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4.1.5Predicting and Identifying Reactions and Products

Predicting Reactivity — OCR Gateway GCSE Combined Science A J250 - Chemistry Revision Notes & Topical Questions

5 min read 6 parts Lesson 6 of 7

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Part 1 of 4Reactivity patterns in the periodic table

Metals in Groups 1 and 2
  • Metals in Groups 1 and 2 These are the most reactive metals, and their reactivity increases going down each group.
  • Their atoms lose their outer electrons more easily the further those electrons are from the nucleus.
Non-metals in Group 7
  • Non-metals in Group 7 The halogens are reactive non-metals, but their reactivity decreases going down the group.
  • A larger atom attracts an extra electron less strongly, so gaining one is harder.
Group 0
  • Group 0 The noble gases have full outer shells and are generally unreactive.
Compound formation
  • Compound formation Reactive metals combine with reactive non-metals to form ionic compounds, for example sodium and chlorine give sodium chloride.

Part 2 of 4Group 1 compared with transition metals

PropertyGroup 1 metalsTransition metals
Hardness and strengthSoft and easy to cutHard and strong
DensityLow; the first three float on waterHigh
Melting pointLow, for example potassium melts at about 64 °CHigh, for example titanium melts at about 1700 °C
Ion chargeAlways 1+Variable, for example Fe2+ and Fe3+
ReactivityVery high; react quickly with water, oxygen and halogensMuch lower; react slowly or not at all

Part 3 of 4Reaction with oxygen: a case study

1Cut sodium or potassium
  • Cut sodium or potassium The freshly cut surface is bright and shiny.
2Oxygen in the air reacts
  • Oxygen in the air reacts The metal combines with oxygen to form a metal oxide on the surface.
3Dull coating within seconds
  • Dull coating within seconds The shine disappears because the surface is now covered by the dull oxide.
4Compare with iron
  • Compare with iron Iron takes weeks to form rust and needs water as well as oxygen, which shows the transition metal is far less reactive.

Part 4 of 4Using the patterns to identify an element

1
Look at the clues given: a soft metal that floats on water and reacts violently suggests Group 1.
2
Use the ion charge to decide the group: an element that only ever forms 1+ ions is an alkali metal, while variable charges point to a transition metal.
3
Compare the data with neighbouring elements in the same group and extend the trend, for example a melting point that should lie between two known values.
4
State your prediction and support it with the pattern, such as increasing reactivity down the group.
5
Remember that unreactive gases with full outer shells belong to Group 0.

Key terms

TermMeaning
Transition metalA metal in the central block of the periodic table, typically hard, dense and with variable ion charges.
Alkali metalA very reactive, soft Group 1 metal that forms 1+ ions.
HalogenA reactive non-metal in Group 7.
Variable chargeThe ability of an element to form ions with more than one possible charge, as iron does.
Ionic compoundA compound formed when a metal transfers electrons to a non-metal, forming oppositely charged ions.

Avoid these mistakes

1
Assuming reactivity increases down every group: it increases down Groups 1 and 2 but decreases down Group 7.
2
Saying transition metals form only one type of ion: many have more than one charge.
3
Describing transition metals as soft and light: that describes Group 1; transition metals are hard and dense.
4
Claiming iron rusts as quickly as sodium tarnishes: rusting is slow and needs both oxygen and water.

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