2.2.1Inorganic Chemistry: Part 1
Indicators — Edexcel International GCSE Science Double Award (Modular) - Chemistry Unit 1 Revision Notes & Topical Questions
5 min read 7 parts Lesson 8 of 15
Part 1 of 5Two-colour indicators
| Indicator | Colour in acid | Colour in alkali |
|---|---|---|
| Litmus | Red | Blue |
| Phenolphthalein | Colourless | Pink |
| Methyl orange | Red | Yellow |
Part 2 of 5Choosing an indicator
Litmus
- Litmus Extracted from lichens, litmus is best used as paper (red or blue) for dipping into solutions or testing gases.
- It changes colour gradually through purple in neutral solution, so it is not suitable for titrations.
Synthetic indicators
- Synthetic indicators Phenolphthalein and methyl orange are organic compounds that change colour sharply over a narrow pH range.
- This sharp change makes them ideal for showing the end-point of a titration.
Universal indicator
- Universal indicator A mixture of dyes that gives a range of colours across the pH scale.
- It gives only an approximate pH, so it is not suitable for titration.
Part 3 of 5The pH scale
1pH 0 to 3
- pH 0 to 3 Strongly acidic; values below 1 are extremely acidic.
2pH 4 to 6
- pH 4 to 6 Weakly acidic.
3pH 7
- pH 7 Neutral: neither acidic nor alkaline, as in pure water.
4pH 8 to 10
- pH 8 to 10 Weakly alkaline.
5pH 11 to 14
- pH 11 to 14 Strongly alkaline.
Part 4 of 5Why indicators change colour
Indicator behaviour
Weak acids and bases
- Weak acids and bases Most indicators are themselves weak acids or bases whose molecules and ions have different colours.
- Adding acid or alkali shifts the balance between the two forms, so the observed colour changes.
Narrow range
- Narrow range A synthetic indicator switches colour over only about two pH units, which is why it marks the end-point of a titration sharply.
Natural sources
- Natural sources Plants such as red cabbage and many flowers contain pigments that act as indicators,
- but their colour changes are usually gradual and less precise.
Practical use
- Practical use Phenolphthalein is used when titrating a strong alkali against a strong acid,
- while methyl orange suits titrations of acids with weaker alkalis such as sodium carbonate.
Part 5 of 5Using universal indicator
1
Add a few drops of universal indicator solution to a small sample of the unknown liquid.
2
Swirl gently and note the colour that develops.
3
Compare the colour with the manufacturer's chart to read off an approximate pH.
4
Decide whether the solution is acidic (pH below 7), neutral (7) or alkaline (above 7), and how strongly.
Key terms
| Term | Meaning |
|---|---|
| Indicator | A substance that changes colour depending on whether a solution is acidic or alkaline. |
| pH | A scale from 0 to 14 that shows how acidic or alkaline a solution is. |
| End-point | The moment in a titration when the indicator changes colour, showing neutralisation. |
| Neutral | Having a pH of exactly 7. |
| Alkali | A soluble base that forms hydroxide ions in water and has a pH above 7. |
Avoid these mistakes
1
Choosing universal indicator for a titration. It changes colour gradually, so the end-point cannot be seen clearly.
2
Mixing up the colours of methyl orange: it is red in acid and yellow in alkali.
3
Stating that litmus turns purple in alkali. Purple is the transition colour in neutral solution; alkali turns it blue.
4
Assuming a lower pH is more alkaline. The lower the pH, the more acidic the solution.
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