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CHEMISTRY · Stage 9 · Chapter 11: Patterns in the Periodic Table

Chemistry 11.3 Using density — Displacement Method for Irregular Solids

5 min read 6 parts Lesson 3 of 7

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11.3 Using density — Displacement Method for Irregular Solids — Alhussan International Academy — Chemistry (Stages 7–9) notes: Find the volume of an irregular solid by displacement, calculate its density, and describe how al-Biruni used density to identify gemstones.Irregular sol…

  • Identifying the material
  • Assumptions
  • Floating objects
  • Narrow cylinder
  • Air bubbles
  • Thin thread

Part 1 of 6The problem with irregular solids

  • Irregular solid — a stone has no regular shape, so its volume cannot be found by multiplying length, width and height.
  • Displacement — when an object is fully submerged it pushes aside a volume of water equal to its own volume.
    • Measuring the water pushed aside gives the volume of the solid.

Part 2 of 6Method with a measuring cylinder

  1. Find the mass of the solid on a balance and record it in grams.
  2. Half-fill a measuring cylinder with water and record the volume V1, reading the bottom of the meniscus at eye level.
  3. Tie the solid to a thread and lower it gently into the water so it is fully covered and no water splashes out.
  4. Record the new volume V2.
  5. Volume of the solid = V2 - V1.
  6. Density = mass ÷ volume.
  • Identifying the material — compare the result with a data table, for example 8.9 g/cm3 suggests copper.

Part 3 of 6Method with a eureka can

  1. Fill a displacement (eureka) can until water flows out of the spout and wait until dripping stops.
  2. Place a measuring cylinder under the spout.
  3. Lower the solid in and collect the water that overflows.
  4. The volume of the overflow is the volume of the solid.
  • Assumptions — the solid does not dissolve or absorb water, and it sinks.
  • Floating objects — tie a small weight to the object to push it under and allow for the volume of the weight.

Part 4 of 6Reducing errors

  • Meniscusread it at eye level to avoid parallax error.
  • Narrow cylinderuse one with small scale divisions for better precision.
  • Air bubblesremove any stuck to the solid.
  • Dry soliddry it before weighing.
  • Thin threadthick string adds to the volume.
  • Larger samplea larger volume change makes the percentage error smaller.
  • Absorbent solidsa material such as brick absorbs water and gives a false result, so coat it in wax.
  • Repeatsrepeat the measurement and calculate a mean density.

Part 5 of 6Al-Biruni and the density of gemstones

  • Al-Biruni — more than 1000 years ago Abu Rayhan al-Biruni, born in what is now Uzbekistan, became a great scientist and mathematician.
    • He wrote on astronomy, geology and medicines and built on earlier scientists to design new instruments for accurate measurements.
  • Problem — quartz is common and cheap, and a cheating trader could pretend a lump of quartz is diamond, so al-Biruni asked how to identify gemstones reliably.
  • Idea — use density, but gemstones have irregular shapes, so volume was difficult to measure.
  • Apparatus — a flask with a side arm.
    • He filled the flask until water overflowed through the side arm into a beaker, then emptied the beaker and put it under the side arm again.
    • He lowered the gemstone into the flask and measured the volume of water that flowed into the beaker, which equals the volume of the gemstone.
  • Calculation — density = mass ÷ volume.
MaterialDensity calculated by al-Biruni (g/cm3)Modern value (g/cm3)
Quartz2.582.58
Ruby4.014.40
Pearl2.702.70
  • Precision — his measurements were very precise, and it was another 700 years before scientists in Europe could measure density as precisely.
  • Other properties — he also classified gemstones by hardness, colour, crystal shape and whether the gemstone splits white light into a rainbow.

Part 6 of 6Science building on science

  • Building on othersscientists build on others' work to develop scientific knowledge over time.
  • Todaymost scientists specialise in one area, work in teams and publish papers in journals that scientists around the world read.
  • Modern gemstone identificationscientists and jewellers still use a method like al-Biruni's, together with other techniques such as conductivity and how much a gemstone changes the direction of light.

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