8.4.2The Periodic Table
Oxidation and Reduction in Terms of Electrons — Cambridge IGCSE Chemistry 0620 Revision Notes & Topical Questions
5 min read 5 parts Lesson 14 of 23 Unit quiz
Curriculum Equation Key قوانين الرقم الهيدروجيني والاتزان الأيوني - pH & Acid-Base Equilibrium FormulasFast Exam Solution
pH = -log[H⁺] | pOH = -log[OH⁻] | pH + pOH = 14 | [H⁺][OH⁻] = 10⁻¹⁴
Word Equation & Conditions: الرقم الهيدروجيني = -لوغاريتم تركيز أيون الهيدروجين | pH + pOH = 14
Location & Specifications: الاتزان الأيوني، كيمياء 3 ثانوي، التحصيلي، و AP Chemistry.
Part 1 of 5Electron Definitions
Electron transfer gives the more general definition of redox reactions.
Oxidation
- Oxidation Oxidation is the loss of electrons, so a species that loses electrons has been oxidised.
Reduction
- Reduction Reduction is the gain of electrons, so a species that gains electrons has been reduced.
OILRIG
- OILRIG Oxidation Is Loss, Reduction Is Gain, a simple way to remember which definition is which.
Redox
- Redox When one species loses electrons and another gains them in the same reaction, the reaction is a redox reaction.
Part 2 of 5A Displacement Example
Iron reacting with copper(II) sulfate solution shows electron transfer clearly.
1
Iron reacts with copper(II) sulfate solution: Fe(s) + CuSO₄(aq) → FeSO₄(aq) + Cu(s).
2
Sulfate ions do not change, so they are spectator ions, leaving the ionic equation Fe(s) + Cu²⁺(aq) → Fe²⁺(aq) + Cu(s).
3
The iron atom loses two electrons to form Fe²⁺, so the iron is oxidised.
4
The copper(II) ion gains two electrons to form a copper atom, so the copper(II) ion is reduced.
Part 3 of 5Identifying the Changes
A systematic method works for any equation.
Identifying the Changes
Step one
- Step one Write the change for each species, noting how many electrons are lost or gained.
Step two
- Step two Label each change as oxidation (loss of electrons) or reduction (gain of electrons).
Charge clue
- Charge clue A species whose positive charge increases has lost electrons, and one whose positive charge decreases has gained them.
Check
- Check In Mg + Cu²⁺ → Mg²⁺ + Cu, magnesium loses two electrons and copper(II) ions gain two electrons.
Part 4 of 5Worked Example
Question Which species is reduced in the reaction Mg(s) + Cu²⁺(aq) → Mg²⁺(aq) + Cu(s)?
- Mg → Mg²⁺each magnesium atom loses two electrons, so magnesium is oxidised.
- Cu²⁺ → Cueach copper(II) ion gains two electrons, so the copper(II) ion is reduced.
- The species that gains electrons is the one that is reduced.
Answer The copper(II) ion, Cu²⁺, is reduced.
Part 5 of 5Exam Checklist & Tips
8.4.2 – Key Points for the Exam
- Electron A negatively charged particle that can be lost or gained in a reaction.
- Spectator ion An ion that is unchanged by a reaction and is left out of the ionic equation.
- Ionic equation An equation showing only the ions and species that take part in a reaction.
- OILRIG A memory aid meaning oxidation is loss and reduction is gain of electrons.
Common Mistakes
- Using the wrong definitionoxidation is the loss of electrons, not the gain.
- Naming copper as reduced when the copper(II) ion is reduced; name the species precisely.
- Leaving spectator ions in the equation when an ionic equation is requested.
- Confusing the loss of electrons with the loss of oxygen, which is a different definition.
Last updated:
\n