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1.6.2Principles of Chemistry

Common Ions — Edexcel International GCSE Science Double Award 4SD0 - Chemistry Revision Notes & Topical Questions

5 min read 11 parts Lesson 35 of 50

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Curriculum Equation Key قوانين الرقم الهيدروجيني والاتزان الأيوني - pH & Acid-Base Equilibrium FormulasFast Exam Solution
pH = -log[H⁺] | pOH = -log[OH⁻] | pH + pOH = 14 | [H⁺][OH⁻] = 10⁻¹⁴
Word Equation & Conditions: الرقم الهيدروجيني = -لوغاريتم تركيز أيون الهيدروجين | pH + pOH = 14
Location & Specifications: الاتزان الأيوني، كيمياء 3 ثانوي، التحصيلي، و AP Chemistry.
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Part 1 of 5Predicting simple ions from the periodic table

GroupOuter electronsChangeIon chargeExamples
11Lose 11+Li+, Na+, K+
22Lose 22+Mg2+, Ca2+, Ba2+
33Lose 33+Al3+
66Gain 22−O2−, S2−
77Gain 11−F−, Cl−, Br−, I−

Part 2 of 5Ions you must simply remember

Transition metal ions
  • Transition metal ions These do not follow the group pattern and can have more than one charge.
  • Common ones are Fe2+ and Fe3+, Cu2+, Zn2+ and Ag+;
    • the Roman numeral in a name, such as iron(III), gives the charge.
Hydrogen and metal-like ions
  • Hydrogen and metal-like ions Hydrogen forms H+ in acids.
  • Ammonium, NH4+, is a positive ion made of non-metals.
Hydroxide
  • Hydroxide The hydroxide ion, OH−, is found in alkalis and metal hydroxides.

Part 3 of 5Compound (molecular) ions

NameFormulaCharge
HydroxideOH−1−
NitrateNO3−1−
CarbonateCO32−2−
SulfateSO42−2−
AmmoniumNH4+1+

Part 4 of 5Naming negative ions

-ide endings
  • -ide endings A single non-metal atom that has gained electrons ends in -ide: chloride, bromide, oxide, sulfide.
-ate endings
  • -ate endings Ions that contain oxygen along with another element end in -ate: sulfate, nitrate, carbonate.
  • Hydroxide is an exception that ends in -ide.
Group of atoms, one charge
  • Group of atoms, one charge In a compound ion the charge belongs to the whole group, not to a single atom,
    • which is why the brackets matter in later formulae.

Part 5 of 5Memory strategies

1
Learn the group pattern first: groups 1, 2 and 3 form 1+, 2+ and 3+ ions, and groups 6 and 7 form 2− and 1− ions.
2
Learn the five compound ions in the table, grouping them by charge: two with 1− (hydroxide, nitrate), two with 2− (carbonate, sulfate) and one with 1+ (ammonium).
3
Attach each transition metal to its usual charge, remembering that Fe and Cu can differ.
4
Test yourself by covering a column of the tables and writing it from memory.

Key terms

TermMeaning
CationA positive ion.
AnionA negative ion.
Compound ionA group of covalently bonded atoms that carries an overall charge, such as sulfate.
Transition metalA metal in the central block of the periodic table, often forming ions with different charges.
Roman numeralA number in brackets in a name that shows the charge on a metal ion, as in copper(II).

Avoid these mistakes

1
Writing the nitrate ion as NO32−. It has a 1− charge, whereas carbonate and sulfate are 2−.
2
Assuming all transition metals form the same charge. Check the Roman numeral in the name.
3
Forgetting that ammonium is positive, even though it contains only non-metals.
4
Confusing sulfide (S2−) with sulfate (SO42−).

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