CHEMISTRY · Stage 9 · Chapter 11: Patterns in the Periodic Table
Chemistry 11.2 Explaining density — Particle Mass and Packing in Solids, Liquids and Gases
5 min read 6 parts Lesson 2 of 7
Lesson summary
11.2 Explaining density — Particle Mass and Packing in Solids, Liquids and Gases — Alhussan International Academy — Chemistry (Stages 7–9) notes: Explain why substances differ in density and why a substance has different densities in its three states, using the particle model and…
- Two factors
- Layers of liquids
- Comparison
- Prediction
- Liquid and gas
- Solid and liquid
Section 1 of 6What density depends on
- Two factors
- the density of a substance depends on the mass of its particles and on how closely packed the particles are.
- Layers of liquids
- honey (bottom), milk and oil (top) form separate layers because their densities differ, with honey the densest and oil the least dense.
Section 2 of 6Mass of the particles
- Rule
- in the solid state, substances with the heaviest particles have the greatest densities.
- Metals
- with the same type of packing, the metal with heavier atoms is denser.
| Metal | Relative mass of atoms | Density (g/cm3) |
|---|---|---|
| Magnesium | 24 | 1.8 |
| Aluminium | 27 | 2.7 |
| Gold | 197 | 19 |
- Comparison
- gold atoms are about seven times as massive as aluminium atoms, and gold is about seven times denser.
- Prediction
- tungsten (atom mass 184) is predicted to be denser than chromium (atom mass 52).
Section 3 of 6Particle packing in the three states
| State | Particle spacing | Density |
|---|---|---|
| Solid | Very close, regular pattern | High |
| Liquid | Close, random arrangement | Slightly lower or similar |
| Gas | Far apart | Very low |
- Liquid and gas
- particles in a liquid are more closely packed than in a gas, so the liquid has a greater density.
- 500 cm3 of steam has a smaller mass than 500 cm3 of liquid water because the particles are further apart in steam.
- Solid and liquid
- for most substances the solid is a little denser than the liquid because its particles are a little more closely packed.
- Gas density
- a gas is about a thousand times less dense than a liquid.
Section 4 of 6Changes of state and water
- Melting and boiling
- the mass is unchanged but the volume usually increases, so the density falls.
- Water
- it is unusual because ice is less dense than liquid water, since the molecules form an open structure when they freeze.
- This is why ice floats and pipes can burst when water freezes inside them.
- Heating a gas
- the particles move faster and spread out, so a given mass occupies a larger volume and the density falls.
- This is why warm air rises in a hot-air balloon.
Section 5 of 6The dried-peas analogy
- Analogy = a comparison between one thing and another that helps to explain something.
- Liquid model
- peas in a jar touch each other without a pattern and slide randomly over each other when the jar is moved gently.
- Gas model
- shaking the jar hard moves the peas far apart.
- A volume of 100 cm3 in the gas model has fewer particles, and so less mass, than in the liquid model, so the gas has a lower density.
- Strength
- it helps to explain density.
- Limitation
- you need to move the jar to move the peas, whereas real particles move themselves.
Section 6 of 6Everyday uses of density ideas
- Floating and sinking
- wood floats in water because its average density is lower, and a steel ball sinks because steel is denser.
- Iron floats on mercury because mercury has a very high density.
- Oil
- it floats on water because it is less dense, so oil spills spread over the sea surface.
- Balloons
- hot-air balloons rise because heated air is less dense, and helium balloons float because helium is less dense than air.
- Divers and life jackets
- weight belts increase a diver's average density so they sink, and life jackets with air or foam reduce it so the wearer floats.
- Earth's layers
- a dense iron-rich core lies at the centre, surrounded by a less dense mantle and a thin, light crust.
- Oceans
- cold salty water is denser than warm fresh water and sinks, driving currents.
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