1.7.1Principles of Chemistry
Formation of Covalent Bonds — Edexcel International GCSE Science Double Award 4SD0 - Chemistry Revision Notes & Topical Questions
5 min read 11 parts Lesson 41 of 50
Part 1 of 5Why atoms share electrons
Non-metals bonding together
- Non-metals bonding together When two non-metal atoms react, neither can easily lose electrons, so they share them instead.
Shared pairs
- Shared pairs A covalent bond is a shared pair of electrons between two atoms.
- Each atom contributes one electron to the pair.
Full outer shells
- Full outer shells By sharing, each atom has access to enough electrons to fill its outer shell, which makes the molecule stable.
Part 2 of 5How a covalent bond holds atoms together
1Atoms approach
- Atoms approach The outer shells of two atoms overlap.
2Electrons shared
- Electrons shared A pair of electrons is held in the region between the two nuclei.
3Electrostatic attraction
- Electrostatic attraction Both positive nuclei are attracted to the shared negative electrons, and this strong attraction is the bond.
4Molecule formed
- Molecule formed The atoms stay joined as a molecule with a definite formula.
Part 3 of 5Single, double and triple bonds
| Bond type | Shared pairs | Example | Drawn as |
|---|---|---|---|
| Single | 1 | H2, Cl2, HCl, H2O, CH4 | H–H |
| Double | 2 | O2, CO2, C2H4 | O=O |
| Triple | 3 | N2 | N≡N |
Part 4 of 5Common simple molecules
Covalent molecules
Hydrogen, H2
- Hydrogen, H2 Each hydrogen atom has one electron and needs one more to have two, a full first shell, so they share one pair.
Chlorine, Cl2
- Chlorine, Cl2 Each atom has seven outer electrons and needs one more, so one pair is shared.
Water, H2O
- Water, H2O Oxygen shares one pair with each of two hydrogen atoms, leaving two non-bonding pairs on oxygen.
Methane, CH4
- Methane, CH4 Carbon has four outer electrons and shares each with a hydrogen atom, making four single bonds.
Oxygen, O2 and nitrogen, N2
- Oxygen, O2 and nitrogen, N2 Oxygen atoms need two more electrons, so they share two pairs.
- Nitrogen atoms need three more, so they share three pairs.
Part 5 of 5Covalent compared with ionic bonding
Which elements
- Which elements Covalent bonding happens between non-metal atoms;
- ionic bonding is between a metal and a non-metal.
What happens to electrons
- What happens to electrons In covalent bonds electrons are shared; in ionic bonds they are transferred.
Strength
- Strength The covalent bond within a molecule is strong, but this tells us nothing about the forces between molecules, which are weak.
Key terms
| Term | Meaning |
|---|---|
| Covalent bond | A shared pair of electrons that holds two atoms together. |
| Molecule | A group of atoms joined by covalent bonds. |
| Single bond | A covalent bond with one shared pair of electrons. |
| Double bond | A covalent bond with two shared pairs of electrons. |
| Triple bond | A covalent bond with three shared pairs of electrons. |
Avoid these mistakes
1
Saying that electrons are transferred in covalent bonding. They are shared.
2
Counting a double bond as two electrons in total; it is two shared pairs, so four electrons.
3
Thinking the covalent bond is the attraction between molecules. It is the attraction between nuclei and shared electrons within a molecule.
4
Forgetting that hydrogen needs only two electrons in its outer shell.
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