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2.2The Particulate Nature of Matter

Elements, compounds and mixtures — Combined Science 0653 - Chemistry Revision Notes & Topical Questions

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2.2 Elements, compounds and mixtures — COMBINED SCIENCE (CHEMISTRY) notes: Define elements, compounds and mixtures and distinguish them by composition, bonding and separation.Element — = substance made of atoms that all have the same number of protons and that cannot be split int…

  • Fixed ratio
  • Properties
  • Proportions
  • Physical method
  • Pure substance
  • Number — there are about 118 elements in the Periodic Table

Section 1 of 14Elements

Element
  • = substance made of atoms that all have the same number of protons and that cannot be split into anything simpler by chemical means.
Number
  • Number there are about 118 elements in the Periodic Table.
Examples
  • Examples iron, oxygen and sodium are elements.

Section 2 of 14Compounds

Compound
  • = pure substance made of two or more elements chemically combined.
Fixed ratio
  • Fixed ratio the elements are always combined in the same proportions, such as H2O for water.
Properties
  • Properties a compound has properties different from its elements.
  • Sodium chloride is unlike sodium or chlorine.
Separation
  • Separation a compound can only be split into its elements by a chemical reaction.
Examples
  • Examples copper(II) sulfate, calcium carbonate and carbon dioxide.

Section 3 of 14Mixtures

Mixture
  • = two or more substances that are not chemically combined.
Proportions
  • Proportions a mixture can have any proportions.
Properties
  • Properties each part keeps its own properties.
  • Iron filings in sand stay magnetic.
Separation
  • Separation a mixture is separated by physical methods such as filtration, evaporation and distillation.
Examples
  • Examples sand and water, oil and water, air.

Section 4 of 14Comparing the three types

FeatureElementCompoundMixture
Made ofOne type of atomTwo or more elementsTwo or more substances
Chemically joined—YesNo
Fixed proportions—YesNo
PropertiesIts ownDifferent from its elementsEach part keeps its own
SeparationCannot be splitChemical reactionPhysical methods
ExamplesIron, oxygenWater, carbon dioxideAir, salty water

Section 5 of 14Common examples classified

Common examples classified
Air
  • Air is a mixture of gases.
Water
  • Water is a compound.
Oxygen
  • Oxygen is an element.

Section 6 of 14More from the specification

1Noble gases
  • The Group 0 elements, which are unreactive monatomic gases
2Atomic number (Proton number)
  • The number of protons located in the nucleus of an atom, defining its chemical identity.
3Electronic configuration
  • The specific arrangement of electrons in successive energy shells surrounding the atomic nucleus.
4Relative atomic mass (Ar)
  • The weighted average mass of naturally occurring atoms of an element relative to 1/12th the mass of a carbon-12 atom.
5Isotopes
  • Atoms of the same element containing identical numbers of protons and electrons but differing numbers of neutrons.
6Valence shell
  • The outermost electron shell whose electron configuration determines chemical reactivity and bonding capacity.
7Symbol
  • Shorthand for an element, e.g. Na.
8Electronic configuration
  • The number of electrons in each shell, written with commas.
9Outer shell
  • Highest-energy occupied shell.
10Electron
  • Negative particle moving around the nucleus.
11Neutron
  • Neutral particle in the nucleus.
12Isotopes
  • Atoms of the same element with the same number of protons but different numbers of neutrons.
13Isotope
  • Atoms of an element with different numbers of neutrons.
14Nucleus
  • Central part of an atom with protons and neutrons.
15Shell
  • An energy level around the nucleus that holds a limited number of electrons.
16Hydrogen
  • A gas that gives a squeaky pop with a lighted splint.

Section 7 of 14Particle diagrams

Particle diagrams
Element
  • Element all particles are the same type of atom.
Compound
  • Compound particles are groups of different atoms joined together, all groups identical.
Mixture
  • Mixture different particles are present that are not joined, such as separate atoms and molecules.

Section 8 of 14Making a compound from elements

Iron and sulfur
  • Iron and sulfur heating the mixture makes the compound iron sulfide.
  • Before heating the mixture can be separated with a magnet.
  • After heating the product is not magnetic because a new substance has formed.
Evidence
  • Evidence a compound needs a chemical reaction to form, often with heat or light given out.

Section 9 of 14Physical separation of mixtures

MethodSeparatesExample
FiltrationInsoluble solid from a liquidSand from water
Evaporation / crystallisationSoluble solid from a solutionSalt from salt solution
Simple distillationSolvent from a solutionWater from salty water
Fractional distillationMiscible liquidsEthanol and water
MagnetMagnetic solid from non-magneticIron filings from sand

Section 10 of 14Getting pure salt from rock salt

1
Crush the rock salt.
2
Stir it into warm water so the salt dissolves.
3
Filter the mixture; sand stays on the filter paper as residue.
4
Heat the filtrate in an evaporating basin until the solution is saturated.
5
Leave it to cool so that salt crystals form, then filter and dry them.

Section 11 of 14Obtaining a soluble solid from an insoluble one

  • Method
    • dissolve the soluble solid, filter off the insoluble solid, then evaporate and crystallise the filtrate.
    • Calcium sulfate is insoluble and magnesium chloride is soluble in water.
    • Water dissolves the magnesium chloride and the calcium sulfate stays as the residue.

Section 12 of 14More from the specification

More from the specification
Subatomic Structure and Atomic Numbers
  • An atom consists of a central nucleus containing positively charged protons and neutral neutrons, surrounded by negatively charged electrons arranged in electronic shells;
    • the atomic number equals the number of protons.
Definition and Properties of Isotopes
  • Isotopes are atoms of the same chemical element possessing identical atomic numbers but different nucleon numbers due to differing counts of neutrons.
    • (same number of protons and electrons)
Relative Atomic Mass Calculation
  • The relative atomic mass (Ar) of an element listed in the periodic table is the weighted average mass of naturally occurring isotopes relative to 1/12th the mass of a carbon-12 atom: Ar = Σ / 100.
    • (isotope mass × abundance)
Electronic Configurations and Valence Shells
  • The arrangement of electrons across principal electron shells dictates an element's chemical properties, with elements in the same periodic table group possessing identical numbers of outer-shell valence electrons.
Periodic
  • Describing properties that repeat at regular intervals along the table
Noble gases
  • The Group 0 elements, which are unreactive monatomic gases
Shell
  • An energy level around the nucleus that holds a limited number of electrons.
Hydrogen
  • A gas that gives a squeaky pop with a lighted splint.
Symbol
  • Shorthand for an element, e.g. Na.
Electronic configuration
  • The number of electrons in each shell, written with commas.
Outer shell
  • Highest-energy occupied shell.
Electron shell
  • An energy level for electrons.
Electron
  • Negative particle moving around the nucleus.
Proton
  • Positive particle in the nucleus.
Neutron
  • Neutral particle in the nucleus.
Isotopes
  • Atoms of the same element with the same number of protons but different numbers of neutrons.
Isotope
  • Atoms of an element with different numbers of neutrons.
Nucleus
  • Central part of an atom with protons and neutrons.

Section 13 of 14Key terms

TermMeaning
ElementSubstance made of atoms with the same number of protons.
CompoundPure substance of two or more elements chemically combined.
MixtureSubstances together but not chemically combined.
AtomSmallest particle of an element.
Physical methodSeparation method that does not make new substances.
Pure substanceSubstance containing only one type of particle.
TermMeaning
ResidueSolid left on the filter paper.
FiltrateLiquid that passes through the filter paper.
CrystallisationFormation of crystals from a saturated solution on cooling.
Saturated solutionSolution that cannot dissolve any more solute at that temperature.
InsolubleNot able to dissolve in a solvent.
SolubleAble to dissolve in a solvent.

Section 14 of 14Exam technique

1
Saying a mixture and a compound are the same — a compound has chemically combined elements in a fixed ratio.
2
Saying a compound keeps the properties of its elements — its properties are different.
3
Saying air is a compound — it is a mixture.
4
Saying compounds are separated by filtering — a chemical reaction is needed.
1
Saying the iron and sulfur mixture and iron sulfide are the same — the compound is a new substance.
2
Boiling off all the water — crystals are formed by cooling a saturated solution.
3
Mixing up residue and filtrate.
4
Thinking a compound can be separated by filtering.

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