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A1.1Theme A — Unity and diversity

Water — IB Biology SL Revision Notes & Topical Questions

5 min read 12 parts Lesson 5 of 11 1 quiz

📚 IB Biology SL Hub / Topical Revision
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Curriculum Equation Key قوانين الرقم الهيدروجيني والاتزان الأيوني - pH & Acid-Base Equilibrium FormulasFast Exam Solution
pH = -log[H⁺] | pOH = -log[OH⁻] | pH + pOH = 14 | [H⁺][OH⁻] = 10⁻¹⁴
Word Equation & Conditions: الرقم الهيدروجيني = -لوغاريتم تركيز أيون الهيدروجين | pH + pOH = 14
Location & Specifications: الاتزان الأيوني، كيمياء 3 ثانوي، التحصيلي، و AP Chemistry.
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Lesson summary

A1.1 Water — IB BIOLOGY SL notes: Explain how the polarity and hydrogen bonding of water give it the properties that make it the medium for life.Medium for life — the first cells evolved in a watery environment, probably in deep oceans near hydrothermal ventsSome water and solute…

  • Liquid water
  • Search for life
  • Covalent bonds
  • Partial charges
  • Polar molecule
  • Consequences

Part 1 of 10Water and the origin of life

Medium for life
  • Medium for life the first cells evolved in a watery environment, probably in deep oceans near hydrothermal vents
  • Some water and solutes became trapped within a membrane and chemical reactions began inside it.
Liquid water
  • Liquid water lets dissolved molecules move, collide and react, so most life processes occur in water
Cytoplasm
  • Cytoplasm mostly water, so enzymes and substrates meet in solution
Water in numbers
  • Roughly 70-95% of cell mass is water.
  • About 71% of the Earth's surface is covered by water, a vast habitat.
Search for life
  • Search for life astronomers treat water on other planets and moons as a clue to possible life

Part 2 of 10Polarity of water

Polarity of water
Covalent bonds
  • Covalent bonds one oxygen atom shares electrons with two hydrogen atoms, but unequally
  • Oxygen is more electronegative, so it pulls the shared electrons closer.
Partial charges
  • δ- on the oxygen and δ+ on each hydrogen
  • The molecule is bent, with an angle of about 104.5°, so the charges do not cancel.
Dipole
Dipole a separation of charge within a molecule caused by unequal sharing of electrons
Polar molecule
Polar molecule a molecule with one slightly negative end and one slightly positive end
  • Water is overall neutral but polar.

Part 3 of 10Hydrogen bonds

Polar water molecules joined by intermolecular hydrogen bonds; O–H bonds within each molecule are covalent
Polar water molecules joined by intermolecular hydrogen bonds; O–H bonds within each molecule are covalent
1Hydrogen bond
Hydrogen bond the attraction between the δ+ hydrogen of one molecule and the δ- oxygen of a neighbouring molecule
  • Each water molecule can form up to four hydrogen bonds.
2Strength
  • Strength one bond is weak, so bonds constantly break and reform in liquid water
  • Huge numbers of bonds together give water strong collective properties.
3Consequences
  • Consequences hydrogen bonds explain cohesion, adhesion, solvent action and the thermal properties of water

Part 4 of 10Hydrogen bonds in other molecules

Covalent bonding in biological polymers — section 4
Covalent bonding in biological polymers — section 4
DNA
  • DNA hydrogen bonds hold complementary bases together across the two strands
Proteins
  • Proteins hydrogen bonds stabilise secondary and tertiary structure
Cellulose and collagen
  • Cellulose and collagen many hydrogen bonds between chains give high tensile strength
Protein synthesis
  • Protein synthesis tRNA anticodons attach to mRNA codons by hydrogen bonds
Membranes
  • Membranes polar phosphate heads hydrogen-bond with the surrounding water

Part 5 of 10Cohesion, adhesion and capillary action

Cohesion
Cohesion attraction between water molecules
  • It lets the xylem hold a continuous column of water under tension.
Surface tension
  • Surface tension cohesion at an air-water boundary
  • It forms a film that supports small insects such as pond skaters.
Adhesion
Adhesion attraction between water and other polar or charged surfaces, such as cellulose
  • Adhesion keeps the cell walls of leaf mesophyll cells moist for gas exchange.
Capillary action
  • Capillary action adhesion plus cohesion pulls water up narrow tubes and through soil pores
  • Spaces between cellulose fibres in cell walls also draw water out of the xylem.
1
Water evaporates from the leaf cell walls.
2
This creates tension that pulls on the water column.
3
Cohesion keeps the column unbroken.
4
Adhesion to the xylem walls resists the water falling back.
5
More water is drawn up from the roots.

Part 6 of 10Water as a solvent

Water transports dissolved mineral ions from roots through xylem to leaves.
Water transports dissolved mineral ions from roots through xylem to leaves.
Hydrophilic
  • Hydrophilic polar or charged substances such as ions, sugars and amino acids that dissolve readily
Hydrophobic
  • Hydrophobic non-polar substances such as lipids that do not dissolve
  • Hydrophobic interaction clusters non-polar molecules together because water bonds with itself and excludes them.
Hydration shell
  • Hydration shell water molecules cluster around an ion or polar solute and keep the particles apart
Universal solvent
  • Universal solvent most biological molecules are hydrophilic and dissolve in water
Metabolism
  • Metabolism many reactions in cells take place in solution
  • Hydrolysis and condensation involve water directly.
1
The crystal is placed in water.
2
The δ- oxygens face the positive sodium ions.
3
The δ+ hydrogens face the negative chloride ions.
4
Ions are pulled off the crystal lattice.
5
Hydration shells surround each ion.
6
The ions spread evenly through the solution.

Part 7 of 10Solubility and transport

Substance typeExampleSolubilityHow transported in blood
Ionic compoundSodium chlorideHighly solubleDissolved in plasma
Small polar moleculeGlucose, amino acidsSolubleDissolved in plasma
Non-polar gasOxygenPoorly solubleBound to haemoglobin
LipidTriglycerides, cholesterolInsolublePackaged in lipoproteins
Dissolved in plasma
  • Dissolved in plasma glucose, ions, urea and CO2 as hydrogencarbonate
Oxygen
  • Oxygen it is non-polar, so little dissolves, and it is less soluble at 37 °C than at 20 °C
  • Enough dissolves for aquatic life to breathe.
  • Haemoglobin binds oxygen so that enough is carried to all body cells.
Phospholipids
  • Phospholipids their non-polar tails form the water-excluding core of membranes, so insolubility is essential here
Amino acids
  • Amino acids even those with non-polar R groups dissolve enough to be transported
Enzymes
  • Enzymes water holds their shape stable, and hydrogen bonds help the substrate bind the active site

Part 8 of 10Physical properties: water compared with air

PropertyWaterAirConsequence for animals
BuoyancyHighVery lowAquatic animals need less skeletal support
ViscosityHighVery lowStreamlined shapes save energy when swimming
Thermal conductivityHigh, about 30 times that of airLowAquatic mammals lose heat fast and need blubber
Specific heat capacityHigh, about 4200 J kg-1 °C-1Low, about 1000 J kg-1 °C-1Water temperature stays stable and air temperature swings
Oxygen contentLow, falls as temperature risesAbout 21%Gills must extract oxygen efficiently
  • Specific heat capacity = the energy needed to raise 1 kg of a substance by 1 °C
    • Many hydrogen bonds must be broken to warm water, so its temperature changes slowly.
    • This gives stable aquatic habitats such as lakes and seas.

Part 9 of 10Adaptations of the ringed seal and black-throated loon

Floating ice
  • Floating ice ice is less dense than water, so it floats
  • It gives seals a resting surface and shelter below.
  • It conducts heat poorly, so it insulates the water beneath from freezing solid.
Ringed seal
  • Ringed seal blubber insulates against heat loss in Arctic water
  • Blubber is less dense than water, so it also aids buoyancy.
  • Flippers propel the seal.
Black-throated loon
  • Black-throated loon feathers trap air, which conducts heat poorly
  • Solid heavy bones and air squeezed from the feathers and lungs let it dive.
  • Webbed feet set far back reduce drag.
  • The low viscosity of air lets it fly with little resistance.

Part 10 of 10More from the specification

More from the specification
Polarity and dipolar nature
  • The asymmetric distribution of electron density creates a partially negative charged region on oxygen and partially positive regions on hydrogen atoms.
Hydrogen bonding
  • Electrostatic attraction between dipolar water molecules allows extensive hydrogen bond networks to form,
  • giving water high specific heat capacity and cohesion.
Surface tension and habitats
  • Cohesion allows water to form a resilient surface layer that small organisms can walk across.
Thermal buffering in living organisms
  • High latent heat of vaporisation allows water to act as an effective coolant during transpiration and sweating.
Organism
  • A living thing, such as a plant or an animal.

Key terms

TermMeaning
Polar moleculeA molecule with an uneven spread of charge, with the oxygen end of water slightly negative.
Hydrogen bondA weak attraction between a slightly positive hydrogen and a slightly negative atom of a neighbouring molecule.
CohesionWater molecules sticking to one another through hydrogen bonds.
AdhesionWater molecules sticking to other polar or charged surfaces.
HydrophilicAttracted to water, describing polar or charged substances.
HydrophobicNot attracted to water, describing non-polar substances such as fats.
Specific heat capacityThe energy needed to raise 1 kg of a substance by 1 °C.
Surface tensionThe film at an air-water surface caused by cohesion that supports small organisms.

Avoid these mistakes

1
Thinking hydrogen bonds are strong individually — each is weak and the strength comes from large numbers
2
Mixing up cohesion and adhesion — cohesion is water to water and adhesion is water to other surfaces
3
Saying water is polar because it is charged — it is neutral overall, with partial charges from unequal sharing
4
Saying all biological molecules dissolve in water — non-polar substances such as lipids do not

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