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CHEMISTRY · Stage 7 · Chapter 1: The Particle Model and States of Matter

Chemistry 1.4 Changes of state — Evaporating, Boiling, and Condensing

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1.4 Changes of state — Evaporating, Boiling, and Condensing — Alhussan International Academy — Chemistry (Stages 7–9) notes: Define and compare evaporation, boiling and condensation and explain them using the particle model.Six changes — melting (solid to liquid), freezing (liqui…

  • Candle wax
  • Particle explanation
  • Higher temperature
  • Larger surface area
  • Moving air
  • Low humidity

Section 1 of 7Changes of state

  • Six changes
    • melting, freezing (liquid to solid), evaporating and boiling (liquid to gas), condensing (gas to liquid) and the reverse of evaporating for gas to liquid.
      • (solid to liquid)
    • Most substances change state, not only water.
  • Candle wax
    • it shows several changes, since near a burning wick solid wax melts to liquid wax and some liquid wax evaporates to wax in the gas state,
    • which is the part that burns.
  • Particles
    • when a substance changes state its particles stay the same and do not get bigger or smaller.
    • What changes is how the particles are arranged, how they move and how far apart they are.

Section 2 of 7Evaporation

  • Evaporation = the change of state from liquid to gas that can happen at any temperature below the boiling point.
  • Where
    • it happens only at the surface of the liquid.
  • Particle explanation
    • in a liquid the particles touch and slide over each other, and some move faster than others.
    • The faster particles near the surface have enough kinetic energy to overcome the attraction of their neighbours and leave the surface.
    • They separate from each other and form gas.
  • Cooling
    • the fastest particles leave, so the average energy of those left falls and the liquid cools, which is why sweating cools the body.

Section 3 of 7Factors that speed up evaporation

  • Higher temperature
    • more particles have enough energy to escape.
  • Larger surface area
    • more particles are at the surface, so wet washing spread out dries faster than washing in a heap.
  • Moving air
    • wind carries escaped particles away so they cannot return to the liquid.
  • Low humidity
    • dry air can accept more vapour, so fewer particles return.

Section 4 of 7Boiling

1Boiling
= the change of state from liquid to gas at the boiling point, which happens only if the liquid is hot enough.
2Bubbles3 points
  • bubbles of the substance in the gas state form everywhere in the liquid, rise to the surface and escape.
  • In the liquid the particles touch, while inside the bubbles they are spread far apart.
  • The bubbles are water vapour, which is an invisible gas, and visible steam is condensed droplets.
3Boiling point2 points
  • the temperature at which a substance boils, different for each substance.
  • It is high if the particles hold together strongly and low if they hold together weakly.
4Constant temperature2 points
  • energy from a heater does not raise the temperature while boiling, because it is used to break the forces between particles.
  • Pure water stays at 100 °C at normal pressure until all the liquid has become gas.
FeatureEvaporationBoiling
TemperatureAny temperature below boiling pointOnly at the boiling point
Where it happensSurface onlyThroughout the liquid
SpeedSlowFast, with bubbles

Section 5 of 7Making conclusions from boiling point data

  • Gas at room temperature
    • a substance with a boiling point below 20 °C, such as nitrogen at −196 °C, is a gas at room temperature.
  • Strong attraction
    • a substance with a very high boiling point, such as copper or diamond, has particles held together very strongly.
  • Comparing
    • ethanol boils at 78 °C, water at 100 °C and mercury at 357 °C.

Section 6 of 7Condensation

  • Condensing = the change of state from gas to liquid, which happens at any temperature below the boiling point and is the reverse of evaporation.
  • Particle explanation
    • when a gas is cooled its particles lose kinetic energy and slow down.
    • They get closer until they touch, because the attractive forces can now hold them together.
    • Energy is released to the surroundings.
  • Everyday example
    • warm, moist air touching a cold surface such as a bathroom mirror or cold glass of drink leaves droplets of water.
    • The water condensed from vapour in the air and did not pass through the glass.
  • Condenser
    • a tube cooled by water cools vapour from a boiling liquid so it drips out as a liquid, which is the basis of distillation.

Section 7 of 7Physical change

  • Reversible
    • a change of state is a physical change that can be reversed, because only arrangement, spacing and movement change.

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