SurroundingsEverything outside the reacting chemicals, such as the solution, container and air.
Conservation of energyThe principle that energy is transferred but never created or destroyed.
Thermal decompositionBreaking down of a compound by heating.

Avoid these mistakes

1
Saying exothermic reactions 'give out cold' — they heat the surroundings.
2
Describing the temperature of the chemicals instead of the surroundings; the thermometer measures the solution.
3
Stating that energy is made in an exothermic reaction; it is transferred from stored chemical energy.
4
Calling all reactions needing heating endothermic — a reaction may need heat to start yet release more overall.

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