10.1Chemistry of the Environment
Water and Water Pollution — Cambridge O Level Chemistry 5070 Revision Notes & Topical Questions
5 min read 13 parts Lesson 1 of 3
Lesson summary
Describe tests for water and its purity, substances in natural water, and the stages of water treatment.
Part 1 of 11Chemical tests for water
- Cobalt(II) chloride
- blue anhydrous CoCl2 turns pink with water.
- Equation
- CoCl2(s) + 6H2O(l) ⇌ CoCl2·6H2O(s).
- Form
- often used as cobalt chloride paper.
- Copper(II) sulfate
- white anhydrous CuSO4 turns blue with water.
- Equation
- CuSO4(s) + 5H2O(l) ⇌ CuSO4·5H2O(s).
- Note
- these tests show water is present, not that it is pure.
Part 2 of 11Purity of water
- Pure substances
- melt and boil at sharp, specific temperatures.
- Water
- boils at 100 °C and melts at 0 °C.
- Mixtures
- melt and boil over a range of temperatures.
- Impurities in water
- raise the boiling point and lower the melting point.
- Use
- melting and boiling data show whether water is pure.
- Distilled water
- water that is vaporised and condensed again, containing very few impurities.
- Practical use
- used in chemistry because tap water has impurities that can interfere with reactions.
Part 3 of 11Uses and natural sources of water
- Domestic
- drinking, cooking, gardening and sanitation.
- Agricultural
- drink for animals and watering crops.
- Industrial
- solvent, coolant and steam for generating electricity.
- Sources
- lakes, rivers and groundwater.
- Aquifer
- a rock that stores water.
Part 4 of 11Substances in natural water
- List
- dissolved oxygen, metal compounds, plastics, sewage, harmful microbes, nitrates from fertilisers and phosphates from fertilisers and detergents.
- Entry
- rain washes many of these into lakes, rivers and groundwater.
- Origin
- some are natural but many come from human activity.
- Caution
- natural water is not automatically clean.
Part 5 of 11Beneficial and harmful substances
| Substance | Beneficial effect | Harmful effect |
|---|---|---|
| Dissolved oxygen | Essential for aquatic life | — |
| Metal compounds | Calcium and magnesium provide essential minerals | Lead, arsenic, mercury and aluminium compounds are toxic |
| Plastics | — | Trap or starve aquatic animals |
| Sewage | — | Contains microbes that cause disease |
| Nitrates and phosphates | — | Promote plant growth that removes oxygen, causing eutrophication |
Part 6 of 11Stages of water treatment
- Water is taken from rivers, reservoirs or groundwater.
- Sedimentationwater stands in tanks and mud and sand sink to the bottom.
- Filtrationlayers of sand and gravel trap smaller particles.
- Carbon (charcoal) filterremoves tastes and odours.
- Chlorinationchlorine is added to kill bacteria and microorganisms.
- Why chlorine
- microbes are too small for filters.
- Diseases prevented
- cholera and typhoid.
- Impurities
- insoluble ones include soil and plant matter, soluble ones include dissolved calcium and metal compounds.
- Exam focus
- state the purpose of each stage.
Part 7 of 11Examples of exam reasoning
- Test for water
- use the colour change of anhydrous copper(II) sulfate from white to blue or cobalt chloride paper from blue to pink.
- Purity
- a pure sample has a sharp fixed boiling point, so a range shows a mixture.
- Distillation
- the method for making distilled water.
- Treatment purposes
- link each stage to its job.
- Sedimentation
- removes large solids.
- Filtration
- removes small solids.
- Charcoal
- removes taste and smell.
- Chlorine
- kills microbes.
Part 8 of 11Water pollution sources
| Source | Pollutant | Problem |
|---|---|---|
| Fertilisers | Nitrates and phosphates | Excess plant growth and loss of oxygen |
| Detergents | Phosphates | Excess plant growth |
| Industrial waste | Metal compounds | Toxic to living things |
| Sewage | Microbes | Disease such as cholera and typhoid |
| Litter | Plastics | Harm to aquatic animals |
Part 9 of 11Key facts to recall
- Water tests
- cobalt chloride blue to pink and copper sulfate white to blue.
- Pure water
- boils at exactly 100 °C and melts at 0 °C.
- Sedimentation then filtration then chlorination
- the usual order of treatment.
Part 10 of 11Why water must be treated
- Safety
- untreated water can carry microbes that cause disease.
- Taste
- some dissolved substances and organic matter give an unpleasant taste or smell.
- Result
- the stages remove solids, tastes and microbes in turn.
Part 11 of 11Worked examples
Describe a chemical test for water. [2]2 marks
- Add the substance to anhydrous copper(II) sulfate.
- It turns from white to blue.
A liquid boils at 102 °C. What does this show? [2]2 marks
- It is not pure water.
- Impurities raise the boiling point.
State the purpose of chlorination. [1]1 mark
- To kill bacteria and other microorganisms.
Explain why fertiliser run-off harms aquatic life. [2]2 marks
- Nitrates and phosphates promote growth of aquatic plants.
- This deoxygenates the water, which can damage aquatic life.
Key terms
| Term | Meaning |
|---|---|
| Anhydrous | Containing no water of crystallisation. |
| Distilled water | Water that has been vaporised and condensed, with few impurities. |
| Aquifer | A rock that stores water underground. |
| Sedimentation | Particles settling to the bottom of a liquid under gravity. |
| Chlorination | Adding chlorine to kill microorganisms. |
| Eutrophication | Damage to water bodies caused by excess nutrients leading to oxygen loss. |
Avoid these mistakes
- Saying the cobalt chloride test proves the water is pure — it only shows water is present.
- Saying filtration removes bacteria — chlorine does that.
- Saying all metal compounds in water are harmful — some are essential.
- Saying impurities lower the boiling point — they raise it.
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