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2.1.6Inorganic Chemistry: Part 1

Practical: Investigate Metals Reacting with Acids — Edexcel International GCSE Science Double Award (Modular) - Chemistry Unit 1 Revision Notes & Topical Questions

5 min read 6 parts Lesson 7 of 15

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Part 1 of 4Aim and variables

Aim
  • Aim To compare how magnesium, zinc and iron react with dilute hydrochloric acid and dilute sulfuric acid.
Variables
  • Variables The independent variable is the type of metal;
    • the dependent variable is how vigorously it reacts (bubbling rate, heat, time to dissolve).
  • Control the acid volume, concentration, temperature and the size or surface area of each metal sample.
Safety
  • Safety Wear eye protection throughout because acid splashes damage eyes.
  • Keep flames away from the hydrogen being produced except when carrying out the splint test on a small sample.

Part 2 of 4Method

1
Use a small measuring cylinder to put about 5 cm3 of dilute hydrochloric acid into each of three test tubes in a rack.
2
Add a piece of magnesium ribbon about 1 cm long to the first tube and record what you see.
3
Hold a lighted splint at the mouth of the tube to test any gas given off.
4
Add iron filings to the second tube and zinc granules to the third, then observe and test for gas in the same way.
5
Rinse out the tubes and repeat the whole experiment with dilute sulfuric acid.
6
Record all observations in a results table.

Part 3 of 4Typical results

MetalWith hydrochloric acidWith sulfuric acid
MagnesiumDissolves quickly, tube warms, gas pops with a lighted splint, colourless solution remainsRapid bubbling, splint pops, metal dissolves
ZincSteady bubbles, metal slowly dissolvesGas given off slowly, metal dissolves to a colourless solution
IronVery slow bubblingSlow reaction with small bubbles

Part 4 of 4Conclusions and equations

Mg, Zn, Fe in order
Order of reactivity
  • Order of reactivity Magnesium reacts fastest, then zinc, then iron, so the reactivity order is magnesium, zinc, iron.
Products
  • Products With each acid, the products are a salt solution and hydrogen gas.
  • Hydrogen is confirmed by the squeaky pop with a lighted splint.
Equations
  • Equations Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)
  • Zn(s) + H2SO4(aq) → ZnSO4(aq) + H2(g)
  • Fe(s) + 2HCl(aq) → FeCl2(aq) + H2(g)

Key terms

TermMeaning
Dilute acidAn acid with a low concentration of acid dissolved in water.
Lighted splintA burning wooden splint used to test for hydrogen gas.
Surface areaThe total area of metal exposed to the acid; a bigger area speeds up a reaction.
Dependent variableThe quantity measured to see the effect of the change.
Salt solutionThe solution of a metal chloride or sulfate left after the metal reacts.

Avoid these mistakes

1
Using different sizes of metal pieces, so the comparison is unfair because the surface area is not controlled.
2
Describing the test for hydrogen as a glowing splint relighting; that is the test for oxygen. Hydrogen gives a squeaky pop with a lighted splint.
3
Saying the metal 'melts' in acid. It reacts and dissolves to form a salt.
4
Forgetting that the reaction with sulfuric acid gives a sulfate while hydrochloric acid gives a chloride.

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