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CHEMISTRY · Stage 9 · Chapter 11: Patterns in the Periodic Table

Chemistry 11.2 Explaining density — Particle Mass and Packing in Solids, Liquids and Gases

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11.2 Explaining density — Particle Mass and Packing in Solids, Liquids and Gases — Alhussan International Academy — Chemistry (Stages 7–9) notes: Explain why substances differ in density and why a substance has different densities in its three states, using the particle model and…

  • Two factors
  • Layers of liquids
  • Comparison
  • Prediction
  • Liquid and gas
  • Solid and liquid

Section 1 of 6What density depends on

  • Two factors
    • the density of a substance depends on the mass of its particles and on how closely packed the particles are.
  • Layers of liquids
    • honey (bottom), milk and oil (top) form separate layers because their densities differ, with honey the densest and oil the least dense.

Section 2 of 6Mass of the particles

  • Rule
    • in the solid state, substances with the heaviest particles have the greatest densities.
  • Metals
    • with the same type of packing, the metal with heavier atoms is denser.
MetalRelative mass of atomsDensity (g/cm3)
Magnesium241.8
Aluminium272.7
Gold19719
  • Comparison
    • gold atoms are about seven times as massive as aluminium atoms, and gold is about seven times denser.
  • Prediction
    • tungsten (atom mass 184) is predicted to be denser than chromium (atom mass 52).

Section 3 of 6Particle packing in the three states

StateParticle spacingDensity
SolidVery close, regular patternHigh
LiquidClose, random arrangementSlightly lower or similar
GasFar apartVery low
  • Liquid and gas
    • particles in a liquid are more closely packed than in a gas, so the liquid has a greater density.
    • 500 cm3 of steam has a smaller mass than 500 cm3 of liquid water because the particles are further apart in steam.
  • Solid and liquid
    • for most substances the solid is a little denser than the liquid because its particles are a little more closely packed.
  • Gas density
    • a gas is about a thousand times less dense than a liquid.

Section 4 of 6Changes of state and water

  • Melting and boiling
    • the mass is unchanged but the volume usually increases, so the density falls.
  • Water
    • it is unusual because ice is less dense than liquid water, since the molecules form an open structure when they freeze.
    • This is why ice floats and pipes can burst when water freezes inside them.
  • Heating a gas
    • the particles move faster and spread out, so a given mass occupies a larger volume and the density falls.
    • This is why warm air rises in a hot-air balloon.

Section 5 of 6The dried-peas analogy

  • Analogy = a comparison between one thing and another that helps to explain something.
  • Liquid model
    • peas in a jar touch each other without a pattern and slide randomly over each other when the jar is moved gently.
  • Gas model
    • shaking the jar hard moves the peas far apart.
    • A volume of 100 cm3 in the gas model has fewer particles, and so less mass, than in the liquid model, so the gas has a lower density.
  • Strength
    • it helps to explain density.
  • Limitation
    • you need to move the jar to move the peas, whereas real particles move themselves.

Section 6 of 6Everyday uses of density ideas

  • Floating and sinking
    • wood floats in water because its average density is lower, and a steel ball sinks because steel is denser.
    • Iron floats on mercury because mercury has a very high density.
  • Oil
    • it floats on water because it is less dense, so oil spills spread over the sea surface.
  • Balloons
    • hot-air balloons rise because heated air is less dense, and helium balloons float because helium is less dense than air.
  • Divers and life jackets
    • weight belts increase a diver's average density so they sink, and life jackets with air or foam reduce it so the wearer floats.
  • Earth's layers
    • a dense iron-rich core lies at the centre, surrounded by a less dense mantle and a thin, light crust.
  • Oceans
    • cold salty water is denser than warm fresh water and sinks, driving currents.

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