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CHEMISTRY · Stage 9 · Chapter 11: Patterns in the Periodic Table

Chemistry 11.4 The periodic table: Group 1 — Alkali Metals Physical Trends

5 min read 5 parts Lesson 4 of 7

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11.4 The periodic table: Group 1 — Alkali Metals Physical Trends — Alhussan International Academy — Chemistry (Stages 7–9) notes: Give the position of Group 1, describe and explain the pattern in its melting points and use data to describe trends.Position — Group 1 is the column …

  • Boiling point
  • Compared with other metals
  • Down the group
  • Attraction
  • Secondary source
  • Conclusion

Part 1 of 5Position and general properties

1Position1 point
— Group 1 is the column on the left of the periodic table.
  • The elements are lithium, sodium, potassium, rubidium, caesium and francium.
2Metals1 point
— like other metals, the Group 1 elements conduct electricity and are shiny when freshly cut.
  • A freshly cut surface tarnishes quickly in air.
3Softness
— they are softer than most other metals and can be cut with a knife.
4Uses
— lithium is used in the batteries of electric cars, and Bolivia has huge reserves of lithium in salt flats.

Part 2 of 5Physical trends down the group

MetalMelting point (°C)Boiling point (°C)Density (g/cm3)
Lithium18113300.53
Sodium988900.97
Potassium637740.86
Rubidium396881.53
  • Melting point — it decreases from lithium at the top to caesium at the bottom.
    • Caesium melts at about 29 °C, close to room temperature on a warm day.
  • Boiling point — it also decreases down the group.
  • Softness — the metals get softer down the group.
  • Compared with other metals — melting points are low compared with a typical transition metal such as iron (1538 °C).

Part 3 of 5Explaining the melting point pattern

  • Structure — Group 1 elements have giant metallic structures in which each atom loses its one outer electron to form a positive ion.
    • The electrons move around between the ions.
  • Down the group — the outer electron gets further from the nucleus and the positive ions get bigger.
  • Attraction — the electrostatic attraction between positive ions and negative electrons gets weaker.
  • Result — as attractions get weaker, ions leave their fixed positions more easily, so the melting point decreases.

Part 4 of 5Presenting data and drawing conclusions

  • Secondary source — Banjeet could not measure melting points himself, so he chose a trustworthy secondary source such as a reference table.
    • Evaluate a source by asking whether it is a reliable textbook or scientific database.
  • Table — the independent variable (the element) goes in the left column.
  • Bar chart — it is used because the independent variable, the element, is categoric (described by words).
  • Conclusion — from lithium at the top to caesium at the bottom, melting point decreases.
    • Quote values: lithium melts at 181 °C and rubidium at 39 °C, a fall of 142 °C.
  • Predicting — caesium should melt below rubidium, and interpolation within the data is more reliable than extrapolation beyond it.

Part 5 of 5Density

  • Patternoverall density increases from lithium at the top to caesium at the bottom, because the atoms become heavier.
  • Exceptionpotassium does not fit the pattern.
  • Floatinglithium, sodium and potassium are less dense than water and float, whereas rubidium and caesium are denser and sink.

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