Curriculum
Course: IAL Edexcel Linear (Chemistry)
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Curriculum

IAL Edexcel Linear (Chemistry)

Unit 1. Structure, Bonding and Introduction to Organic Chemistry

0/52 Dr Dabour Hub Science Diagram and Course Material

Unit 2. Energetics, Group Chemistry, Halogenoalkanes and Alcohols

0/68 Dr Dabour Hub Science Diagram and Course Material

Unit 4. Rates, Equilibria and Further Organic Chemistry

0/71 Dr Dabour Hub Science Diagram and Course Material

Unit 5. Transition Metals and Organic Nitrogen Chemistry

0/57 Dr Dabour Hub Science Diagram and Course Material
Quiz

4.8 Organic Analytical Techniques — Notes – Exam questions

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1.

Infrared spectroscopy identifies

functional groups from the absorption of characteristic wavenumbers
molecular mass
isotopes
empirical formula
2.

A strong, sharp absorption near 1700 cm⁻¹ indicates

an O–H group
a C–H group
a C=O group
a C≡N group
3.

A very broad absorption at 2500–3000 cm⁻¹ indicates

O–H in an alcohol
O–H in a carboxylic acid
N–H
C=C
4.

In a mass spectrum, the molecular ion peak gives

the number of carbon atoms directly
the relative molecular mass
the functional groups
the boiling point
5.

The M+1 peak is due to

loss of hydrogen
an impurity
the presence of ¹³C
²H only
6.

A compound containing one chlorine atom shows M and M+2 peaks in the ratio

1 : 1
3 : 1
1 : 3
9 : 1
7.

A compound containing one bromine atom shows M and M+2 peaks in the ratio

3 : 1
1 : 3
2 : 1
1 : 1
8.

A peak at m/e 15 in a mass spectrum is likely to be due to

C₂H₅⁺
OH⁺
CHO⁺
CH₃⁺
9.

The number of carbon atoms n is found from

n = M/12
n = M+1
n = 100 × (abundance of M+1)/(1.1 × abundance of M)
n = 1.1 × M
10.

An alcohol and a carboxylic acid can be distinguished by infrared because only the acid shows

a C=O absorption near 1700 cm⁻¹
an O–H absorption
a C–H absorption
a C–O absorption
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