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3.2.4Particle Model of Matter

Specific Latent Heat — AQA GCSE Combined Science Trilogy 8464 - Physics Revision Notes & Topical Questions

5 min read 8 parts Lesson 9 of 12

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Part 1 of 6Definition and equation

Specific latent heat
  • Specific latent heat The amount of energy needed to change the state of 1 kg of a substance with no change in temperature.
Equation
  • Equation E = m × L, where E is energy in joules (J), m is mass in kilograms (kg) and L is specific latent heat in J/kg.
Two values per substance
  • Two values per substance Specific latent heat of fusion applies to melting or freezing;
    • specific latent heat of vaporisation applies to boiling or condensing.
  • For waterfusion about 334 000 J/kg and vaporisation about 2 260 000 J/kg.

Part 2 of 6Worked calculation

1
Question: how much energy is needed to boil away 0.50 kg of water at 100 °C? L = 2 260 000 J/kg.
2
Write the equation E = m × L.
3
Substitute: E = 0.50 × 2 260 000.
4
Answer: E = 1 130 000 J, or 1.13 MJ. To find a mass or L, rearrange to m = E ÷ L or L = E ÷ m.

Part 3 of 6More practice calculations

QuestionWorkingAnswer
Energy to melt 2.0 kg of ice already at 0 °C (L = 334 000 J/kg)E = 2.0 × 334 000668 000 J
Mass of water boiled by 452 000 J (L = 2 260 000 J/kg)m = 452 000 ÷ 2 260 0000.20 kg
A 0.25 kg sample of a metal needs 62 500 J to melt at its melting point. Find L.L = 62 500 ÷ 0.25250 000 J/kg
Energy released when 0.10 kg of steam condenses to water at 100 °CE = 0.10 × 2 260 000226 000 J

Part 4 of 6Heating ice to steam: two stages

1Warming
  • Warming Use ΔE = m × c × Δθ while the temperature changes within one state.
2Changing state
  • Changing state Use E = m × L while the temperature is constant at the melting or boiling point.
3Add the stages
  • Add the stages For a full journey, such as ice at −10 °C to steam, calculate each stage separately and add the energies together.

Part 5 of 6Measuring L for ice or water

1
Place a heater in a beaker containing a known mass of crushed ice (or water already at its boiling point), connected to a joulemeter or to an ammeter and voltmeter.
2
Switch on and record the electrical energy transferred, E = V × I × t.
3
For vaporisation, place the beaker on a balance and measure the mass of water boiled off.
4
Calculate L = E ÷ m. Insulate the container and repeat to reduce heat losses and improve accuracy.

Part 6 of 6Comparing the two quantities

FeatureFusionVaporisation
ChangeSolid to liquidLiquid to gas
Typical size for waterSmallerAbout seven times larger
WhyParticles stay close, only the lattice is loosenedParticles must be separated far apart
EquationE = m × LfE = m × Lv

Key terms

TermMeaning
Specific latent heatEnergy per kilogram needed to change state without a temperature change.
JouleThe unit of energy.
JoulemeterAn instrument that records the electrical energy supplied.
FusionMelting or freezing.
VaporisationBoiling or condensing.
Specific heat capacityEnergy needed to raise the temperature of 1 kg of a substance by 1 °C.

Avoid these mistakes

1
Using a temperature change in E = m × L — there is no temperature term.
2
Using grams rather than kilograms for the mass.
3
Using the latent heat of fusion for boiling problems, or vice versa.
4
Forgetting that the practical result is usually too high because of energy lost to the surroundings.
5
Using E = m × L for a stage where the temperature is changing instead of m × c × Δθ.

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