4.8.2Electrochemistry
Disposal of Addition Polymers — Cambridge IGCSE Chemistry 0620 Revision Notes & Topical Questions
5 min read 4 parts Lesson 16 of 20 Unit quiz
Part 1 of 4Why Polymers Persist

Strong bonds
- Addition polymers are built from strong C–C bonds, so they are chemically unreactive.
Non-biodegradable
- Micro-organisms cannot break down most addition polymers, so they are described as non-biodegradable.
Inert
- Addition polymers do not react easily with water, acids or oxygen in the environment, so they persist.
Accumulation
- Because they last, polymers build up in the environment and in landfill sites.
Reduction
- Recycling and reducing single-use plastics lowers the amount of polymer waste sent for disposal.
Part 2 of 4Landfill and Incineration
Landfill and Incineration
Landfill
- Waste polymers are buried in landfill sites, which uses valuable land that fills up quickly.
Non-decomposition
- Non-biodegradable polymers do not decompose, so they remain in landfill for a very long time.
Heat
- Burning polymers releases a large amount of heat energy, which can be used to generate power.
Carbon dioxide
- Burning polymers produces carbon dioxide, a greenhouse gas that contributes to climate change.
Chlorine
- PVC releases toxic hydrogen chloride gas when it is burned.
Part 3 of 4Products of Incineration
1
Complete combustion of a hydrocarbon polymer gives carbon dioxide and water as the main products.
2
Incomplete combustion in a poor air supply produces carbon monoxide, a toxic gas that reduces the blood's oxygen-carrying capacity.
3
Polymers containing chlorine, such as PVC, release hydrogen chloride gas when burned.
4
Incinerators with good design and filtration can capture some harmful gases before they are released.
Part 4 of 4Exam Checklist & Tips
4.8.2 – Key Points for the Exam
- Non-biodegradable Not broken down by micro-organisms in the environment.
- Landfill A site where waste is buried in the ground.
- Incineration Burning waste materials at high temperature.
- Greenhouse gas A gas, such as carbon dioxide, that traps heat in the atmosphere.
- Hydrogen chloride A toxic gas produced when chlorine-containing polymers such as PVC are burned.
Common Mistakes
- Saying addition polymers biodegrade quickly in landfill, as paper does.
- Forgetting that burning PVC releases hydrogen chloride as well as carbon dioxide.
- Claiming that burning polymers causes no pollution because it releases useful energy.
- Treating incomplete combustion as harmless; it produces toxic carbon monoxide.
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