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2.2.52 · Biological Molecules

Starch and Glycogen — Cambridge AS & A Level Biology 9700 Revision Notes & Topical Questions

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2.2.5 Starch and Glycogen — CAMBRIDGE AS & A LEVEL BIOLOGY 9700 — REVISION NOTES notes: Describe the structure and functions of starch and glycogen.Compact — many molecules fit in a small space, so large amounts can be stored.Insoluble — they have no osmotic effect, whereas solub…

  • Chain shapes
  • Composition
  • Amylopectin
  • Triglyceride
  • Phospholipid
  • Monosaccharide

Section 1 of 8Why they are storage polysaccharides

Compact
  • Compact many molecules fit in a small space, so large amounts can be stored.
Insoluble
  • Insoluble they have no osmotic effect, whereas soluble glucose would lower water potential and draw in water.
Chain shapes
  • Chain shapes chains may be branched or unbranched, and straight or coiled.

Section 2 of 8Starch

Source
  • Source the storage polysaccharide of plants, stored as granules in plastids such as chloroplasts.
Digestion
  • Digestion it takes longer to digest than glucose.
Composition
  • Composition amylose and amylopectin, both made of alpha-glucose.

Section 3 of 8Amylose and amylopectin

Amylose
  • 10–30% of starch.
  • It is an unbranched helix with alpha-1,4 glycosidic bonds.
  • The helix makes it compact and resistant to digestion.
Amylopectin
  • 70–90% of starch.
  • It has alpha-1,4 bonds and alpha-1,6 bonds that create branches.
  • Branches give many terminal glucose ends that are easily hydrolysed for respiration or added to for storage.

Section 4 of 8Glycogen

Glycogen
Source
  • Source the storage polysaccharide of animals and fungi.
Structure
  • Structure highly branched and not coiled, with alpha-1,4 and alpha-1,6 bonds.
Location
  • Location liver and muscle cells hold visible granules because respiration is fast there.
Function
  • Function more branching than amylopectin makes it more compact and gives more free ends for rapid addition or removal of glucose.

Section 5 of 8Comparison of starch and glycogen

FeatureAmyloseAmylopectinGlycogen
Monomeralpha-glucosealpha-glucosealpha-glucose
BranchedNoYesYes, more highly
HelixYesNoNo
Bondsalpha-1,4alpha-1,4 and 1,6alpha-1,4 and 1,6
SourcePlantsPlantsAnimals and fungi

Section 6 of 8More from the specification

More from the specification
Polysaccharide Energy Stores
  • Starch (in plants) and glycogen (in animals) are compact, insoluble polymers formed from α-glucose monosaccharides linked by covalent glycosidic bonds.
Structural Role of Cellulose
  • Cellulose is an unbranched polymer of β-glucose where straight chains form hydrogen bonds to assemble into rigid microfibrils in plant cell walls.
Structure of Triglycerides
  • Formed from one glycerol molecule condensed with three fatty acids via covalent ester bonds, serving as energy-dense, hydrophobic storage molecules.
Amphipathic Phospholipids
  • Phospholipids consist of a hydrophilic phosphate head and two hydrophobic fatty acid tails,
  • forming the stable structural matrix of biological membranes.
Condensation
  • A reaction that joins molecules and removes water.
Lipids
  • Concentrated energy, insulation, cell membranes.
Sucrose
  • The sugar mainly transported in phloem.
Covalent bond
  • A shared electron pair linking monomers.
Non-reducing sugar
  • A sugar that cannot reduce Benedict's reagent until hydrolysed.
Condensation reaction
  • A reaction joining molecules with the release of water.
Cellulose
  • A structural polysaccharide of β-glucose.
Triglyceride
  • A lipid made of glycerol and three fatty acids.
Polymer
  • A large molecule made of many repeating monomers.
Phospholipid
  • Glycerol, two fatty acids and a phosphate group, which is amphipathic.
Monosaccharide
  • A single sugar unit such as glucose, fructose or galactose.
Hydrophobic
  • Water-hating; non-polar and unable to dissolve in water.
Carbohydrate
  • A molecule of carbon, hydrogen and oxygen, including sugars, starch, glycogen and cellulose.
Carbon
  • Element with four valence electrons that forms the backbone of organic molecules.

Section 7 of 8Key terms

TermMeaning
StarchThe plant storage polysaccharide made of amylose and amylopectin.
GlycogenThe animal and fungal storage polysaccharide.
AmyloseAn unbranched helical chain of alpha-glucose.
AmylopectinA branched polymer of alpha-glucose.
PlastidA plant organelle such as a chloroplast that can store starch.
BranchingSide chains that create many free ends for enzymes.

Section 8 of 8Exam technique

1
Saying glycogen is the plant store — it is the animal and fungal store; starch is in plants.
2
Saying starch is one molecule — it is a mixture of amylose and amylopectin.
3
Saying amylose is branched — it is an unbranched helix.
4
Saying storage polysaccharides are soluble — they are insoluble so cause no osmotic effect.

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