1.3.1Principles of Chemistry
Atoms- Definitions and Structure — Edexcel International GCSE Science Double Award 4SD0 - Chemistry Revision Notes & Topical Questions
5 min read 5 parts Lesson 15 of 50
Part 1 of 5Structure of the Atom

All matter is built from atoms, each made of a central nucleus surrounded by electrons arranged in shells.
Proton
- A particle in the nucleus with a relative mass of 1 and a relative charge of +1, which gives the nucleus its positive charge.
Neutron
- A particle in the nucleus with a relative mass of 1 and no charge, which adds mass to the atom without changing the element.
Electron
- A particle in shells around the nucleus with a very small mass and a relative charge of −1,
- so a neutral atom has equal numbers of protons and electrons.
Nucleus
- The dense central region containing protons and neutrons, where almost all of the mass of the atom is concentrated.
| Particle | Relative mass | Relative charge | Location |
|---|---|---|---|
| Proton | 1 | +1 | Nucleus |
| Neutron | 1 | 0 | Nucleus |
| Electron | About 1/1840 | −1 | Shells around the nucleus |
Part 2 of 5Atomic Terms
Atomic Terms
Atomic number
- The number of protons in the nucleus, which identifies the element and equals the number of electrons in a neutral atom.
Mass number
- The total number of protons and neutrons in the nucleus, always the larger of the two numbers shown for an element.
Isotopes
- Atoms of the same element with the same number of protons but different numbers of neutrons, so their mass numbers differ.
Relative atomic mass
- The weighted average mass of the atoms of an element, compared with one twelfth of the mass of a carbon-12 atom.
Part 3 of 5Finding the Particle Numbers
1
Read the atomic number from the periodic table or the notation to find the number of protons in the atom.
2
In a neutral atom the number of electrons is equal to the number of protons, so the electron count is the same.
3
Subtract the atomic number from the mass number to find the number of neutrons.
4
Check that the protons plus neutrons add up to the mass number before writing the final answer.
Part 4 of 5Worked Example
Question Work out the numbers of protons, electrons and neutrons in potassium-39, which has atomic number 19 and mass number 39.
- Protons = atomic number = 19.
- Electrons = protons in a neutral atom = 19.
- Neutrons = mass number − atomic number = 39 − 19 = 20.
Answer 19 protons, 19 electrons and 20 neutrons.
Part 5 of 5Exam Checklist & Tips
1.3.1 – Key Points for the Exam
- Atom The smallest particle of an element that keeps the chemical properties of that element.
- Molecule A group of two or more atoms chemically combined to form an identifiable unit.
- Atomic number The number of protons in the nucleus of an atom.
- Mass number The number of protons plus neutrons in the nucleus of an atom.
- Isotope Atoms of the same element with the same number of protons but different numbers of neutrons.
- Relative atomic mass The weighted average mass of an atom of an element compared with one twelfth of a carbon-12 atom.
Common Mistakes
- Swapping the atomic number and mass number;
- the mass number is the larger value and includes protons plus neutrons.
- Placing electrons inside the nucleus; electrons occupy shells outside the nucleus.
- Saying that isotopes are different elements;
- isotopes have the same number of protons and so are the same element.
- Giving the atomic number as the number of neutrons; it is the number of protons.
Last updated:
\n