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2.2.22 · Biological Molecules

Covalent Bonds in Polymers — Cambridge AS & A Level Biology 9700 Revision Notes & Topical Questions

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2.2.2 Covalent Bonds in Polymers — CAMBRIDGE AS & A LEVEL BIOLOGY 9700 — REVISION NOTES notes: Describe covalent bonding, condensation and hydrolysis, and the bonds in the four types of organic molecule.Definition — a covalent bond is the sharing of electrons between two atoms.Po…

  • Multiple bonds
  • Macromolecule
  • Glycosidic bond
  • Peptide bond
  • Ester bond
  • Triglyceride

Section 1 of 7Covalent bonds

Definition
  • Definition a covalent bond is the sharing of electrons between two atoms.
Polarity
  • Polarity equal sharing gives a non-polar bond, and unequal sharing gives a polar bond.
    • (a more electronegative atom)
Valency
  • Valency each atom forms a set number of bonds, e.g. H forms 1 and C forms 4.
Stability
  • Stability covalent bonds need a lot of energy to break.
Multiple bonds
  • Multiple bonds pairs of electrons can be shared to give double bonds, e.g. C=C in unsaturated fats.

Section 2 of 7Condensation reactions

Definition
  • Definition monomers combine by covalent bonds and water is removed.
Outcome
  • Outcome polymers form by polymerisation, and lipids form as macromolecules.
Mechanism
  • Mechanism when monomers are close, their outer orbitals overlap and electrons are shared.

Section 3 of 7Hydrolysis reactions

Meaning
  • Meaning hydro means with water and lyse means to break.
Outcome
  • Outcome water is added and the covalent bond between monomers is broken.
Enzymes
  • Enzymes different enzymes catalyse hydrolysis and condensation.

Section 4 of 7Bonds in each biological molecule

Organic moleculeCovalent bond
CarbohydratesGlycosidic
ProteinsPeptide
LipidsEster
Nucleic acidsPhosphodiester

Section 5 of 7More from the specification

1Reducing sugars and non-reducing sugars
  • Reducing sugars and non-reducing sugars heating test samples with Benedict's reagent identifies reducing sugars,
    • whereas non-reducing sugars require acid hydrolysis first.
2Sucrose
  • The sugar mainly transported in phloem.
3Non-reducing sugar
  • A sugar that cannot reduce Benedict's reagent until hydrolysed.
4Condensation reaction
  • A reaction joining molecules with the release of water.
5Glucose
  • A simple sugar; the unit that starch, glycogen and cellulose are built from.
6Cellulose
  • A structural polysaccharide of β-glucose.
7Starch
  • An insoluble polysaccharide of glucose used by plants for energy storage.
8Triglyceride
  • A lipid made of glycerol and three fatty acids.
9Phospholipid
  • Glycerol, two fatty acids and a phosphate group, which is amphipathic.
10Monosaccharide
  • A single sugar unit such as glucose, fructose or galactose.
11Hydrophobic
  • Water-hating; non-polar and unable to dissolve in water.
12Carbon
  • Element with four valence electrons that forms the backbone of organic molecules.
13Monomer
  • Monomer a small molecule that can join to many others by covalent bonds to form a polymer.
14Macromolecule
  • Macromolecule a very large molecule, such as a polysaccharide, protein or nucleic acid, built from many atoms.

Section 6 of 7Key terms

TermMeaning
Covalent bondA bond formed by sharing electrons between atoms.
CondensationA reaction joining two molecules with the loss of water.
HydrolysisA reaction splitting a bond by the addition of water.
Glycosidic bondThe bond between sugar units.
Peptide bondThe bond between amino acids.
Ester bondThe bond between glycerol and fatty acids.
Phosphodiester bondThe bond between nucleotides.

Section 7 of 7Exam technique

1
Saying hydrolysis removes water — it adds water.
2
Saying condensation adds water — it releases water.
3
Naming the wrong bond for a molecule — carbohydrates glycosidic, proteins peptide, lipids ester, nucleic acids phosphodiester.
4
Saying covalent bonds are weak — they are strong and need high energy to break.

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